Plasma-Driven Tuning of Dielectric Permittivity in Graphene.
2D plasmons
N‐graphene
negative permittivity
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
27 Mar 2024
27 Mar 2024
Historique:
revised:
29
02
2024
received:
23
04
2023
medline:
27
3
2024
pubmed:
27
3
2024
entrez:
27
3
2024
Statut:
aheadofprint
Résumé
Materials with tunable negative electromagnetic performance, i.e., where dielectric permittivity becomes negative, have long been pursued in materials research due to their peculiar electromagnetic (EM) characteristics. Here, this promising feature is reported in materials on the case of plasma-synthesized nitrogen-doped graphene sheets with tunable permittivity over a wide (1-40 GHz) frequency range. Selectively incorporated nitrogen atoms in a graphene scaffold tailor the electronic structure in a way that provides an ultra-low energy (0.5-2 eV) 2D surface plasmon excitation, leading to subunitary and negative dielectric constant values in the Ka-band, from 30 up to 40 GHz. By allowing the tailoring of structures at atomic scale, this novel plasma-based approach creates a new paradigm for designing 2D nanomaterials like nanocarbons with controllable and tunable permittivity, opening a path to the next generation of 2D metamaterials.
Identifiants
pubmed: 38533978
doi: 10.1002/smll.202303421
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2303421Subventions
Organisme : European Union's Horizon Research
ID : 766894
Organisme : Portuguese FCT - Fundação para a Ciência e a Tecnologia
ID : UIDB/50010/2020
Organisme : Portuguese FCT - Fundação para a Ciência e a Tecnologia
ID : UIDP/50010/2020
Organisme : Portuguese FCT - Fundação para a Ciência e a Tecnologia
ID : LA/P/0061/202
Organisme : Eager project
ID : PTDC/NAN-MAT/30565/2017
Organisme : iBB
Organisme : i4HB projects
ID : UIDB/04565/2020
Organisme : i4HB projects
ID : UIDP/04565/2020
Organisme : i4HB projects
ID : LA/P/0140/2020
Organisme : Slovenian Research Agency
ID : N2-0107
Organisme : Slovenian Research Agency
ID : N2-0213
Organisme : Slovenian Research Agency
ID : Z2-4467
Organisme : EU Graphene Flagship FLAG-ERA III JTC 2021 project "VEGA"
ID : ANR-21-GRF1-0004
Organisme : EU Graphene Flagship FLAG-ERA III JTC 2021 project "VEGA"
ID : MIZS-PR-11938
Informations de copyright
© 2024 The Authors. Small published by Wiley‐VCH GmbH.
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