Highly sensitive plasmonic paper substrate fabricated via amphiphilic polymer self-assembly in microdroplet for detection of emerging pharmaceutical pollutants.
Air/liquid interface
Emerging pollutants
Microdroplet
Self-assembly
Surface-enhanced Raman scattering
Journal
Nano convergence
ISSN: 2196-5404
Titre abrégé: Nano Converg
Pays: England
ID NLM: 101695675
Informations de publication
Date de publication:
29 Mar 2024
29 Mar 2024
Historique:
received:
06
01
2024
accepted:
13
03
2024
medline:
29
3
2024
pubmed:
29
3
2024
entrez:
29
3
2024
Statut:
epublish
Résumé
We report an innovative and facile approach to fabricating an ultrasensitive plasmonic paper substrate for surface-enhanced Raman spectroscopy (SERS). The approach exploits the self-assembling capability of poly(styrene-b-2-vinyl pyridine) block copolymers to form a thin film at the air-liquid interface within the single microdroplet scale for the first time and the subsequent in situ growth of silver nanoparticles (AgNPs). The concentration of the block copolymer was found to play an essential role in stabilizing the droplets during the mass transfer phase and formation of silver nanoparticles, thus influencing the SERS signals. SEM analysis of the morphology of the plasmonic paper substrates revealed the formation of spherical AgNPs evenly distributed across the surface of the formed copolymer film with a size distribution of 47.5 nm. The resultant enhancement factor was calculated to be 1.2 × 10
Identifiants
pubmed: 38551725
doi: 10.1186/s40580-024-00420-x
pii: 10.1186/s40580-024-00420-x
doi:
Types de publication
Journal Article
Langues
eng
Pagination
13Subventions
Organisme : Ministry of Education
ID : 2023R1A2C1004414
Informations de copyright
© 2024. The Author(s).
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