Structure and complexation mechanism of aqueous Zn(II)-acetate complex studied by XAFS and Raman spectroscopies.
Metal chelates
Raman spectroscopy
Structure of aqueous complexes
XAFS in liquids
Journal
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
ISSN: 1348-2246
Titre abrégé: Anal Sci
Pays: Switzerland
ID NLM: 8511078
Informations de publication
Date de publication:
05 Apr 2024
05 Apr 2024
Historique:
received:
05
12
2023
accepted:
27
02
2024
medline:
6
4
2024
pubmed:
6
4
2024
entrez:
5
4
2024
Statut:
aheadofprint
Résumé
In this work, the structure of Zn acetate has been determined by a combination of X-ray absorption fine structure and Raman spectroscopy. We have analyzed the local atomic environment and the main vibrational bands of the acetate and Zn acetate at different pH. The results suggest that Zn acetate complex acquires a bidentate structure that modifies its first coordination shell. Meanwhile, the coordination shell of the hydrated Zn cation is formed by 6 hydroxides at a mean distance of 2.06 Å, the coordination shell of the Zn cation in the complex is formed by 2 hydroxides and 2 oxygens from the carboxyl group of the acetate, at a mean Zn-O distance of 1.96 Å. The structure of the Zn acetate complex is compared to those of Zn malonate and Zn citrate, none of which present a reduction in the coordination shell neither a shrinkage of the Zn-O shell distance.
Identifiants
pubmed: 38580852
doi: 10.1007/s44211-024-00549-z
pii: 10.1007/s44211-024-00549-z
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : Comunidad de Madrid
ID : 2018-T1/IND-10360
Organisme : Ministerio de Ciencia e Innovación
ID : PID2021-126323OA-I00
Organisme : Japan Society for the Promotion of Science
ID : 21H01670
Informations de copyright
© 2024. The Author(s).
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