The Ring-Closing Reaction of Cyclopentadiene Probed with Ultrafast X-ray Scattering.

Journal

The journal of physical chemistry. A
ISSN: 1520-5215
Titre abrégé: J Phys Chem A
Pays: United States
ID NLM: 9890903

Informations de publication

Date de publication:
06 May 2024
Historique:
medline: 6 5 2024
pubmed: 6 5 2024
entrez: 6 5 2024
Statut: aheadofprint

Résumé

The dynamics of cyclopentadiene (CP) following optical excitation at 243 nm was investigated by time-resolved pump-probe X-ray scattering using 16.2 keV X-rays at the Linac Coherent Light Source (LCLS). We present the first ultrafast structural evidence that the reaction leads directly to the formation of bicyclo[2.1.0]pentene (BP), a strained molecule with three- and four-membered rings. The bicyclic compound decays

Identifiants

DOI: 10.1021/acs.jpca.4c02509 PMID: 38709555
pubmed: 38709555
doi: 10.1021/acs.jpca.4c02509
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Auteurs

Lisa Huang (L)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
ORCID: 0000-0002-4357-9038

Lauren Bertram (L)

Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom.

Lingyu Ma (L)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.

Nathan Goff (N)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.

Stuart W Crane (SW)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
ORCID: 0000-0002-3517-5615

Asami Odate (A)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.

Thomas Northey (T)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.

Andrés Moreno Carrascosa (AM)

Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom.

Mats Simmermacher (M)

Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom.

Sri Bhavya Muvva (SB)

Department of Physics and Astronomy, University of Nebraska - Lincoln, Lincoln, Nebraska 68588, United States.
ORCID: 0000-0002-1051-019X

Joseph D Geiser (JD)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.

Matthew J Lueckheide (MJ)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
ORCID: 0000-0003-3590-6112

Zane Phelps (Z)

Department of Physics, Kansas State University, Manhattan, Kansas 66506, United States.

Mengning Liang (M)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.

Xinxin Cheng (X)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.
ORCID: 0000-0001-7586-8240

Ruaridh Forbes (R)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.
ORCID: 0000-0003-2097-5991

Joseph S Robinson (JS)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.

Matthew J Hayes (MJ)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.

Felix Allum (F)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.
ORCID: 0000-0002-8044-8969

Alice E Green (AE)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.
European XFEL, Schenefeld 22869, Germany.

Kenneth Lopata (K)

Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
ORCID: 0000-0002-9141-684X

Artem Rudenko (A)

Department of Physics, Kansas State University, Manhattan, Kansas 66506, United States.

Thomas J A Wolf (TJA)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.
ORCID: 0000-0002-0641-1279

Martin Centurion (M)

Department of Physics and Astronomy, University of Nebraska - Lincoln, Lincoln, Nebraska 68588, United States.

Daniel Rolles (D)

Department of Physics, Kansas State University, Manhattan, Kansas 66506, United States.
ORCID: 0000-0002-3965-3477

Michael P Minitti (MP)

SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States.

Adam Kirrander (A)

Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom.
ORCID: 0000-0002-3347-8137

Peter M Weber (PM)

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States.
ORCID: 0000-0003-3017-336X

Classifications MeSH