Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides.
hydroxide ion conductivity
intercalation
layered double hydroxide
surface ionic conductivity
surface modification
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
08 May 2024
08 May 2024
Historique:
revised:
09
04
2024
received:
25
03
2024
medline:
8
5
2024
pubmed:
8
5
2024
entrez:
8
5
2024
Statut:
aheadofprint
Résumé
Understanding ionic conduction in layered double hydroxides (LDHs) is a crucial step towards utilizing them as solid, hydroxide ion-conducting electrolytes in energy conversion applications. We selectively modified the interlayer and external surfaces of MgAl LDHs with tris(hydroxymethyl)aminomethane (TRIS) ligands. By adjusting the concentration of the TRIS surface modifier, the LDH basal plane surfaces could be functionalized everywhere (internally and externally) or only externally. External modification resulted in loss of OH-conductivity compared to pristine LDHs, confirming that external platelet surfaces are the primary ion conduction pathway.
Identifiants
pubmed: 38717790
doi: 10.1002/cssc.202400641
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202400641Subventions
Organisme : U.S. Department of Energy, Office of Science, Basic Energy Sciences
ID : DE-SC0019445
Organisme : U.S. Department of Energy, Office of Science, Basic Energy Sciences
ID : NSF GRFP
Organisme : U.S. Department of Energy, Office of Science, Basic Energy Sciences
ID : DGE-1845298
Organisme : University of Pennsylvania Department of Chemistry
ID : NNCI-2025608
Informations de copyright
© 2024 The Authors. ChemSusChem published by Wiley-VCH GmbH.
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