Fluorescence Lifetime Imaging of Lipid Heterogeneity in the Inner Mitochondrial Membrane with a Super-photostable Environment-Sensitive Probe.

Fluorescence lifetime imaging Imaging agents Inner mitochondrial membrane Lipid heterogeneity Phosphorus heterocycles

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
28 May 2024
Historique:
received: 04 03 2024
medline: 28 5 2024
pubmed: 28 5 2024
entrez: 28 5 2024
Statut: aheadofprint

Résumé

The inner mitochondrial membrane (IMM) undergoes dynamic morphological changes, which are crucial for the maintenance of mitochondrial functions as well as cell survival. As the dynamics of the membrane are governed by its lipid components, a fluorescent probe that can sense spatiotemporal alterations in the lipid properties of the IMM over long periods of time is required to understand mitochondrial physiological functions in detail. Herein, we report a red-emissive IMM-labeling reagent with excellent photostability and sensitivity to its environment, which enables the visualization of the IMM ultrastructure using super-resolution microscopy as well as of the lipid heterogeneity based on the fluorescence lifetime at the single mitochondrion level. Combining the probe and fluorescence lifetime imaging microscopy (FLIM) showed that peroxidation of unsaturated lipids in the IMM by reactive oxygen species caused an increase in the membrane order, which took place prior to mitochondrial swelling.

Identifiants

pubmed: 38804831
doi: 10.1002/anie.202404328
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202404328

Subventions

Organisme : Japan Society for the Promotion of Science
ID : 19H02849
Organisme : Japan Society for the Promotion of Science
ID : 23K06101
Organisme : Japan Society for the Promotion of Science
ID : JP22H04926
Organisme : Core Research for Evolutional Science and Technology
ID : JPMJCR21O5
Organisme : Exploratory Research for Advanced Technology
ID : JPMJER2101

Informations de copyright

© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

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Auteurs

Junwei Wang (J)

Institute of Transformative Bio-Molecules, Nagoya University, Furo, Chikusa, Nagoya 464-8601, Japan.

Masayasu Taki (M)

Institute of Transformative Bio-Molecules, Nagoya University, Furo, Chikusa, Nagoya 464-8601, Japan.

Yohsuke Ohba (Y)

Division of Physiological Chemistry and Metabolism, Graduate School of Pharmaceutical Sciences, Keio University, Minato-ku, Tokyo 105-8512, Japan.
Laboratory for Metabolomics, RIKEN Center for Integrative Medical Sciences (IMS), Tsurumi-ku, Yokohama, Kanagawa 230-0045, Japan.

Makoto Arita (M)

Division of Physiological Chemistry and Metabolism, Graduate School of Pharmaceutical Sciences, Keio University, Minato-ku, Tokyo 105-8512, Japan.
Laboratory for Metabolomics, RIKEN Center for Integrative Medical Sciences (IMS), Tsurumi-ku, Yokohama, Kanagawa 230-0045, Japan.
Cellular and Molecular Epigenetics Laboratory, Graduate School of Medical Life Science, Yokohama-City University, Tsurumi-ku, Yokohama, Kanagawa 230-0045, Japan.
Human Biology-Microbiome-Quantum Research Center (WPI-Bio2Q), Keio University, Shinjuku-ku, Tokyo 160-8582, Japan.

Shigehiro Yamaguchi (S)

Institute of Transformative Bio-Molecules, Nagoya University, Furo, Chikusa, Nagoya 464-8601, Japan.
Department of Chemistry, Graduate School of Science, Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan.

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