Photochemical Action Plots Map Orthogonal Reactivity in Photochemical Release Systems.

photochemical action plots precision photochemistry wavelength orthogonal release systems

Journal

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
ISSN: 2198-3844
Titre abrégé: Adv Sci (Weinh)
Pays: Germany
ID NLM: 101664569

Informations de publication

Date de publication:
09 Jun 2024
Historique:
revised: 03 05 2024
received: 25 02 2024
medline: 9 6 2024
pubmed: 9 6 2024
entrez: 9 6 2024
Statut: aheadofprint

Résumé

The wavelength-by-wavelength resolved photoreactivity of two photo-caged carboxylic acids, i. e. 7-(diethylamino)-coumarin- and 3-perylene-modified substrates, is investigated via photochemical action plots. The observed wavelength-dependent reactivity of the chromophores is contrasted with their absorption profile. The photochemical action plots reveal a remarkable mismatch between the maximum reactivity and the absorbance. Through the action plot data, the study is able to uncover photochemical reactivity maxima at longer and shorter wavelengths, where the molar absorptivity of the chromophores is strongly reduced. Finally, the laser experiments are translated to light emitting diode (LED) irradiation and show efficient visible-light-induced release in a near fully wavelength-orthogonal, sequence-independent fashion (λ

Identifiants

pubmed: 38852174
doi: 10.1002/advs.202402011
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2402011

Subventions

Organisme : Australian Research Council
Organisme : QUT's Centre for Materials Science
Organisme : Deutsche Forschungsgemeinschaft
Organisme : QUT's Research Portfolio

Informations de copyright

© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.

Références

H. D. Roth, Angew. Chem., Int. Ed. 1989, 28, 1193.
J. O. Mueller, N. K. Guimard, K. K. Oehlenschlaeger, F. G. Schmidt, C. Barner‐Kowollik, Polym. Chem. 2014, 5, 1447.
H. Frisch, D. E. Marschner, A. S. Goldmann, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2018, 57, 2036.
a) S. Aubert, M. Bezagu, A. C. Spivey, S. Arseniyadis, Nat. Rev. Chem. 2019, 3, 706;
b) A. Jana, K. S. P. Devi, T. K. Maiti, N. D. P. Singh, J. Am. Chem. Soc. 2012, 134, 7656.
T. Friedel, N. Travitzky, F. Niebling, M. Scheffler, P. Greil, J. Eur. Ceram. Soc. 2005, 25, 193.
a) S. C. Gauci, M. Gernhardt, H. Frisch, H. A. Houck, J. P. Blinco, E. Blasco, B. T. Tuten, C. Barner‐Kowollik, Adv. Funct. Mater. 2022, 33, 2206303;
b) M. Regehly, Y. Garmshausen, M. Reuter, N. F. König, E. Israel, D. P. Kelly, C.‐Y. Chou, K. Koch, B. Asfari, S. Hecht, Nature 2020, 588, 620;
c) V. Hahn, P. Rietz, F. Hermann, P. Müller, C. Barner‐Kowollik, T. Schlöder, W. Wenzel, E. Blasco, M. Wegener, Nat. Photon. 2022, 16, 784.
a) R. T. Michenfelder, L. Delafresnaye, V. X. Truong, C. Barner‐Kowollik, H.‐A. Wagenknecht, Chem. Commun. 2023, 59, 4012;
b) Z. Yu, T. Y. Ohulchanskyy, P. An, P. N. Prasad, Q. Lin, J. Am. Chem. Soc. 2013, 135, 16766;
c) S. Nainar, M. Kubota, C. McNitt, C. Tran, V. V. Popik, R. C. Spitale, J. Am. Chem. Soc. 2017, 139, 8090;
d) V. M. Lechner, M. Nappi, P. J. Deneny, S. Folliet, J. C. K. Chu, M. J. Gaunt, Chem. Rev. 2022, 122, 1752.
a) I. M. Irshadeen, S. L. Walden, M. Wegener, V. X. Truong, H. Frisch, J. P. Blinco, C. Barner‐Kowollik, J. Am. Chem. Soc. 2021, 143, 21113;
b) K. Ehrmann, C. Barner‐Kowollik, J. Am. Chem. Soc. 2023, 145, 24438.
T. N. Eren, F. Feist, K. Ehrmann, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2023, 62, e202307535.
J. Kaufmann, F. Sinsel, A. Heckel, Chem. ‐ Eur. J. 2023, 29, e202204014.
a) L. Duy Thai, J. Fanelli, R. Munaweera, M. O'Mara, C. Barner‐Kowollik, H. Mutlu, Angew. Chem. Int. Ed. 2024, 63, e202315887;
b) S. C. Gauci, F. E. Du Prez, J. O. Holloway, H. A. Houck, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2023, 62, e202310274.
a) H. Frisch, J. P. Menzel, F. R. Bloesser, D. E. Marschner, K. Mundsinger, C. Barner‐Kowollik, J. Am. Chem. Soc. 2018, 140, 9551;
b) D. E. Marschner, H. Frisch, J. T. Offenloch, B. T. Tuten, C. R. Becer, A. Walther, A. S. Goldmann, P. Tzvetkova, C. Barner‐Kowollik, Macromolecules 2018, 51, 3802;
c) D. E. Marschner, P. W. Kamm, H. Frisch, A.‐N. Unterreiner, C. Barner‐Kowollik, Chem. Commun. 2020, 56, 14043;
d) J. P. Menzel, B. B. Noble, J. P. Blinco, C. Barner‐Kowollik, Nat. Commun. 2021, 12, 1691;
e) F. Feist, S. L. Walden, J. Alves, S. V. Kunz, A. S. Micallef, A. J. Brock, J. C. McMurtrie, T. Weil, J. P. Blinco, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2021, 60, 10402;
f) V. X. Truong, J. Bachmann, A.‐N. Unterreiner, J. P. Blinco, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2022, 61, e202113076;
g) I. M. Irshadeen, K. De Bruycker, A. S. Micallef, S. L. Walden, H. Frisch, C. Barner‐Kowollik, Polym. Chem. 2021, 12, 4903;
h) K. Kalayci, H. Frisch, V. X. Truong, C. Barner‐Kowollik, Nat. Commun. 2020, 11, 4193;
i) J. A. Carroll, F. Pashley‐Johnson, H. Frisch, C. Barner‐Kowollik, Chem. Eur. J. 2024, 30, e202304174.
J. Bachmann, C. Petit, L. Michalek, Y. Catel, E. Blasco, J. P. Blinco, A.‐N. Unterreiner, C. Barner‐Kowollik, ACS Macro Lett. 2021, 10, 447.
S. L. Walden, J. A. Carroll, A.‐N. Unterreiner, C. Barner‐Kowollik, Adv. Sci. 2024, 11, 2306014.
a) I. Aujard, C. Benbrahim, M. Gouget, O. Ruel, J.‐B. Baudin, P. Neveu, L. Jullien, Chem. ‐ Eur. J. 2006, 12, 6865;
b) M. S. Kim, S. L. Diamond, Bioorg. Med. Chem. Lett. 2006, 16, 4007.
a) A. Bollu, N. Klöcker, P. Špaček, F. P. Weissenboeck, S. Hüwel, A. Rentmeister, Angew. Chem., Int. Ed. 2023, 62, e202209975;
b) T. Yu, P. Zhang, Y. Zhao, H. Zhang, J. Meng, D. Fan, Org. Electron. 2009, 10, 653.
a) P. Seyfried, M. Heinz, G. Pintér, D.‐P. Klötzner, Y. Becker, M. Bolte, H. R. A. Jonker, L. S. Stelzl, G. Hummer, H. Schwalbe, A. Heckel, Chem.‐Eur. J. 2018, 24, 17568;
b) W. Zhou, C. P. Hankinson, A. Deiters, ChemBioChem 2020, 21, 1832.
M. Zhou, X. Liang, T. Mochizuki, H. Asanuma, Angew. Chem., Int. Ed. 2010, 49, 2167.
N. Klöcker, F. P. Weissenboeck, M. van Dülmen, P. Špaček, S. Hüwel, A. Rentmeister, Nat. Chem. 2022, 14, 905.
V. X. Truong, F. Li, J. S. Forsythe, ACS Appl. Mater. Interfaces 2017, 9, 32441.
P. A. Shaw, M. Klausen, M. Bradley, Polym. Chem. 2024, 15, 54.
a) M. A. Azagarsamy, K. S. Anseth, Angew. Chem., Int. Ed. 2013, 52, 13803;
b) T. L. Rapp, C. A. DeForest, Nat. Commun. 2023, 14, 5250.
a) K. Hiltebrandt, T. Pauloehrl, J. P. Blinco, K. Linkert, H. G. Börner, C. Barner‐Kowollik, Angew. Chem. Int. Ed. 2015, 54, 2838;
b) V. X. Truong, F. Li, F. Ercole, J. S. Forsythe, ACS Macro Lett. 2018, 7, 464.
D. E. Fast, A. Lauer, J. P. Menzel, A.‐M. Kelterer, G. Gescheidt, C. Barner‐Kowollik, Macromolecules 2017, 50, 1815.
J. L. Pelloth, P. A. Tran, A. Walther, A. S. Goldmann, H. Frisch, V. X. Truong, C. Barner‐Kowollik, Adv. Mater. 2021, 33, 2102184.
a) P. Klán, T. Šolomek, C. G. Bochet, A. Blanc, R. Givens, M. Rubina, V. Popik, A. Kostikov, J. Wirz, Chem. Rev. 2013, 113, 119;
b) R. Weinstain, T. Slanina, D. Kand, P. Klán, Chem. Rev. 2020, 120, 13135.
a) B. Schade, V. Hagen, R. Schmidt, R. Herbrich, E. Krause, T. Eckardt, J. Bendig, J. Org. Chem. 1999, 64, 9109;
b) R. Schmidt, D. Geissler, V. Hagen, J. Bendig, J. Phys. Chem. 2007, 111, 5768.
S. Kinze, M. Clauss, U. Reuter, T. Wolf, J. P. Dreier, K. M. Einhäupl, G. Arnold, Headache 2001, 41, 774.

Auteurs

Rita T Michenfelder (RT)

School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.
Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.

Fred Pashley-Johnson (F)

School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.
Polymer Chemistry Research Group, Centre of Macromolecular Chemistry (CMaC) and Laboratory of Organic Synthesis, Department of Organic and Macromolecular Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281-S4, Ghent, 9000, Belgium.

Viktor Guschin (V)

Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.

Laura Delafresnaye (L)

School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.

Vinh X Truong (VX)

Institute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), 1 Pesek Round, Jurong Island, Singapore, 627833, Republic of Singapore.

Hans-Achim Wagenknecht (HA)

Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.

Christopher Barner-Kowollik (C)

School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.
Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.

Classifications MeSH