Redox Active Ligands for Catalyzing the Hydrogen Evolution Reaction.
Antimony corrole, boron subphthalocyanines, hydrogen evolution reaction (HER), catalysis, reaction mechanism
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
13 Jun 2024
13 Jun 2024
Historique:
revised:
10
06
2024
received:
05
06
2024
accepted:
10
06
2024
medline:
13
6
2024
pubmed:
13
6
2024
entrez:
13
6
2024
Statut:
aheadofprint
Résumé
Boron subphthalocyanines with chloride and fluoride axial ligands and three antimony complexes chelated by corroles that differ in size and electron-richness were examined as electrocatalysts for reduction of protons to hydrogen. Experiment- and computation-based investigations revealed that all redox events are ligand-centered and that the meso-C of the corroles and the peripheral N atoms of the subphthalocyanines are the largely preferred proton-binding sites.
Identifiants
pubmed: 38869100
doi: 10.1002/chem.202402145
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202402145Informations de copyright
© 2024 Wiley‐VCH GmbH.