Brucine Suppresses Malignant Progression of Prostate Cancer by Decreasing Sarcosine Accumulation via Downregulation of GNMT in the Glycine/sarcosine Metabolic Pathway.

Amino acid metabolism Apoptosis Brucine Proliferation Prostate cancer

Journal

Cell biochemistry and biophysics
ISSN: 1559-0283
Titre abrégé: Cell Biochem Biophys
Pays: United States
ID NLM: 9701934

Informations de publication

Date de publication:
14 Jun 2024
Historique:
accepted: 01 06 2024
medline: 15 6 2024
pubmed: 15 6 2024
entrez: 14 6 2024
Statut: aheadofprint

Résumé

Prostate cancer (PCa) remains a leading cause of cancer-related incidence and mortality in men. Disruptions in amino acid (AA) metabolism contribute to the disease progression, with brucine, a glycine antagonist, exhibiting antitumor effects. This study explores the antitumor impact of brucine on PCa and investigates its mechanisms in regulating AA metabolic pathways. The study employed the PCa cell line DU-145, characterized by high sarcosine (Sar) levels, for various assays including Cell Counting Kit-8 (CCK8), wound healing, Transwell, 5-Ethynyl-2'-deoxyuridine (EDU), TdT mediated dUTP Nick End Labeling (TUNEL), flow cytometry, Western blot, and ultra-high-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). Network pharmacological analysis determined the anticancer mechanisms of brucine. Sar levels in DU-145 cells were significantly higher than in normal prostatic epithelial cells RWPE-1. Treatment with brucine resulted in a marked decrease in cell viability, proliferation, invasion, and migration, while promoting apoptosis in a dose-dependent manner. Sar levels decreased with increasing brucine concentration. Network pharmacology analysis linked brucine's anticancer effect to the AA metabolism and glycine N-methyltransferase (GNMT) pathways. GNMT expression in prostate cancer tissues and The Cancer Genome Atlas database was significantly elevated compared to controls. Treatment with brucine led to downregulation of GNMT expression in DU-145 cells without significant effect on sarcosine dehydrogenase (SARDH). Addition of recombinant GNMT partially reversed the inhibitory effects of brucine on DU-145 cells. Treatment with brucine downregulates GNMT expression in DU-145 cells, reducing Sar accumulation and inhibiting tumor progression. These findings provide new insights into the antitumor mechanisms of brucine in PCa.

Identifiants

pubmed: 38877335
doi: 10.1007/s12013-024-01348-z
pii: 10.1007/s12013-024-01348-z
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : the Science and Technology Planning Project of Traditional Chinese Medicine, Jiangsu
ID : YB2020050

Informations de copyright

© 2024. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.

Références

Saeidi, H., Ismail, P., & Samudi Raju, C., et al. (2023). Genetic alterations in prostate cancer as diagnostic and prognostic markers. Malaysian Journal of Pathology, 45(2), 149–155.
pubmed: 37658525
Washington, C., Goldstein, D. A., & Moore, A., et al. (2022). Health Disparities in Prostate Cancer and Approaches to Advance Equitable Care. American Society of Clinical Oncology Educational Book, 42, 1–6.
pubmed: 35671436
Liu, J., Dong, L., & Zhu, Y., et al. (2022). Prostate cancer treatment - China’s perspective. Cancer Letters, 550, 215927.
doi: 10.1016/j.canlet.2022.215927 pubmed: 36162714
Sung, H., Ferlay, J., & Siegel, R. L., et al. (2021). Global Cancer Statistics 2020: GLOBOCAN Estimates of Incidence and Mortality Worldwide for 36 Cancers in 185 Countries. CA A Cancer Journal for Clinicians, 71(3), 209–249.
doi: 10.3322/caac.21660 pubmed: 33538338
Wang, G., Zhao, D., & Spring, D. J., et al. (2018). Genetics and biology of prostate cancer. Genes Dev, 32(17-18), 1105–1140.
doi: 10.1101/gad.315739.118 pubmed: 30181359 pmcid: 6120714
Harris, A. E., Metzler, V. M., & Lothion-Roy, J., et al. (2022). Exploring anti-androgen therapies in hormone dependent prostate cancer and new therapeutic routes for castration resistant prostate cancer. Frontiers in Endocrinology, 13, 1006101.
doi: 10.3389/fendo.2022.1006101 pubmed: 36263323 pmcid: 9575553
Zhang, Q., Zhang, P., & Zhao, Z., et al. (2023). Exploring the role of differentially expressed metabolic genes and their mechanisms in bone metastatic prostate cancer. PeerJ, 11, e15013.
doi: 10.7717/peerj.15013 pubmed: 37070095 pmcid: 10105558
Zhang, X., Xia, B., & Zheng, H., et al. (2022). Identification of characteristic metabolic panels for different stages of prostate cancer by (1)H NMR-based metabolomics analysis. Journal of Translational Medicine, 20(1), 275.
doi: 10.1186/s12967-022-03478-5 pubmed: 35715864 pmcid: 9205125
Kdadra, M., Hockner, S., & Leung, H., et al. (2019). Metabolomics Biomarkers of Prostate Cancer: A Systematic Review. Diagnostics, 9(1), 21.
doi: 10.3390/diagnostics9010021 pubmed: 30791464 pmcid: 6468767
Zheng, H., Dong, B., & Ning, J., et al. (2020). NMR-based metabolomics analysis identifies discriminatory metabolic disturbances in tissue and biofluid samples for progressive prostate cancer. Clinica Chimica Acta, 501, 241–251.
doi: 10.1016/j.cca.2019.10.046
Strmiska, V., Michalek, P., & Eckschlager, T., et al. (2019). Prostate cancer-specific hallmarks of amino acids metabolism: Towards a paradigm of precision medicine. Biochimica et Biophysica Acta Reviews on Cancer, 1871(2), 248–258.
doi: 10.1016/j.bbcan.2019.01.001 pubmed: 30708041
Sreekumar, A., Poisson, L. M., & Rajendiran, T. M., et al. (2009). Metabolomic profiles delineate potential role for sarcosine in prostate cancer progression. Nature, 457(7231), 910–4.
doi: 10.1038/nature07762 pubmed: 19212411 pmcid: 2724746
Huang, Y. C., Lee, C. M., & Chen, M., et al. (2007). Haplotypes, loss of heterozygosity, and expression levels of glycine N-methyltransferase in prostate cancer. Clinical Cancer Research, 13(5), 1412–20.
doi: 10.1158/1078-0432.CCR-06-1551 pubmed: 17332283
Dodt, G., Kim, D. G., & Reimann, S. A., et al. (2000). L-Pipecolic acid oxidase, a human enzyme essential for the degradation of L-pipecolic acid, is most similar to the monomeric sarcosine oxidases. Biochemical Journal, 345(Pt 3), 487–94.
doi: 10.1042/bj3450487 pubmed: 10642506 pmcid: 1220782
Song, Y. H., Shiota, M., & Kuroiwa, K., et al. (2011). The important role of glycine N-methyltransferase in the carcinogenesis and progression of prostate cancer. Modern Pathology, 24(9), 1272–80.
doi: 10.1038/modpathol.2011.76 pubmed: 21572396
Strmiska, V., Michalek, P., & Lackova, Z., et al. (2019). Sarcosine is a prostate epigenetic modifier that elicits aberrant methylation patterns through the SAMe-Dnmts axis. Molecular Oncology, 13(5), 1002–1017.
Khan, A. P., Rajendiran, T. M., & Ateeq, B., et al. (2013). The role of sarcosine metabolism in prostate cancer progression. Neoplasia, 15(5), 491–501.
doi: 10.1593/neo.13314 pubmed: 23633921 pmcid: 3638352
Heger, Z., Gumulec, J., & Cernei, N., et al. (2016). Relation of exposure to amino acids involved in sarcosine metabolic pathway on behavior of non-tumor and malignant prostatic cell lines. Prostate, 76(7), 679–90.
doi: 10.1002/pros.23159 pubmed: 26847870
Lu, L., Huang, R., & Wu, Y., et al. (2020). Brucine: A Review of Phytochemistry, Pharmacology, and Toxicology. Frontiers in Pharmacology, 11, 377.
doi: 10.3389/fphar.2020.00377 pubmed: 32308621 pmcid: 7145893
Kang, Q., Zheng, K., & Jiang, G. M., et al. (2023). Brucine suppresses proliferation and promotes apoptosis of human cholangiacarcinoma cells via the inhibition of COX2 expression. Journal of Cancer, 14(14), 2700–2706.
doi: 10.7150/jca.87514 pubmed: 37779869 pmcid: 10539398
Lei, Y., Hou, F., & Wu, X., et al. (2022). Brucine-Induced Neurotoxicity by Targeting Caspase 3: Involvement of PPARgamma/NF-kappaB/Apoptosis Signaling Pathway. Neurotoxicity Research, 40(6), 2117–2131.
Yan, W., Zeng, Z., & Qin, F., et al. (2022). Effects of brucine on mitochondrial apoptosis and expression of HSP70 in prostate cancer cells. Translational Cancer Research, 11(3), 500–507.
doi: 10.21037/tcr-22-209 pubmed: 35402184 pmcid: 8990831
Liu, X., Yu, C., & Bi, Y., et al. (2019). Trends and age-period-cohort effect on incidence and mortality of prostate cancer from 1990 to 2017 in China. Public Health, 172, 70–80.
doi: 10.1016/j.puhe.2019.04.016 pubmed: 31220754
Shen, M. M., & Abate-Shen, C. (2010). Molecular genetics of prostate cancer: new prospects for old challenges. Genes and Development, 24(18), 1967–2000.
doi: 10.1101/gad.1965810 pubmed: 20844012 pmcid: 2939361
Huggins, C., & Hodges, C. V. (2002). Studies on prostatic cancer. I. The effect of castration, of estrogen and of androgen injection on serum phosphatases in metastatic carcinoma of the prostate. 1941. The Journal of Urology, 167(2 Pt 2), 948–51. discussion 952.
doi: 10.1016/S0022-5347(02)80307-X pubmed: 11905923
Chen, X., Overcash, R., & Green, T., et al. (2011). The tumor suppressor activity of the transmembrane protein with epidermal growth factor and two follistatin motifs 2 (TMEFF2) correlates with its ability to modulate sarcosine levels. Journal of Biological Chemistry, 286(18), 16091–100.
doi: 10.1074/jbc.M110.193805 pubmed: 21393249 pmcid: 3091218
Yang, Y., Li, P., & Li, X., et al. (2024). Brucine D restrains colorectal cancer tumorigenesis and autophagy by downregulating circ_0068464. Chemical Biology and Drug Design, 103(1), e14407.
doi: 10.1111/cbdd.14407 pubmed: 38040413
Li, M., Li, P., & Zhang, M., et al. (2018). Brucine suppresses breast cancer metastasis via inhibiting epithelial mesenchymal transition and matrix metalloproteinases expressions. Chinese Journal of Integrative Medicine, 24(1), 40–46.
doi: 10.1007/s11655-017-2805-1 pubmed: 28795388
Shu, G., Mi, X., & Cai, J., et al. (2013). Brucine, an alkaloid from seeds of Strychnos nux-vomica Linn., represses hepatocellular carcinoma cell migration and metastasis: the role of hypoxia inducible factor 1 pathway. Toxicology Letters, 222(2), 91–101.
doi: 10.1016/j.toxlet.2013.07.024 pubmed: 23933019
Seshadri, V. D. (2021). Brucine promotes apoptosis in cervical cancer cells (ME-180) via suppression of inflammation and cell proliferation by regulating PI3K/AKT/mTOR signaling pathway. Environmental Toxicology, 36(9), 1841–1847.
doi: 10.1002/tox.23304 pubmed: 34076332
Shi, X., Zhu, M., & Kang, Y., et al. (2018). Wnt/beta-catenin signaling pathway is involved in regulating the migration by an effective natural compound brucine in LoVo cells. Phytomedicine, 46, 85–92.
doi: 10.1016/j.phymed.2018.04.019 pubmed: 30097126
Matos, A., Carvalho, M., & Bicho, M., et al. (2021). Arginine and Arginases Modulate Metabolism, Tumor Microenvironment and Prostate Cancer Progression. Nutrients, 13(12), 4503.
doi: 10.3390/nu13124503 pubmed: 34960055 pmcid: 8704013
Gao, X., Locasale, J. W., & Reid, M. A. (2019). Serine and Methionine Metabolism: Vulnerabilities in Lethal Prostate Cancer. Cancer Cell, 35(3), 339–341.
doi: 10.1016/j.ccell.2019.02.014 pubmed: 30889375 pmcid: 6425948
Chen, L., Xu, Y. X., & Wang, Y. S., et al. (2023). Lipid metabolism, amino acid metabolism, and prostate cancer: a crucial metabolic journey. Asian Journal of Andrology, 26(2), 123–34.
doi: 10.4103/aja202363 pubmed: 38157428 pmcid: 10919422
Pal, S., Sharma, A., & Mathew, S. P., et al. (2022). Targeting cancer-specific metabolic pathways for developing novel cancer therapeutics. Frontiers in Immunology, 13, 955476.
doi: 10.3389/fimmu.2022.955476 pubmed: 36618350 pmcid: 9815821
Cavaliere, B., Macchione, B., & Monteleone, M., et al. (2011). Sarcosine as a marker in prostate cancer progression: a rapid and simple method for its quantification in human urine by solid-phase microextraction-gas chromatography-triple quadrupole mass spectrometry. Analytical and Bioanalytical Chemistry, 400(9), 2903–12.
doi: 10.1007/s00216-011-4960-0 pubmed: 21491110
Lasorsa, F., di Meo, N. A., & Rutigliano, M., et al. (2023). Emerging Hallmarks of Metabolic Reprogramming in Prostate Cancer. International Journal of Molecular Sciences, 24(2), 910.
doi: 10.3390/ijms24020910 pubmed: 36674430 pmcid: 9863674

Auteurs

Long Miao (L)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Yang Liu (Y)

Department of Hematology, The Affiliated Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Wei Chen (W)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Chao Gao (C)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Yijing Zhang (Y)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Jin Wei (J)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China.

Xiliang Cao (X)

Department of Urology, Xuzhou No. 1 People's Hospital, the Affiliated Xuzhou Municipal Hospital of Xuzhou Medical University, Xuzhou, 221004, PR China. caoxiliang1971@sina.com.

Classifications MeSH