Scalable multifunctional MOFs-textiles via diazonium chemistry.
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
21 Jun 2024
21 Jun 2024
Historique:
received:
03
08
2023
accepted:
13
06
2024
medline:
22
6
2024
pubmed:
22
6
2024
entrez:
21
6
2024
Statut:
epublish
Résumé
Cellulose fiber-based textiles are ubiquitous in daily life for their processability, biodegradability, and outstanding flexibility. Integrating cellulose textiles with functional coating materials can unlock their potential functionalities to engage diverse applications. Metal-organic frameworks (MOFs) are ideal candidate materials for such integration, thanks to their unique merits, such as large specific surface area, tunable pore size, and species diversity. However, achieving scalable fabrication of MOFs-textiles with high mechanical durability remains challenging. Here, we report a facile and scalable strategy for direct MOF growth on cotton fibers grafted via the diazonium chemistry. The as-prepared ZIF-67-Cotton textile (ZIF-67-CT) exhibits excellent ultraviolet (UV) resistance and organic contamination degradation via the peroxymonosulfate activation. The ZIF-67-CT is also used to encapsulate essential oils such as carvacrol to enable antibacterial activity against E. coli and S. aureus. Additionally, by directly tethering a hydrophobic molecular layer onto the MOF-coated surface, superhydrophobic ZIF-67-CT is achieved with excellent self-cleaning, antifouling, and oil-water separation performances. More importantly, the reported strategy is generic and applicable to other MOFs and cellulose fiber-based materials, and various large-scale multi-functional MOFs-textiles can be successfully manufactured, resulting in vast applications in wastewater purification, fragrance industry, and outdoor gears.
Identifiants
pubmed: 38906900
doi: 10.1038/s41467-024-49636-9
pii: 10.1038/s41467-024-49636-9
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
5297Subventions
Organisme : Ministry of Education - Singapore (MOE)
ID : MOE2019-T2-2-127, MOE-T2EP50120-0002, MOE-T2EP50123-0014 and RG62/22
Organisme : A*STAR | Singapore Institute of Manufacturing Technology (Singapore Institute of Manufacturing Technology - A STAR)
ID : A2083c0062, IAF-ICP Programme I2001E0067
Informations de copyright
© 2024. The Author(s).
Références
Masoomi, M. Y., Morsali, A., Dhakshinamoorthy, A. & Garcia, H. Mixed‐metal MOFs: unique opportunities in metal–organic framework (MOF) functionality and design. Angew. Chem. Int. Ed. 131, 15330–15347 (2019).
doi: 10.1002/ange.201902229
Kim, H. et al. Water harvesting from air with metal-organic frameworks powered by natural sunlight. Science 356, 430–434 (2017).
pubmed: 28408720
doi: 10.1126/science.aam8743
Liu, J. & Wöll, C. Surface-supported metal–organic framework thin films: fabrication methods, applications, and challenges. Chem. Soc. Rev. 46, 5730–5770 (2017).
pubmed: 28682401
doi: 10.1039/C7CS00315C
Hanikel, N., Prévot, M. S. & Yaghi, O. M. MOF water harvesters. Nat. Nanotechnol. 15, 348–355 (2020).
pubmed: 32367078
doi: 10.1038/s41565-020-0673-x
Zhang, K. et al. Extended metal–organic frameworks on diverse supports as electrode nanomaterials for electrochemical energy storage. ACS Appl. Nano Mater. 3, 3964–3990 (2020).
doi: 10.1021/acsanm.0c00702
Yang, Z. et al. ZIF-62 glass foam self-supported membranes to address CH
doi: 10.1038/s41563-023-01545-w
Peterson, G. W. et al. Fibre-based composites from the integration of metal–organic frameworks and polymers. Nat. Rev. Mater. 6, 605–621 (2021).
doi: 10.1038/s41578-021-00291-2
Ma, K. et al. Fiber composites of metal–organic frameworks. Chem. Mater. 32, 7120–7140 (2020).
doi: 10.1021/acs.chemmater.0c02379
Cheng, Y. et al. Advances in metal–organic framework-based membranes. Chem. Soc. Rev. 51, 8300–8350 (2022).
pubmed: 36070414
doi: 10.1039/D2CS00031H
Ma K. et al. Fibrous Zr‐MOF nanozyme aerogels with macro‐nanoporous structure for enhanced catalytic hydrolysis of organophosphate toxins. Adv. Mater. 36, 2300951 (2023).
Eagleton, A. M. et al. Fiber integrated metal‐organic frameworks as functional components in smart textiles. Angew. Chem. Int. Ed. 135, e202309078 (2023).
doi: 10.1002/ange.202309078
Zhuang, J. L. et al. Patterned deposition of metal‐organic frameworks onto plastic, paper, and textile substrates by inkjet printing of a precursor solution. Adv. Mater. 25, 4631–4635 (2013).
pubmed: 23813674
doi: 10.1002/adma.201301626
Lee, D. T., Jamir, J. D., Peterson, G. W. & Parsons, G. N. Protective fabrics: metal-organic framework textiles for rapid photocatalytic sulfur mustard simulant detoxification. Matter 2, 404–415 (2020).
doi: 10.1016/j.matt.2019.11.005
Zhang, B. et al. CelluMOFs: green, facile, and flexible metal‐organic frameworks for versatile applications. Adv. Funct. Mater. 31, 2105395 (2021).
doi: 10.1002/adfm.202105395
Smith, M. K. & Mirica, K. A. Self-organized frameworks on textiles (SOFT): conductive fabrics for simultaneous sensing, capture, and filtration of gases. J. Am. Chem. Soc. 139, 16759–16767 (2017).
pubmed: 29087700
doi: 10.1021/jacs.7b08840
Li W. et al. Multifunctional sandwich‐structured super‐hygroscopic zinc‐based MOF‐overlayed cooling wearables for special personal thermal management. Small 20, 2311272 (2024).
Qian, J. et al. Highly stable, antiviral, antibacterial cotton textiles via molecular engineering. Nat. Nanotechnol. 18, 168–176 (2023).
pubmed: 36585515
doi: 10.1038/s41565-022-01278-y
Fu C. et al. Sustainable polymer coating for stainproof fabrics. Nat. Sustain. 6, 984–994 (2023).
Cheng, Y. et al. A novel strategy for fabricating robust superhydrophobic fabrics by environmentally-friendly enzyme etching. Chem. Eng. J. 355, 290–298 (2019).
doi: 10.1016/j.cej.2018.08.113
Li W. et al. Environmentally-friendly foam-coating synthetic strategy for fabrics with robust superhydrophobicity, self-cleaning capability and flame retardance properties. Chem. Eng. J. 470, 144376 (2023).
Martin, C. et al. Graphite‐grafted silicon nanocomposite as a negative electrode for lithium‐ion batteries. Adv. Mater. 21, 4735–4741 (2009).
doi: 10.1002/adma.200900235
Mahouche-Chergui, S., Gam-Derouich, S., Mangeney, C. & Chehimi, M. M. Aryl diazonium salts: a new class of coupling agents for bonding polymers, biomacromolecules and nanoparticles to surfaces. Chem. Soc. Rev. 40, 4143–4166 (2011).
pubmed: 21479328
doi: 10.1039/c0cs00179a
Jiang, C. et al. Aryldiazonium salt derived mixed organic layers: from surface chemistry to their applications. J. Electroanal. Chem. 785, 265–278 (2017).
doi: 10.1016/j.jelechem.2016.11.043
Li, W., Wang, F. & Li, Z. A facile strategy for fabricating robust superhydrophobic and superoleophilic metal mesh via diazonium chemistry. Colloids Surf. A Physicochem. Eng. Asp. 630, 127570 (2021).
doi: 10.1016/j.colsurfa.2021.127570
Ryder, C. R. et al. Covalent functionalization and passivation of exfoliated black phosphorus via aryl diazonium chemistry. Nat. Chem. 8, 597–602 (2016).
pubmed: 27219705
doi: 10.1038/nchem.2505
Jiang, D.-e, Sumpter, B. G. & Dai, S. Structure and bonding between an aryl group and metal surfaces. J. Am. Chem. Soc. 128, 6030–6031 (2006).
pubmed: 16669660
doi: 10.1021/ja061439f
Ma, K. et al. Scalable and template-free aqueous synthesis of zirconium-based metal–organic framework coating on textile fiber. J. Am. Chem. Soc. 141, 15626–15633 (2019).
pubmed: 31532665
doi: 10.1021/jacs.9b07301
Zhao, J. et al. Ultra‐fast degradation of chemical warfare agents using MOF–nanofiber kebabs. Angew. Chem. Int. Ed. 128, 13418–13422 (2016).
doi: 10.1002/ange.201606656
Chen, Z. et al. Integration of metal–organic frameworks on protective layers for destruction of nerve agents under relevant conditions. J. Am. Chem. Soc. 141, 20016–20021 (2019).
pubmed: 31833359
doi: 10.1021/jacs.9b11172
Zhang, L. et al. Fabrication of 2D metal–organic framework nanosheet@fiber composites by spray technique. Chem. Commun. 55, 8293–8296 (2019).
doi: 10.1039/C9CC02614B
Eagleton, A. M. et al. Fabrication of multifunctional electronic textiles using oxidative restructuring of copper into a Cu-based metal–organic framework. J. Am. Chem. Soc. 144, 23297–23312 (2022).
pubmed: 36512516
pmcid: 9801431
doi: 10.1021/jacs.2c05510
Zhang, Y. et al. Preparation of nanofibrous metal–organic framework filters for efficient air pollution control. J. Am. Chem. Soc. 138, 5785–5788 (2016).
pubmed: 27090776
doi: 10.1021/jacs.6b02553
Chen, Y. et al. A solvent‐free hot‐pressing method for preparing metal–organic‐framework coatings. Angew. Chem. Int. Ed. 55, 3419–3423 (2016).
doi: 10.1002/anie.201511063
Li, C. et al. High-performance quasi-solid-state flexible aqueous rechargeable Ag–Zn battery based on metal–organic framework-derived Ag nanowires. ACS Energy Lett. 3, 2761–2768 (2018).
doi: 10.1021/acsenergylett.8b01675
Wang, S. et al. Soft nanobrush-directed multifunctional MOF nanoarrays. Nat. Commun. 13, 6673 (2022).
pubmed: 36335188
pmcid: 9637124
doi: 10.1038/s41467-022-34512-1
Zhang, S. et al. Facile in situ synthesis of ZIF-67/cellulose hybrid membrane for activating peroxymonosulfate to degrade organic contaminants. Cellulose 28, 3585–3598 (2021).
doi: 10.1007/s10570-021-03717-w
Qiao, X. et al. Preparation of zeolitic imidazolate framework-67/wool fabric and its adsorption capacity for reactive dyes. J. Environ. Manag. 321, 115972 (2022).
doi: 10.1016/j.jenvman.2022.115972
Li, W. et al. In situ growth of a stable metal–organic framework (MOF) on flexible fabric via a layer-by-layer strategy for versatile applications. ACS Nano 16, 14779–14791 (2022).
pubmed: 36103395
doi: 10.1021/acsnano.2c05624
Hu, Z. et al. Construction of anti-ultraviolet “shielding clothes” on poly (p-phenylene benzobisoxazole) fibers: metal organic framework-mediated absorption strategy. ACS Appl. Mater. Interfaces 10, 43262–43274 (2018).
pubmed: 30379514
doi: 10.1021/acsami.8b16845
Zhao, J. et al. Conformal and highly adsorptive metal–organic framework thin films via layer-by-layer growth on ALD-coated fiber mats. J. Mater. Chem. A 3, 1458–1464 (2015).
doi: 10.1039/C4TA05501B
Saliba, D. et al. Crystal growth of ZIF-8, ZIF-67, and their mixed-metal derivatives. J. Am. Chem. Soc. 140, 1812–1823 (2018).
pubmed: 29302958
doi: 10.1021/jacs.7b11589
Ma, K. et al. Protection against chemical warfare agents and biological threats using metal–organic frameworks as active layers. Acc. Mater. Res. 4, 168–179 (2023).
doi: 10.1021/accountsmr.2c00200
Li, W. et al. A facile strategy to prepare robust self-healable superhydrophobic fabrics with self-cleaning, anti-icing, UV resistance, and antibacterial properties. Chem. Eng. J. 446, 137195 (2022).
doi: 10.1016/j.cej.2022.137195
Lu, Y. et al. Recent advances in metal organic framework and cellulose nanomaterial composites. Coord. Chem. Rev. 461, 214496 (2022).
doi: 10.1016/j.ccr.2022.214496
Zhang, Z. et al. Daylight-induced antibacterial and antiviral nanofibrous membranes containing vitamin K derivatives for personal protective equipment. ACS Appl. Mater. Interfaces 12, 49416–49430 (2020).
pubmed: 33089989
doi: 10.1021/acsami.0c14883
Wiyantoko, B., Rusitasari, R. & Putri, R. N. Study of hydrolysis process from pineapple leaf fibers using sulfuric acid, nitric acid, and bentonite catalysts. Bull. Chem. React. Eng. Catal. 16, 571–580 (2021).
doi: 10.9767/bcrec.16.3.10281.571-580
Mia, R. et al. Review on various types of pollution problem in textile dyeing & printing industries of Bangladesh and recommandation for mitigation. J. Tex. Eng. Fash. Technol. 5, 220–226 (2019).
Che, Y., Li, W., Wu, W. & Li, Z. Preparation of fluorine-free robust superhydrophobic fabric via diazonium radical graft polymerization. Prog. Org. Coat. 183, 107721 (2023).
doi: 10.1016/j.porgcoat.2023.107721