Citrullus colocynthis fruit extract as effective eco-friendly corrosion inhibitor in a hydrochloric acid pickling medium for carbon steel by using both experimental and theoretical studies.
AC impedance
Acid medium
C-S substrate
DFT/MD
Gravimetry
Organic corrosion inhibitor
Potentiodynamic polarization
XPS
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
22 Jun 2024
22 Jun 2024
Historique:
received:
18
03
2024
accepted:
17
06
2024
medline:
22
6
2024
pubmed:
22
6
2024
entrez:
22
6
2024
Statut:
aheadofprint
Résumé
The present study focuses on an environmental approach based on the use of an eco-friendly corrosion inhibitor from the Citrullus colocynthis fruit extract for enhancement corrosion resistance of carbon steel (C-S) in acid medium as an alternative to various organic and non-organic chemical inhibitors. The evaluation of the inhibition properties of the fruit methanolic extract of Citrullus colocynthis (CCE) were performed in molar hydrochloric acid (1 M HCl) medium using gravimetric and electrochemical (potentiodynamic polarization and AC impedance) techniques as well as surface analyses. CCE is rich in amino acids, mainly citrulline and β-(pyrazo-1-yl)-L-analine molecules. Based on the weight loss evaluation, the results demonstrated that this plant extract acts as an effective corrosion inhibitor and a protection level of 93.6% was attained at 500 ppm of CCE after 6 h of metal exposure at 303 K. According to polarization curves, CCE functions as a mixed-type inhibitor. In addition, AC impedance analyses have shown that the incorporation of CCE into the corrosive solution leads to a decrease in load capacity, while improving the charge/discharge function at the interface. This suggests the possibility of the formation of an adsorbed layer on the C-S surface. In addition, scanning electron microscope (SEM) observation, contact angle measurements, and Fourier-transform infrared spectroscopy (FTIR) analyses supported the development of a protective film over CS substrate surface afterwards addition of CCE. Langmuir and/or Temkin isotherms can be used to characterize the adsorption of this organic inhibitor on the C-S surface. X-ray photoelectron spectroscopy (XPS) has revealed that the inhibiting effect of CCE on the corrosion of C-S in 1 M HCl solution is mainly controlled by a chemisorption process and the inhibitive layer is composed of an iron oxide/hydroxide mixture where CCE molecules are incorporated. In order to understand the relationship between the molecular structure and anti-corrosion effectiveness of these inhibitor molecules, quantum chemical studies were carried out using density functional theory (DFT) and molecular dynamics (MD) simulation.
Identifiants
pubmed: 38907820
doi: 10.1007/s11356-024-34055-6
pii: 10.1007/s11356-024-34055-6
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Informations de copyright
© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
Références
Abd El-Lateef HM, Abo-Riya MA, Tantawy AH (2016) Empirical and quantum chemical studies on the corrosion inhibition performance of some novel synthesized cationic Gemini surfactants on carbon steel pipelines in acid pickling. Corros Sci 108:94–110. https://doi.org/10.1016/j.corsci.2016.03.004
doi: 10.1016/j.corsci.2016.03.004
Abdel-Gaber AM, Khamis E, Abo-ELDahab H, Adeel Sh (2008) Inhibition of aluminium corrosion in alkaline solutions using natural compound. Mater Chem Phys 109(2–3):297–305. https://doi.org/10.1016/j.matchemphys.2007.11.038
doi: 10.1016/j.matchemphys.2007.11.038
Abdel-Gaber AM, Abd-El-Nabey BA, Saadawy M (2009) The role of acid anion on the inhibition of the acidic corrosion of steel by lupine extract. Corros Sci 51(5):1038–1042. https://doi.org/10.1016/j.corsci.2009.03.003
doi: 10.1016/j.corsci.2009.03.003
Ahamad I, Prasad R, Quraishi MA (2010) Inhibition of mild steel corrosion in acid solution by Pheniramine drug: experimental and theoretical study. Corros Sci 52(9):3033–3041. https://doi.org/10.1016/j.corsci.2010.05.022
doi: 10.1016/j.corsci.2010.05.022
Al-Dokheily ME, Kredy HM, Al-Jabery RN (2014) Inhibition of copper corrosion in H
Al‑sharabi HA, Bouiti K, Bouhlal F, Labjar N, Dahrouch A, El Mahi M, Lotfi EM, El Otmani B, Amine Benabdellah G, El Hajjaji (2022) Citrullus colocynthis ethanolic extract as an ecological inhibitor of carbon steel C38 corrosion in hydrochloric medium. J Bio Tribo Corros 8:78. https://doi.org/10.1007/s40735-022-00675-z
doi: 10.1007/s40735-022-00675-z
Andersen HC (1980) Molecular dynamics simulations at constant pressure and/or temperature. J Chem Phys 72(4):2384–2393. https://doi.org/10.1063/1.439486
doi: 10.1063/1.439486
ASTM (1990) G31–72, American Society for Testing and Materials, Philadelphia, PA
Behpour M, Ghoreishi SM, Khayatkashani M, Soltani N (2011) The effect of two oleo-gum resin exudate from Ferula assa-foetida and Dorema ammoniacum on mild steel corrosion in acidic media. Corros Sci 53(8):2489–2501. https://doi.org/10.1016/j.corsci.2011.04.005
doi: 10.1016/j.corsci.2011.04.005
Benhiba F, ELaoufir Y, Belayachi M, Zarrok H, El Assyry A, Zarrouk A, Hammouti B, Ebenso EE, Guenbour A, Al Deyab SS, Oudda H (2014) Theoretical and experimental studies on the inhibition of 1,1′-(2-phenylquinoxaline-1,4-diyl)diethanone for the corrosion of carbon steel in 1.0 M HCl. Der Pharm Lett 6(4):306–318
Benhiba F, Hsissou R, Benzekri Z, Belghiti ME, Lamhamdi A, Bellaouchou A, Guenbour A, Boukhris S, Oudda H, Warad I, Zarrouk A (2020) Nitro substituent effect on the electronic behavior and inhibitory performance of two quinoxaline derivatives in relation to the corrosion of mild steel in 1M HCl. J Mol Liq 312:113367. https://doi.org/10.1016/j.molliq.2020.113367
doi: 10.1016/j.molliq.2020.113367
Bentiss F, Outirite M, Traisnel M, Vezin H, Lagrenée M, Hammouti B, Al-Deyab SS, Jama C (2012) Improvement of corrosion resistance of carbon steel in hydrochloric acid medium by 3,6-bis(3-pyridyl)pyridazine. Int J Electrochem Sci 7:1699–1721
doi: 10.1016/S1452-3981(23)13446-8
Berrissoul A, Ouarhach A, Benhiba F, Romane A, Zarrouk A, Guenbour A, Dikici B, Dafali A (2020a) Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1M HCl solution. Experimental and theoretical approach. J Mol Liq 313:113493. https://doi.org/10.1016/j.molliq.2020.113493
doi: 10.1016/j.molliq.2020.113493
Berrissoul A, Loukili E, Mechbal N, Benhiba F, Guenbour A, Dikici B, Zarrouk A, Dafali A (2020b) Anticorrosion effect of a green sustainable inhibitor on mild steel in hydrochloric acid. J Colloid Interface Sci 580:740–752. https://doi.org/10.1016/j.jcis.2020.07.073
doi: 10.1016/j.jcis.2020.07.073
Bhasin A, Singh S, Garg R (2020) Nutritional and medical importance of Citrullus colocynthis-a review. Plant Arch 20:3400–3406
Bouanis FZ, Bentiss F, Bellayer S, Traisnel M, Vogt JB, Jama C (2011) Radiofrequency cold plasma nitrided carbon steel: microstructural and micromechanical characterizations. Mater Chem Phys 127(1–2):329–334. https://doi.org/10.1016/j.matchemphys.2011.02.013
doi: 10.1016/j.matchemphys.2011.02.013
Bouanis M, Tourabi M, Nyassi A, Zarrouk A, Jama C, Bentiss F (2016) Corrosion inhibition performance of 2,5-bis(4-dimethylaminophenyl)-1,3,4-oxadiazole for carbon steel in HCl solution: Gravimetric, electrochemical and XPS studies. Appl Surf Sci 389:952–966. https://doi.org/10.1016/j.apsusc.2016.07.115
doi: 10.1016/j.apsusc.2016.07.115
Boumhara K, Tabyaoui M, Jama C, Bentiss F (2015) Artemisia Mesatlantica essential oil as green inhibitor for carbon steel corrosion in 1 M HCl solution: electrochemical and XPS investigations. J Indus Eng Chem 29:146–155. https://doi.org/10.1016/j.jiec.2015.03.028
doi: 10.1016/j.jiec.2015.03.028
Bouoidina A, El-hajjaji F, Emran Kh, Belghiti M, Elalaoui A, Elmelouky A, Taleb M, Abdellaoui A, Abdellaoui A, Hammouti B, Obot IB (2019) Towards understanding the anticorrosive mechanism of novel surfactant based on Mentha pulegium oil as eco-friendly bio-source of mild steel in acid medium: a combined DFT and molecular dynamics investigation. Chem Res Chin Univ 35(1):85–100. https://doi.org/10.1007/s40242-019-8205-7
doi: 10.1007/s40242-019-8205-7
Bouyanzer A, Hammouti B, Majidi L (2006) Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1M HCl. Mater Lett 60(23):2840–2843. https://doi.org/10.1016/j.matlet.2006.01.103
doi: 10.1016/j.matlet.2006.01.103
Briggs D, Seah MP (1990) Practical surface analysis by Auger and X-ray photoelectron spectroscopy, 2nd edn. John Wiley & Sons Ltd, Chichester
Catauro M, Papale F, Bollino F, Piccolella S, Marciano S, Nocera P, Pacifico S (2015) Silica/quercetin sol–gel hybrids as antioxidant dental implant materials. Sci Technol Adv Mater 16(3):035001. https://doi.org/10.1088/1468-6996/16/3/035001
doi: 10.1088/1468-6996/16/3/035001
Chevalier M, Robert F, Amusant N, Traisnel M, Roos C, Lebrini M (2014) Enhanced corrosion resistance of mild steel in 1 M hydrochloric acid solution by alkaloids extract from Aniba rosaeodora plant: Electrochemical, phytochemical and XPS studies. Electrochim Acta 131:96–105. https://doi.org/10.1016/j.electacta.2013.12.023
doi: 10.1016/j.electacta.2013.12.023
da Rocha JC, da Cunha Ponciano Gomes JA, D’Elia E (2010) Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts. Corros Sci 52(7):2341–2348. https://doi.org/10.1016/j.corsci.2010.03.033
doi: 10.1016/j.corsci.2010.03.033
Doumane G, Jaouad Bensalah J, Hmada A, Iraqi O, Boussalem O, Mhanni D, Rifi EH, Safi ZS, Zarrouk A, Dkhireche N, Habsaoui A (2023) Corrosion inhibition performance of Citrullus colocynthis seed oil extract as a mild steel in 1.0 M HCl acid using various solvants such as petroleum ether (CSOP) and cyclohexan (CSOC) polymerics. Inorg Chem Commun 155:111042. https://doi.org/10.1016/j.inoche.2023.111042
doi: 10.1016/j.inoche.2023.111042
Eddy NO, Odoemelam SA, Odiongenyi AO (2009) Joint effect of halides and ethanol extract of Lasianthera africana on inhibition of corrosion of mild steel in H
doi: 10.1007/s10800-008-9731-z
Eidi S, Ghodrati Azadi H, Rahbar N, Mehmannavazc HR (2015) Evaluation of antifungal activity of hydroalcoholic extracts of Citrullus colocynthis fruit. J Herb Med 5(1):36–40. https://doi.org/10.1016/j.hermed.2015.01.003
doi: 10.1016/j.hermed.2015.01.003
Belghiti M, Karzazi Y, Dafali A, Hammouti B, Bentiss F, Obot IB, Bahadur I, Ebenso EE (2016) Experimental, quantum chemical and Monte Carlo simulation studies of 3,5-disubstituted-4-amino-1,2,4-triazoles as corrosion inhibitors on mild steel in acidic medium. J Mol Liq 218:281–293. https://doi.org/10.1016/j.molliq.2016.01.076
doi: 10.1016/j.molliq.2016.01.076
El Bribri A, Tabyaoui M, Tabyaoui B, El Attari H, Bentiss F (2013) the use Euphorbia falcata extract as eco-friendly corrosion inhibitor of carbon steel in hydrochloric acid solution. Mat Chem Phys 141:240–247. https://doi.org/10.1016/j.matchemphys.2013.05.006
doi: 10.1016/j.matchemphys.2013.05.006
El Hamdani N, Fdil R, Tourabi M, Jama C, Bentiss F (2015) Alkaloids extract of Retama monosperma (L) Boiss. seeds used as novel eco-friendly inhibitor for carbon steel corrosion in 1 M HCl solution: Electrochemical and surface studies. App Surf Sci 357:1294–1305. https://doi.org/10.1016/j.apsusc.2015.09.159
doi: 10.1016/j.apsusc.2015.09.159
El yaktini A, Lachiri A, El Faydy M, Benhiba F, Zarrok H, El Azzouzi M, Zertoubi M, Azzi M, Lakhrissi B, Zarrouk A (2018) Practical and theoretical study on the inhibitory influences of new azomethine derivatives containing 8-hydroxyquinoline moiety for the corrosion of carbon steel in 1 M HCl. Orient J Chem 34(6):3016–3029. https://doi.org/10.13005/ojc/340643
doi: 10.13005/ojc/340643
Elayyachy M, El Idrissi A, Hammouti B (2006) New thio-compounds as corrosion inhibitor for steel in 1M HCl. Corros Sci 48:2470–2479. https://doi.org/10.1016/j.corsci.2005.09.016
doi: 10.1016/j.corsci.2005.09.016
El-Etre AY (2007) Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves. J Colloid Interface Sci 314(2):578–583. https://doi.org/10.1016/j.jcis.2007.05.077
doi: 10.1016/j.jcis.2007.05.077
EL-Hajjaji F, Ech-chihbi E, Rezki N, Benhiba F, Taleb M, Dheeraj Singh Chauhan, Quraishi MA (2020) Electrochemical and theoretical insights on the adsorption and corrosion inhibition of novel pyridinium-derived ionic liquids for mild steel in 1 M HCl. J Mol Liq 314:113737. https://doi.org/10.1016/j.molliq.2020.113737
doi: 10.1016/j.molliq.2020.113737
Faustin M, Lebrini M, Robert F, Roos C (2011) Corrosion studies of C38 steel by alkaloids extract of a tropical plant type. Int J Electrochem Sci 6(9):4095–4113
doi: 10.1016/S1452-3981(23)18313-1
Faustin M, Maciuk A, Salvin P, Roos C, Lebrini M (2015) Corrosion inhibition of C38 steel by alkaloids extract of Geissospermum leave in 1 M hydrochloric acid: electrochemical and phytochemical studies. Corros Sci 92:287–300. https://doi.org/10.1016/j.corsci.2014.12.005
doi: 10.1016/j.corsci.2014.12.005
Fergachi O, Benhiba F, Rbaa M, Touir R, Ouakki M, Galai M, Lakhrissi B, Oudda H, Ebn Touhami M (2018) Experimental and theoretical study of corrosion inhibition of mild steel in 1.0 M HCl medium by 2(-4(hloro phenyl-1H-benzo[d]imidazol)-1-yl)phenyl)methanone. J Mater Res 21(6). https://doi.org/10.1590/1980-5373-mr-2017-1038
Ferreira ES, Giacomelli C, Giconelli FC, Spinelli A (2004) Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel. Mat Chem Phy 83:129–134. https://doi.org/10.1016/j.matchemphys.2003.09.020
doi: 10.1016/j.matchemphys.2003.09.020
Fiori-Bimbi MV, Alvarez PE, Vaca H, Gervasi CA (2015) Corrosion inhibition of mild steel in HCl solution by pectin. Corros Sci 92:192–199. https://doi.org/10.1016/j.corsci.2014.12.002
doi: 10.1016/j.corsci.2014.12.002
Fouda AS, Etaiw SH, Elnggar W (2014) Punica plant extract as green corrosion inhibitor for C-steel in hydrochloric acid solutions. Int J Electrochem Sci 9(9):4866–4883. https://doi.org/10.1016/S1452-3981(23)08138-5
doi: 10.1016/S1452-3981(23)08138-5
Galtayries A, Warocquier-Clérout R, Nagel MD, Marcus P (2006) Fibronectin adsorption on Fe-Cr alloy studied by XPS. Surf Interface Anal 38(4):186–190. https://doi.org/10.1002/sia.2295
doi: 10.1002/sia.2295
Hassan HH, Abdelghani E, Amin MA (2007) Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives part I. Polarization and EIS studies. Electrochim Acta 52(22):6359–6366. https://doi.org/10.1016/j.electacta.2007.04.046
doi: 10.1016/j.electacta.2007.04.046
Hussain AI, Rathore HA, Sattar MZ, Chatha SA, Sarker SD, Gilani AH (2014) Citrullus colocynthis (L.) Schrad (bitter apple fruit): a review of its phytochemistry, pharmacology, traditional uses and nutritional potential. J Ethnopharmacol 155:54–66. https://doi.org/10.1016/j.jep.2014.06.011
doi: 10.1016/j.jep.2014.06.011
ji G, Shukla SK, Dwivedi P, Sundaram S, Prakash R (2011) Inhibitive effect of Argemone mexicana plant extract on acid corrosion of mild steel. Ind Eng Chem Res 50(21):11954–11959. https://doi.org/10.1021/ie201450d
doi: 10.1021/ie201450d
Kannan P, Karthikeyan J, Murugan P, Rao TS, Rajendran N (2016) Corrosion inhibition effect of novel methyl benzimidazolium ionic liquid for carbon steel in HCl medium. J Mol Liq 221:368–380. https://doi.org/10.1016/j.molliq.2016.04.130
doi: 10.1016/j.molliq.2016.04.130
Kelemen SR, Afeworki M, Gorbaty ML, Cohen AD (2002) Characterization of organically bound oxygen forms in lignites, peats, and pyrolyzed peats by X-ray photoelectron spectroscopy (XPS) and solid-state
doi: 10.1021/ef020050k
Khaled K (2003) The inhibition of benzimidazole derivatives on corrosion of iron in 1 M HCl solutions. Electrochim Acta 48(17):2493–2503. https://doi.org/10.1016/S0013-4686(03)00291-3
doi: 10.1016/S0013-4686(03)00291-3
Khan UN, Inayat A, Shah GMb, Hassan MA, Hassan HMA, Zaki MEA, Abdulaziz A, Alanazi AA, El-Zahhar AA, Noureen S, Abbas SM (2022) Green synthesis of magnesium oxide nanosheets by using Citrullus colocynthis fruit extract and its use in biofuel production. Biomass Bioenergy 167:106640. https://doi.org/10.1016/j.biombioe.2022.106640
doi: 10.1016/j.biombioe.2022.106640
Kharbach Y, Qachchachi FZ, Haoudi A, Tourabi M, Zarrouk A, Jama C, Olasunkanmi LO, Ebenso EE, Bentiss F (2017) Anticorrosion performance of three newly synthesized isatin derivatives on carbon steel in hydrochloric acid pickling environment: electrochemical, surface and theoretical studies. J Mol Liq 246:302–316. https://doi.org/10.1016/j.molliq.2017.09.057
doi: 10.1016/j.molliq.2017.09.057
Khatri S, Faizi S, Fayyaz S, Iqbal E (2021) Citrullus colocynthis: a treasure of phytochemical, pharmacological, pesticidal and nematicidal compounds. Pakistan J Nematol 39:122–150. https://doi.org/10.17582/journal.pjn/2021.39.2.122.150
doi: 10.17582/journal.pjn/2021.39.2.122.150
Kumar S, Kumar D, Saroha K, Singh N, Vashishta B (2008) Antioxidant and free radical scavenging potential of Citrullus colocynthis (L.) Schrad. methanolic fruit extract. Acta Pharm 58:215–220. https://doi.org/10.2478/v10007-008-0008-1
doi: 10.2478/v10007-008-0008-1
Laabaissi T, Benhiba F, Rouifi Z, Rbaa M, Oudda H, Zarrok H, Lakhrissi B, Guenbour A, Warad I, Zarrouk A (2019) Benzodiazepine derivatives as corrosion inhibitors of carbon steel in HCl media: electrochemical and theoretical studies. Prot Met Phys Chem Surf 55(5):986–1000. https://doi.org/10.1134/S2070205119050149
doi: 10.1134/S2070205119050149
Lagrenée M, Mernari B, Bouanis M, Taisnel M, Bentiss F (2002) Study of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4h-1,2,4-triazole on mild steel corrosion in acidic media. Corros Sci 44:573–588. https://doi.org/10.1016/S0010-938X(01)00075-0
doi: 10.1016/S0010-938X(01)00075-0
Lebrini M, Lagrenée M, Traisnel M, Gengembre L, Vezin H, Bentiss F (2007) Enhanced corrosion resistance of mild steel in normal sulfuric acid medium by 2,5-bis(n-thienyl)-1,3,4-thiadiazoles: electrochemical, X-ray photoelectron spectroscopy and theoretical studies. Appl Surf Sci 253(23):9267–9276. https://doi.org/10.1016/j.apsusc.2007.05.062
doi: 10.1016/j.apsusc.2007.05.062
Lebrini M, Bentiss F, Chihib NE, Jama C, Hornez JP, Lagrenée M (2008) Polyphosphate derivatives of guanidine and urea copolymer: inhibiting corrosion effect of armco iron in acid solution and antibacterial activity. Corros Sci 50:2914–2918. https://doi.org/10.1016/j.corsci.2008.07.003
doi: 10.1016/j.corsci.2008.07.003
Lebrini M, Robert F, Lecante A, Roos C (2011a) Corrosion inhibition of C38 steel in 1M hydrochloric acid medium by alkaloids extract from Oxandra asbeckii plant. Corros Sci 53(2):687–695. https://doi.org/10.1016/j.corsci.2010.10.006
doi: 10.1016/j.corsci.2010.10.006
Lebrini M, Robert F, Roos C (2011b) Alkaloids extract from Palicourea guianensis plant as corrosion inhibitor for C38 Steel in 1 M hydrochloric acid medium. Int J Electrochem Sci 6:847–859
doi: 10.1016/S1452-3981(23)15039-5
Li L, Zhang X, Lei J, He J, Zhang S, Pan F (2012) Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel. Corros Sci 63:82–90. https://doi.org/10.1016/j.corsci.2012.05.026
doi: 10.1016/j.corsci.2012.05.026
Li QY, Munawar M, Saeed M, Shen J-Q, Khan MS, Noreen S, Alagawany M, Naveed M, Madni A, Li CX (2022) Citrullus colocynthis (L.) Schrad (bitter apple fruit): promising traditional uses, pharmacological effects, aspects, and potential applications. Front Pharmacol 12:791049. https://doi.org/10.3389/fphar.2021.791049
doi: 10.3389/fphar.2021.791049
Lieth HM, Al-Sabu R, Jassim RJ, Alsahlani A (2021) Enhancement of corrosion resistance and mechanical properties of API 5L X60 steel by heat treatments in different environments. J Eng Res 9(4B):428–440. https://doi.org/10.36909/jer.14591
doi: 10.36909/jer.14591
Lieth HM, Jabbar MA, Jassim RJ, Al-Sabur R (2023) Optimize the corrosion behavior of AISI 204Cu stainless steel in different environments under previous cold working and welding. Metall Res Technol 120(4):415. https://doi.org/10.1051/metal/2023058
doi: 10.1051/metal/2023058
Lopez GP, Castner DG, Ratner BD (1991) XPS O 1s binding energies for polymers containing hydroxyl, ether, ketone and ester groups. Surf Interf Anal 17(5):267–272. https://doi.org/10.1002/sia.740170508
doi: 10.1002/sia.740170508
Maciej Heneczkowski MK, Nowak D, Kuzniar A (2001) Infrared spectrum analysis of some flavonoids. Acta Polon Pharm Drug Res 58:415–420
Martinez S, Metikos-Hukovic M (2003) A nonlinear kinetic model introduced for the corrosion inhibitive properties of some organic inhibitors. J Appl Electrochem 33:1137–1142
doi: 10.1023/B:JACH.0000003851.82985.5e
Materials Studio (2016) Revision 8.0, Accelrys Inc., San Diego, USA
McCafferty E (2005) Validation of corrosion rates measured by the Tafel extrapolation method. Corros Sci 47(12):3202–3215. https://doi.org/10.1016/j.corsci.2005.05.046
doi: 10.1016/j.corsci.2005.05.046
Miralrio A, Vázquez AE (2020) Plant extracts as green corrosion inhibitors for different metal surfaces and corrosive media: A review. Processes 8(8):942. https://doi.org/10.3390/pr8080942
doi: 10.3390/pr8080942
Moulder F, Stickle WF, Sobol PE, Bomben KD (1992). In: Chastain J (ed) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corp, Minnesota
Mourya P, Singh P, Tewari AK, Rastogi RB, Singh MM (2015) Relationship between structure and inhibition behavior of quinolinium salts for mild steel corrosion: experimental and theoretical approach. Corros Sci 95:71–87. https://doi.org/10.1016/j.corsci.2015.02.034
doi: 10.1016/j.corsci.2015.02.034
Murmu M, Saha SK, Murmu NC, Banerjee P (2019) Effect of stereochemical conformation into the corrosion inhibitive behaviour of double azomethine based Schiff bases on mild steel surface in 1 mol L−1 HCl medium: an experimental, density functional theory and molecular dynamics simulation study. Corros Sci 146:134–151. https://doi.org/10.1016/j.corsci.2018.10.002
doi: 10.1016/j.corsci.2018.10.002
Nabah R, Benhiba F, Ramli Y, Ouakki M, Cherkaoui M, Oudda H, Touir R, Warad I, Zarrouk (2018) Corrosion inhibition study of 5, 5-diphenylimidazolidine2, 4-dione for mild steel corrosion in 1 M HCl solution: experimental, theoretical computational and Monte Carlo simulations studies. Anal Bioanal Electrochem 10(10):1375–1398
Nadi I, Bouanis M, Benhiba F, Nohair K, Nyassi A, Zarrouk A, Jama C, Bentiss F (2021) Insights into the inhibition mechanism of 2,5-bis(4-pyridyl)-1,3,4-oxadiazole for carbon steel corrosion in hydrochloric acid pickling via experimental and computational approaches. J Mol Liq 342:116958. https://doi.org/10.1016/j.molliq.2021.116958
doi: 10.1016/j.molliq.2021.116958
Obot IB, Obi-Egbedi NO (2010) Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation. Corros Sci 52:198–204. https://doi.org/10.1016/j.corsci.2009.09.002
doi: 10.1016/j.corsci.2009.09.002
Obot IB, Haruna K, Saleh TA (2019) Atomistic simulation: a unique and powerful computational tool for corrosion inhibition research. Arab J Sci Eng 44(1):1–32. https://doi.org/10.1007/s13369-018-3605-4
doi: 10.1007/s13369-018-3605-4
Oguzie EE (2006) Studies on the inhibitive effect of Occimum viridis extract on the acid corrosion of mild steel. Mater Chem Phys 99(2–3):441–446. https://doi.org/10.1016/j.matchemphys.2005.11.018
doi: 10.1016/j.matchemphys.2005.11.018
Oguzie EE (2008) Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel. Corros Sci 50(11):2993–2998. https://doi.org/10.1016/j.corsci.2008.08.004
doi: 10.1016/j.corsci.2008.08.004
Oguzie EE, Enenebeaku CK, Akalezi CO, Okoro SC, Ayuk AA, Ejike EN (2010) Adsorption and corrosion-inhibiting effect of Dacryodis edulis extract on low-carbon-steel corrosion in acidic media. J Colloid Interface Sci 349(1):283–292. https://doi.org/10.1016/j.jcis.2010.05.027
doi: 10.1016/j.jcis.2010.05.027
Okafor PC, Ikpi ME, Uwah IE, Ebenso EE, Ekpe UJ, Umoren SA (2008) Inhibitory action of Phyllanthus amarus extracts on the corrosion of mild steel in acidic media. Corros Sci 50(8):2310–2317
doi: 10.1016/j.corsci.2008.05.009
Olasunkanmi LO, Obot IB, Kabanda MM, Ebenso EE (2015) Some quinoxalin-6-yl derivatives as corrosion inhibitors for mild steel in hydrochloric acid: experimental and theoretical studies. J Phys Chem C 119:16004–16019. https://doi.org/10.1021/acs.jpcc.5b03285
doi: 10.1021/acs.jpcc.5b03285
Olasunkanmi LO, Obot IB, Ebenso EE (2016) Adsorption and corrosion inhibition properties of: N-{n-[1-R-5-(quinoxalin-6-yl)-4,5-dihydropyrazol-3-yl]phenyl}methanesulfonamides on mild steel in 1 M HCl: experimental and theoretical studies. RSC Adv 6(90):86782–86797. https://doi.org/10.1016/j.corsci.2008.05.009
doi: 10.1016/j.corsci.2008.05.009
Olivares O, Likhanova NV, Gómez B, Navarrete J, Llanos-Serrano ME, Arce E, Hallen JM (2006) Electrochemical and XPS studies of decylamides of α-amino acids adsorption on carbon steel in acidic environment. Appl Surf Sci 252(8):2894–3290. https://doi.org/10.1016/j.apsusc.2005.04.040
doi: 10.1016/j.apsusc.2005.04.040
Ostovari A, Hoseinieh SM, Peikari M, Shadizadeh SR, Hashemi SJ (2009) Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: a comparative study of the inhibition by henna and its constituents (lawsone, gallic acid, α-d-glucose and tannic acid). Corros Sci 51:1935–1949. https://doi.org/10.1016/j.corsci.2009.05.024
doi: 10.1016/j.corsci.2009.05.024
Outirite M, Lagrenée M, Lebrini M, Traisnel M, Jama C, Vezin H, Bentiss F (2010) ac impedance, X-ray photoelectron spectroscopy and density functional theory studies of 3,5-bis(n-pyridyl)-1,2,4-oxadiazoles as efficient corrosion inhibitors for carbon steel surface in hydrochloric acid solution. Electrochim Acta 55(5):1670–1681. https://doi.org/10.1016/j.electacta.2009.10.048
doi: 10.1016/j.electacta.2009.10.048
Popova A, Christov M (2006) Evaluation of impedance measurements on mild steel corrosion in acid media in the presence of heterocyclic compounds. Corros Sci 48(10):3208–3221. https://doi.org/10.1016/j.corsci.2005.11.001
doi: 10.1016/j.corsci.2005.11.001
Popova A, Christov M, Vasilev A (2007) Inhibitive properties of quaternary ammonium bromides of N-containing heterocycles on acid mild steel corrosion. Part II: EIS results. Corros Sci 49(8):3290–3302. https://doi.org/10.1016/j.corsci.2007.03.012
doi: 10.1016/j.corsci.2007.03.012
Popova A, Christov M, Vasilev A (2011) Mono- and dicationic benzothiazolic quaternary ammonium bromides as mild steel corrosion inhibitors. Part II: electrochemical impedance and polarisation resistance results. Corros Sci 53(5):1770–1777. https://doi.org/10.1016/j.corsci.2011.01.055
doi: 10.1016/j.corsci.2011.01.055
Qian S, Cheng YF (2019) Synergism of imidazoline and sodium dodecylbenzenesulphonate inhibitors on corrosion inhibition of X52 carbon steel in CO
doi: 10.1016/j.molliq.2019.111674
Rahmani H, Alaoui KI, EL Azzouzi M, Benhiba F, El Hallaoui A, Rais Z, Taleb M, Saady A, Labriti B, Aouniti A, Zarrouk A (2019) Corrosion assessement of mild steel in acid environment using novel triazole derivative as a anti-corrosion agent: a combined experimental and quantum chemical study. Chem Data Collect 24:100302. https://doi.org/10.1016/j.cdc.2019.100302
doi: 10.1016/j.cdc.2019.100302
Raistrick ID, Franceschetti DR, Macdonald JR, In: Barsoukov E, Macdonald JR, (2005) Impedance spectroscopy, 2n ed., Theory, experimental and applications, John Wiley & Sons, New Jersey
Raja PB, Sethuraman MG (2009) Strychnos nux-vomica an eco-friendly corrosion inhibitor for mild steel in 1 M sulfuric acid medium. Mater Corros 60(1):22–28. https://doi.org/10.1002/maco.200805027
doi: 10.1002/maco.200805027
Ramezanzadeh B, Arman SY, Mehdipour M, Markhali BP (2014) Analysis of electrochemical noise (ECN) data in time and frequency domain for comparison corrosion inhibition of some azole compounds on Cu in 1.0 M H
doi: 10.1016/j.apsusc.2013.10.119
Rouifi Z, Rbaa M, Abousalem AS, Benhiba F, Laabaissi T, Oudda H, Lakhrissi B, Guenbour A, Warad I, Zarrouk A (2020a) Synthesis, characterization and corrosion inhibition potential of newly benzimidazole derivatives: combining theoretical and experimental study. Surf Interfaces 18:100442. https://doi.org/10.1016/j.surfin.2020.100442
doi: 10.1016/j.surfin.2020.100442
Rouifi Z, Rbaa M, Benhiba F, Laabaissi T, Oudda H, Lakhrissi B, Guenbour A, Warad I, Zarrouk A (2020b) Preparation and anti-corrosion activity of novel 8-hydroxyquinoline derivative for carbon steel corrosion in HCl molar: computational and experimental analyses. J Mol Liq 307:112923. https://doi.org/10.1016/j.molliq.2020.112923
doi: 10.1016/j.molliq.2020.112923
Saeed MT, Saleem M, Usmani S, Malik IA, Al-Shammari FA, Deen KM (2019) Corrosion inhibition of mild steel in 1 M HCl by sweet melon peel extract. J King Saud Univ Sci 31(4):1344–1351. https://doi.org/10.1016/j.jksus.2019.01.013
doi: 10.1016/j.jksus.2019.01.013
Saranya J, Benhiba F, Anusuya N, Ram S, Zarrouk A, Chitra S (2020) Experimental and computational approaches on the pyran derivatives for acid corrosion. Colloids Surf A 603:125231. https://doi.org/10.1016/j.colsurfa.2020.125231
doi: 10.1016/j.colsurfa.2020.125231
Sastri VS, Elboujdaini M, Rown JR, Perumareddi JR (1996) Surface analysis of inhibitor films formed in hydrogen sulfide medium. Corrosion 52(6):447–452. https://doi.org/10.5006/1.3292133
doi: 10.5006/1.3292133
Satapathy AK, Gunasekaran G, Sahoo SC, Amit K, Rodrigues RV (2009) Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution. Corros Sci 51(12):2848–2856. https://doi.org/10.1016/j.corsci.2009.08.016
doi: 10.1016/j.corsci.2009.08.016
Schmitt G, Olbertz B (1984) Application of inhibitors for acid media: report prepared for the European Federation of Corrosion Working Party on Inhibitors. Corros J 19:165–176. https://doi.org/10.1179/000705984798273100
doi: 10.1179/000705984798273100
Shih H, Mansfeld F (1989) A fitting procedure for impedance data of systems with very low corrosion rates. Corros Sci 29(10):1235–1240. https://doi.org/10.1016/0010-938X(89)90070-X
doi: 10.1016/0010-938X(89)90070-X
Singh A, Ebenso EE, Quraishi MA (2012) Corrosion inhibition of carbon steel in HCl solution by some plant extracts. Int J Corros 897430. https://doi.org/10.1155/2012/897430
Solmaz R (2010) Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid. Corros Sci 52(10):3321–3330. https://doi.org/10.1016/j.corsci.2010.06.001
doi: 10.1016/j.corsci.2010.06.001
Sykes JM (1990) Silver Jubilee review 25 years of progress in electrochemical methods. Br Corros J 25:175–183. https://doi.org/10.1179/000705990798269577
doi: 10.1179/000705990798269577
Tarraf W, Laquale S, De Mastro G, D’Addabbo T (2019) The potential of Citrullus colocynthis oil as a biocide against phytoparasitic nematodes. Grop Prot 124:104843. https://doi.org/10.1016/j.cropro.2019.104843
doi: 10.1016/j.cropro.2019.104843
Tayebi H, Bourazmi H, Himmi B, El Assyry A, Ramli Y, Zarrouk A, Geunbour A, Hammouti B (2014) Combined electrochemical and quantum chemical study of new quinoxaline derivative as corrosion inhibitor for carbon steel in acidic media. Der Pharma Chem 6(5):220–234
Temesghen W, Sherwood PMA (2002) Analytical utility of valence band X-ray photoelectron spectroscopy of iron and its oxides, with spectral interpretation by cluster and band structure calculations. Anal Bioanal Chem 373(7):601–608. https://doi.org/10.1007/s00216-002-1362-3
doi: 10.1007/s00216-002-1362-3
Torres VV, Amado RS, Faia de Sá C, Fernandez TL, Riehl CAS, Torres AG, D’Elia E (2011) Inhibitory action of aqueous coffee ground extracts on the corrosion of carbon steel in HCl solution. Corros Sci 53:2385–2392. https://doi.org/10.1016/j.corsci.2011.03.021
doi: 10.1016/j.corsci.2011.03.021
Tourabi M, Nohair K, Traisnel M, Jama C, Bentiss F (2013) Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole. Corros Sci 75:123–133. https://doi.org/10.1016/j.corsci.2013.05.023
doi: 10.1016/j.corsci.2013.05.023
Wang L (2001) Evaluation of 2-mercaptobenzimidazole as corrosion inhibitor for mild steel in phosphoric acid. Corros Sci 43(12):2281–2289. https://doi.org/10.1016/S0010-938X(01)00036-1
doi: 10.1016/S0010-938X(01)00036-1
Watts JF, Wolstenholme J (2003) An introduction to surface analysis by XPS and AES. John Wiley and Sons Inc, UK
doi: 10.1002/0470867930
Zakeri A, Bahmani E, Sabour Rouh Aghdam A (2022) Plant extracts as sustainable and green corrosion inhibitors for protection of ferrous metals in corrosive media: a mini review. Corros Commun 5:25–38. https://doi.org/10.1016/j.corcom.2022.03.002
doi: 10.1016/j.corcom.2022.03.002
Zarrouk A, Hammouti B, Lakhlifi T, Traisnel M, Vezin H, Bentiss F (2015) New 1H-pyrrole-2,5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium: electrochemical, XPS and DFT studies. Corros Sci 90:572–584. https://doi.org/10.1016/j.corsci.2014.10.052
doi: 10.1016/j.corsci.2014.10.052
Zheludkevich ML, Yasakau KA, Poznyak SK, Ferreira MGS (2005) Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy. Corros Sci 47(12):3368–3383. https://doi.org/10.1016/j.corsci.2005.05.040
doi: 10.1016/j.corsci.2005.05.040