Insights into Photopolymerization at the Nanoscale Using Surface Plasmon Resonance Imaging.
Plasmonic
SPR imaging
Surface Plasmon Resonance
near‐field photopolymerization
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
25 Jun 2024
25 Jun 2024
Historique:
revised:
08
05
2024
received:
09
03
2024
medline:
26
6
2024
pubmed:
26
6
2024
entrez:
26
6
2024
Statut:
aheadofprint
Résumé
Near-field photopolymerization (NFPP) driven by surface plasmon resonance has attracted increasing attention in nanofabrication. This interest comes from the nanometer-scale control of polymer thickness, due to the confinement of the evanescent wave within a highly restricted volume at the surface. In this study, a novel approach using a multi-spectral surface plasmon resonance instrument is presented that gives access to real-time images of polymer growth during NFPP with nanometer sensitivity. Using the plasmonic evanescent wave for both polymerization and real-time sensing, the influence of irradiance, concentration of dye, and initiator are investigated on the threshold energy and kinetics of NFPP. How oxygen inhibition in the near field strongly affects photopolymerization is highlighted, more than in the far field.
Identifiants
pubmed: 38923283
doi: 10.1002/smll.202401885
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2401885Subventions
Organisme : Institute HiFunMat
ID : ITI 2021-2028
Organisme : University of Strasbourg
Organisme : IdEx Unistra
ID : ANR-10-IDEX-0002
Organisme : French Investments for the Future Program
Organisme : Agence Nationale de la Recherche
ID : ANR-20-SFRI-0012
Organisme : Agence Nationale de la Recherche
ID : ANR-18-CE04-0010
Organisme : Agence Nationale de la Recherche
ID : ANR-19-CE19-0012
Informations de copyright
© 2024 The Author(s). Small published by Wiley‐VCH GmbH.
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