Photon-Modulated Bond Covalency of [Sm(II)(η

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
05 Jul 2024
Historique:
medline: 5 7 2024
pubmed: 5 7 2024
entrez: 5 7 2024
Statut: aheadofprint

Résumé

Lanthanides are widely assumed not to form covalent bonds due to the localized nature of their 4f valence electrons. This work demonstrates that the ionic bond of Sm(II) with cyclononatetraenyl (η

Identifiants

DOI: 10.1021/jacs.3c13934 PMID: 38968342
pubmed: 38968342
doi: 10.1021/jacs.3c13934
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Auteurs

T Vitova (T)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0002-3117-7701

H Ramanantoanina (H)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

B Schacherl (B)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0003-4542-0108

L Münzfeld (L)

Institute for Inorganic Chemistry, Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

A Hauser (A)

Institute for Inorganic Chemistry, Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

R S K Ekanayake (RSK)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0002-5255-1969

C Y Reitz (CY)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

T Prüßmann (T)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0002-7903-9199

T S Neill (TS)

Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0002-4316-1328

J Göttlicher (J)

Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

R Steininger (R)

Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.

V A Saveleva (VA)

ESRF, The European Synchrotron, 71 Avenue des Martyrs, CS40220, 38043 Grenoble Cedex 9, France.
ORCID: 0000-0002-8221-4576

M W Haverkort (MW)

Institute for Theoretical Physics, University of Heidelberg, Philosophenweg 19, D-69120 Heidelberg, Germany.
ORCID: 0000-0002-7216-3146

P W Roesky (PW)

Institute for Inorganic Chemistry, Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
Institute of Nanotechnology (INT), Karlsruhe Institute of Technology, P.O. 3640, D-76021 Karlsruhe, Germany.
ORCID: 0000-0002-0915-3893

Classifications MeSH