Infrared Spectroscopy of SARS-CoV-2 Viral Protein: from Receptor Binding Domain to Spike Protein.

ATR‐IR spectroscopy MultiFOLD Spike glycoproteins hydrophobicity secondary structure

Journal

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
ISSN: 2198-3844
Titre abrégé: Adv Sci (Weinh)
Pays: Germany
ID NLM: 101664569

Informations de publication

Date de publication:
12 Jul 2024
Historique:
revised: 10 04 2024
received: 23 01 2024
medline: 13 7 2024
pubmed: 13 7 2024
entrez: 13 7 2024
Statut: aheadofprint

Résumé

Spike (S) glycoprotein is the largest structural protein of SARS-CoV-2 virus and the main one involved in anchoring of the host receptor ACE2 through the receptor binding domain (RBD). S protein secondary structure is of great interest for shedding light on various aspects, from functionality to pathogenesis, finally to spectral fingerprint for the design of optical biosensors. In this paper, the secondary structure of SARS-CoV-2 S protein and its constituting components, namely RBD, S1 and S2 regions, are investigated at serological pH by measuring their amide I infrared absorption bands through Attenuated Total Reflection Infrared (ATR-IR) spectroscopy. Experimental data in combination with MultiFOLD predictions, Define Secondary Structure of Proteins (DSSP) web server and Gravy value calculations, provide a comprehensive understanding of RBD, S1, S2, and S proteins in terms of their secondary structure content, conformational order, and interaction with the solvent.

Identifiants

pubmed: 39001588
doi: 10.1002/advs.202400823
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2400823

Subventions

Organisme : NATO Science for Peace and Security Program
ID : G5889
Organisme : Next Generation EU (NGEU) PRIN PNRR 2022 MIUR
ID : P2022NMBAJ

Informations de copyright

© 2024 The Authors. Advanced Science published by Wiley‐VCH GmbH.

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Auteurs

Tiziana Mancini (T)

Department of Physics, University La Sapienza, P.le A. Moro 2, Rome, 00185, Italy.

Salvatore Macis (S)

Department of Physics, University La Sapienza, P.le A. Moro 2, Rome, 00185, Italy.

Rosanna Mosetti (R)

Department of Basic and Applied Sciences for Engineering (SBAI), University La Sapienza, Via A. Scarpa 16, Rome, 00161, Italy.

Nicole Luchetti (N)

Engineering Department, University Campus Bio-Medico of Rome, Via Alvaro del Portillo 21, Rome, 00128, Italy.
Centre for Life Nano- and Neuro-Science, Italian Institute of Technology, Viale Regina Elena 291, Rome, 00161, Italy.

Velia Minicozzi (V)

Department of Physics, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, Rome, 00133, Italy.

Andrea Notargiacomo (A)

Istituto di fotonica e nanotecnologie - Consiglio nazionale delle ricerche (CNR-IFN), Rome, 00133, Italy.

Marialilia Pea (M)

Istituto di fotonica e nanotecnologie - Consiglio nazionale delle ricerche (CNR-IFN), Rome, 00133, Italy.

Augusto Marcelli (A)

Laboratori Nazionali Frascati, National Institute for Nuclear Physics (INFN-LNF), Via E. Fermi 54, Frascati, 00044, Italy.
RICMASS, Rome International Center for Materials Science Superstripes, Rome, 00185, Italy.

Giancarlo Della Ventura (GD)

Department of Science, University Rome Tre, Largo San Leonardo Murialdo 1, Rome, 00146, Italy.

Stefano Lupi (S)

Department of Physics, University La Sapienza, P.le A. Moro 2, Rome, 00185, Italy.

Annalisa D'Arco (A)

Department of Physics, University La Sapienza, P.le A. Moro 2, Rome, 00185, Italy.

Classifications MeSH