Mapping protein binding sites by photoreactive fragment pharmacophores.


Journal

Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670

Informations de publication

Date de publication:
31 Jul 2024
Historique:
received: 01 06 2024
accepted: 23 07 2024
medline: 1 8 2024
pubmed: 1 8 2024
entrez: 31 7 2024
Statut: epublish

Résumé

Fragment screening is a popular strategy of generating viable chemical starting points especially for challenging targets. Although fragments provide a better coverage of chemical space and they have typically higher chance of binding, their weak affinity necessitates highly sensitive biophysical assays. Here, we introduce a screening concept that combines evolutionary optimized fragment pharmacophores with the use of a photoaffinity handle that enables high hit rates by LC-MS-based detection. The sensitivity of our screening protocol was further improved by a target-conjugated photocatalyst. We have designed, synthesized, and screened 100 diazirine-tagged fragments against three benchmark and three therapeutically relevant protein targets of different tractability. Our therapeutic targets included a conventional enzyme, the first bromodomain of BRD4, a protein-protein interaction represented by the oncogenic KRas

Identifiants

pubmed: 39085342
doi: 10.1038/s42004-024-01252-w
pii: 10.1038/s42004-024-01252-w
doi:

Types de publication

Journal Article

Langues

eng

Pagination

168

Informations de copyright

© 2024. The Author(s).

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Auteurs

Péter Ábrányi-Balogh (P)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Department of Organic Chemistry and Technology, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary.

Dávid Bajusz (D)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

Zoltán Orgován (Z)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

Aaron B Keeley (AB)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

László Petri (L)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

Nikolett Péczka (N)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Department of Organic Chemistry and Technology, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary.

Tibor Viktor Szalai (TV)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Department of Inorganic and Analytical Chemistry, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary.

Gyula Pálfy (G)

Laboratory of Structural Chemistry and Biology & HUN-REN-ELTE Protein Modelling Research Group, Eötvös Loránd University, Budapest, Hungary.

Márton Gadanecz (M)

National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Laboratory of Structural Chemistry and Biology & HUN-REN-ELTE Protein Modelling Research Group, Eötvös Loránd University, Budapest, Hungary.
Hevesy György PhD School of Chemistry, Eötvös Loránd University, Budapest, Hungary.

Emma K Grant (EK)

GlaxoSmithKline, Hertfordshire, UK.

Tímea Imre (T)

National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
MS Metabolomics Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

Tamás Takács (T)

National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Signal Transduction and Functional Genomics Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Doctoral School of Biology, Institute of Biology, ELTE Eötvös Loránd University, Budapest, Hungary.

Ivan Ranđelović (I)

National Tumor Biology Laboratory and Department of Experimental Pharmacology, National Institute of Oncology, Budapest, Hungary.
KINETO Lab Ltd, Budapest, Hungary.

Marcell Baranyi (M)

KINETO Lab Ltd, Budapest, Hungary.
Department of Pathology, Forensic and Insurance Medicine, Semmelweis University, Budapest, Hungary.

András Marton (A)

Department of Chemical and Environmental Process Engineering, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary.
Waters Research Center, Budapest, Hungary.

Gitta Schlosser (G)

MTA-ELTE Lendület Ion Mobility Mass Spectrometry Research Group, Eötvös Loránd University, Budapest, Hungary.

Qirat F Ashraf (QF)

Department of Chemical & Physical Sciences, University of Toronto Mississauga, Mississauga, ON, Canada.

Elvin D de Araujo (ED)

Centre for Medicinal Chemistry, University of Toronto at Mississauga, Mississauga, ON, Canada.

Tamás Karancsi (T)

Department of Chemical and Environmental Process Engineering, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary.
Waters Research Center, Budapest, Hungary.

László Buday (L)

National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Signal Transduction and Functional Genomics Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.

József Tóvári (J)

National Tumor Biology Laboratory and Department of Experimental Pharmacology, National Institute of Oncology, Budapest, Hungary.

András Perczel (A)

National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary.
Laboratory of Structural Chemistry and Biology & HUN-REN-ELTE Protein Modelling Research Group, Eötvös Loránd University, Budapest, Hungary.

Jacob T Bush (JT)

GlaxoSmithKline, Hertfordshire, UK.

György M Keserű (GM)

Medicinal Chemistry Research Group, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary. keseru.gyorgy@ttk.hu.
National Drug Research and Development Laboratory, HUN-REN Research Centre for Natural Sciences, Budapest, Hungary. keseru.gyorgy@ttk.hu.
Department of Organic Chemistry and Technology, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Budapest, Hungary. keseru.gyorgy@ttk.hu.

Classifications MeSH