High-Resolution Tandem Mass Spectrometry-Based Analysis of Model Lignin-Iron Complexes: Novel Pipeline and Complex Structures.

high-resolution mass spectrometry iron complexes lignin molecular networking organic ligands

Journal

Environmental science & technology
ISSN: 1520-5851
Titre abrégé: Environ Sci Technol
Pays: United States
ID NLM: 0213155

Informations de publication

Date de publication:
08 Aug 2024
Historique:
medline: 8 8 2024
pubmed: 8 8 2024
entrez: 8 8 2024
Statut: aheadofprint

Résumé

Understanding the chemical nature of soil organic carbon (SOC) with great potential to bind iron (Fe) minerals is critical for predicting the stability of SOC. Organic ligands of Fe are among the top candidates for SOCs able to strongly sorb on Fe minerals, but most of them are still molecularly uncharacterized. To shed insights into the chemical nature of organic ligands in soil and their fate, this study developed a protocol for identifying organic ligands using ultrahigh-performance liquid chromatography-high-resolution tandem mass spectrometry (UHPLC-HRMS/MS) and metabolomic tools. The protocol was used for investigating the Fe complexes formed by model compounds of lignin-derived organic ligands, namely, caffeic acid (CA),

Identifiants

DOI: 10.1021/acs.est.4c03608 PMID: 39116213
pubmed: 39116213
doi: 10.1021/acs.est.4c03608
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Auteurs

Abrar Shahriar (A)

Department of Civil and Environmental Engineering, University of Nevada, Reno, 1664 N Virginia St, Reno, Nevada 89557, United States.
Nuclear and Chemical Sciences Division, Physical and Life Sciences, Lawrence Livermore National Laboratory, Livermore, California 94550, United States.

Srinidhi Lokesh (S)

Department of Civil and Environmental Engineering, University of Nevada, Reno, 1664 N Virginia St, Reno, Nevada 89557, United States.

Anil Timilsina (A)

Department of Civil and Environmental Engineering, University of Nevada, Reno, 1664 N Virginia St, Reno, Nevada 89557, United States.
ORCID: 0000-0001-7053-0662

Travis Numan (T)

Department of Civil and Environmental Engineering, University of Nevada, Reno, 1664 N Virginia St, Reno, Nevada 89557, United States.

Tilman Schramm (T)

CMFI Cluster of Excellence, University of Tuebingen, Auf der Morgenstelle 24, 72076 Tuebingen, Germany.
Department of Biochemistry, University of California Riverside, Riverside, California 92521, United States.

Paolo Stincone (P)

CMFI Cluster of Excellence, University of Tuebingen, Auf der Morgenstelle 24, 72076 Tuebingen, Germany.
ORCID: 0000-0002-2214-6655

Laurinda Nyarko (L)

College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, United States.
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States.

Christian Dewey (C)

College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, United States.
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States.

Daniel Petras (D)

CMFI Cluster of Excellence, University of Tuebingen, Auf der Morgenstelle 24, 72076 Tuebingen, Germany.
Department of Biochemistry, University of California Riverside, Riverside, California 92521, United States.

Rene Boiteau (R)

College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, United States.
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States.
ORCID: 0000-0002-4127-4417

Yu Yang (Y)

Department of Civil and Environmental Engineering, University of Nevada, Reno, 1664 N Virginia St, Reno, Nevada 89557, United States.
ORCID: 0000-0002-7568-0202

Classifications MeSH