Functionalized Metal-Free Carbon Nanosphere Catalyst for the Selective C-N Bond Formation under Open-Air Conditions.

A versatile shape-controlled carbon nanomaterial that can efficiently catalyze the selective C-N coupling reactions under metal-free and open-air conditions was developed by applying N-doping and KOH activation strategies in candle soot (ANCS). The TEM and elemental mapping results showed the formation of sphere-shaped carbon particles as well as the uniform distribution of nitrogen species in the carbon framework. KOH activation enhanced the specific surface area of carbon, whereas N-doping enriched the electron-deficient nature by introducing functional N-based pyrrolic/graphitic structures in the carbon framework. The synergistic effect of N-doping and KOH activation significantly improved the catalytic efficiency of the carbon catalyst (ANCS), giving a 96% conversion of

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© 2024 The Authors. Published by American Chemical Society.

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The authors declare no competing financial interest.