Silver-Catalyzed Carbamoylation and Carbonylative Cyclization of Alkenes with Oxamic Acids.
carbonylation
cyclization
radical
silver catalyst
tetralone
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
27 Aug 2024
27 Aug 2024
Historique:
revised:
14
08
2024
received:
26
07
2024
accepted:
27
08
2024
medline:
27
8
2024
pubmed:
27
8
2024
entrez:
27
8
2024
Statut:
aheadofprint
Résumé
Transition metal-catalyzed carbonylation functionalization reaction of alkenes is an attractive research area in modern organic chemistry. However, there have been very few reports on silver-catalyzed reactions in carbonylation reactions. Herein we developed a silver-catalyzed carbamoylation and carbonylative cyclization of alkenes with oxamic acids to obtain 2-acetylamino-1-tetralone derivatives. Various desired cyclized products were formed in moderate to good yields through radical intermediates.
Identifiants
pubmed: 39189789
doi: 10.1002/asia.202400892
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202400892Informations de copyright
© 2024 Wiley‐VCH GmbH.