Structure Sensitive Reaction Kinetics of Chiral Molecules on Intrinsically Chiral Surfaces.


Journal

The journal of physical chemistry. C, Nanomaterials and interfaces
ISSN: 1932-7447
Titre abrégé: J Phys Chem C Nanomater Interfaces
Pays: United States
ID NLM: 101299949

Informations de publication

Date de publication:
22 Aug 2024
Historique:
received: 25 06 2024
revised: 25 07 2024
accepted: 29 07 2024
medline: 28 8 2024
pubmed: 28 8 2024
entrez: 28 8 2024
Statut: epublish

Résumé

Enantiospecific heterogeneous catalysis utilizes chiral surfaces to resolve enantiomers via structure sensitive surface chemistry. The catalyst design challenge is the identification of chiral surface structures that maximize enantiospecificity. Herein, we develop data driven models for the enantiospecificity of tartaric acid reactions on chiral Cu(

Identifiants

pubmed: 39193257
doi: 10.1021/acs.jpcc.4c04224
pmc: PMC11345842
doi:

Types de publication

Journal Article

Langues

eng

Pagination

13879-13887

Informations de copyright

© 2024 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

Auteurs

Kareem Abdelmaqsoud (K)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

Michael Radetic (M)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

Carlos Fernández-Cabán (C)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

Michael Widom (M)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

John R Kitchin (JR)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

Andrew J Gellman (AJ)

Department of Chemical Engineering and Department of Physics, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, United States.

Classifications MeSH