Enantioselective Synthesis of Cyclopentanes by Phosphine-Catalyzed β,γ-Annulation of Allenoates.

Journal

Organic letters

ISSN: 1523-7052

Titre abrégé: Org Lett

Pays: United States

ID NLM: 100890393

Informations de publication

Date de publication:
06 Sep 2024

Historique:

medline: 6 9 2024

pubmed: 6 9 2024

entrez: 6 9 2024

Statut: aheadofprint

Résumé

Herein, we report the enantioselective phosphine-catalyzed β,γ-annulation of electron-poor allenes with bifunctional malonates. The reaction exploits a 2C phosphonium synthon that when accessed using (

Identifiants

DOI: 10.1021/acs.orglett.4c02371 PMID: 39240702

pubmed: 39240702

doi: 10.1021/acs.orglett.4c02371

doi:

Types de publication

Journal Article

Langues

eng