The mechanism of the molecular CISS effect in chiral nano-junctions.

The chirality induced spin selectivity (CISS) effect has been up to now measured in a wide variety of systems but its exact mechanism is still under debate. Whether the spin polarization occurs at an interface layer or builds up in the helical molecule is yet not clear. Here we have investigated the current transmission through helical polyalanine molecules as a part of a tunnel junction realized with a scanning tunneling microscope. Depending on whether the molecules were chemisorbed directly on the magnetic Au/Co/Au substrate or at the STM Au-tip, the magnetizations of the Co layer had been oriented in the opposite direction in order to preserve the symmetry of the

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The authors declare no competing financial interest.