Soft and Deformable Thermoresponsive Hollow Rod-Shaped Microgels.
anisotropic microgels
capillary interactions
hollow microgels
silica rods
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
10 Sep 2024
10 Sep 2024
Historique:
revised:
28
08
2024
received:
21
02
2024
medline:
10
9
2024
pubmed:
10
9
2024
entrez:
10
9
2024
Statut:
aheadofprint
Résumé
Depending on their aspect ratio, rod-shaped particles exhibit a much richer 2D and 3D phase behavior than their spherical counterparts, with additional nematic and smectic phases accompanied by defined orientational ordering. While the phase diagram of colloidal hard rods is extensively explored, little is known about the influence of softness in such systems, partly due to the absence of appropriate model systems. Additionally, investigating higher volume fractions for long rods is usually complicated because non-equilibrium dynamical arrest is likely to precede the formation of more defined states. This has motivated us to develop micrometric rod-like microgels with limited sedimentation that can respond to temperature and reversibly reorganize into defined phases via annealing and seeding procedures. A detailed procedure is presented for synthesizing rod-shaped hollow poly(N-isopropylacrylamide) microgels using micrometric silica rods as sacrificial templates. Their morphological characterization is conducted through a combination of microscopy and light scattering techniques, evidencing the unconstrained swelling of rod-shaped hollow microgels compared to core-shell microgel rods. Different aspects of their assembly in dispersion and at interfaces are further tested to illustrate the opportunities and challenges offered by such systems that combine softness, anisotropy, and thermoresponsivity.
Identifiants
pubmed: 39252647
doi: 10.1002/smll.202401376
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2401376Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB985
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB985
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB985
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB985
Organisme : NSF
ID : DMR-0520547
Informations de copyright
© 2024 The Author(s). Small published by Wiley‐VCH GmbH.
Références
D. Frenkel, J. Phys. Chem. 1988, 92, 3280.
D. Frenkel, H. Lekkerkerker, A. Stroobants, Nature 1988, 322, 822.
S. C. McGrother, D. C. Williamson, G. Jackson, J. Chem. Phys. 1996, 104, 6755.
A. Kuijk, D. V. Byelov, A. V. Petukhov, A. van Blaaderen, A. Imhof, Faraday Discuss. 2012, 159, 181.
L. Onsager, Ann. N. Y. Acad. Sci 1949, 51, 627.
D. Frenkel, B.. Mulder, Mol. Phys 1985, 55, 1171.
H. Maeda, Y. Maeda, Phys. Rev. Lett. 2003, 90, 018303.
Z. Dogic, S. Fraden, Curr. Opin. Colloid Interface Sci. 2006, 11, 47.
B. J. Lemaire, P. Davidson, J. Ferré, J. P. Jamet, D. Petermann, P. Panine, I. Dozov, J. P. Jolivet, Eur. Phys. J. E 2004, 13, 309.
E. van den Pol, A. V. Petukhov, D. M. E. Thies‐Weesie, D. V. Byelov, G. J. Vroege, J. Colloid Interface Sci 2010, 352, 354.
A. Kuijk, A. van Blaaderen, A. S. o. M. Imhof, J. Am. Chem. Soc 2011, 133, 2346.
T. H. Besseling, M. Hermes, A. Kuijk, B. de Nijs, T. S. Deng, M. Dijkstra, A. Imhof, A. van Blaaderen, J. Phys. Condens. Matter 2015, 27, 19410.
A. Kuijk, A. Imhof, M. H. W. Verkuijlen, T. H. Besseling, E. R. H. van Eck, A. van Blaaderen, Part. Part. Syst. Charact. 2014, 31, 706.
J. Roller, A. Laganapan, J.‐M. Meijer, M. Fuchs, A. Zumbusch, Proc. Natl. Acad. Sci. USA 2021, 118, 2018072118.
A. Scotti, M. F. Schulte, C. G. Lopez, J. J. Crassous, S. Bochenek, W. Richtering, Chem. Rev. 2022, 122, 11675.
M. Karg, A. Pich, T. Hellweg, T. Hoare, L. A. Lyon, J. Crassous, D. Suzuki, R. A. Gumerov, S. Schneider, I. I. Potemkin, W. Richtering, Langmuir 2019, 35, 6231.
F. A. Plamper, W. Richtering, Acc. Chem. Res. 2017, 50, 131.
J. Brijitta, P. Schurtenberger, Curr. Opin. Colloid Interface 2019, 40, 87.
S. K. Wypysek, A. Scotti, M. O. Alziyadi, I. I. Potemkin, A. R. Denton, W. Richtering, Macromol. Rapid Commun. 2020, 41, 1900422.
F. Hagemans, F. Camerin, N. Hazra, J. Lammertz, F. Dux, G. Del Monte, O.‐V. Laukkanen, J. J. Crassous, E. Zaccarelli, W. Richtering, ACS Nano 2023, 17, 7257.
A. C. Nickel, A. Scotti, J. E. Houston, T. Ito, J. Crassous, J. S. Pedersen, W. Richtering, Nano Lett. 2019, 19, 8161.
A. C. Nickel, T. Kratzenberg, S. Bochenek, M. M. Schmidt, A. A. Rudov, A. Falkenstein, I. I. Potemkin, J. J. Crassous, W. Richtering, Langmuir 2022, 38, 5063.
A. C. Nickel, A. A. Rudov, I. I. Potemkin, J. J. Crassous, W. Richtering, Langmuir 2022, 38, 4351.
A. C. Nickel, T. Kratzenberg, S. Bochenek, M. M. Schmidt, A. A. Rudov, A. Falkenstein, I. I. Potemkin, J. J. Crassous, W. Richtering, Langmuir 2022, 38, 5063.
J. J. Crassous, A. M. Mihut, E. Wernersson, P. Pfleiderer, J. Vermant, P. Linse, P. Schurtenberger, Nat. Commun. 2014, 5, 5516.
J. J. Crassous, A. M. Mihut, L. K. Månsson, P. Schurtenberger, Nanoscale 2015, 7, 15971.
K. Honda, Y. Sazuka, K. Iizuka, S. Matsui, T. Uchihashi, T. Kureha, M. Shibayama, T. Watanabe, D. Suzuki, Angew. Chem., Int. Ed. 2019, 58, 7294.
A. J. D. Krüger, O. Bakirman, L. P. B. Guerzoni, A. Jans, D. B. Gehlen, D. Rommel, T. Haraszti, A. J. C. Kuehne, L. De Laporte, Adv. Mater. 2019, 31, 1903668.
H. J. M. Wolff, J. Linkhorst, T. Göttlich, J. Savinsky, A. J. D. Krüger, L. de Laporte, M. Wessling, Lab Chip 2020, 20, 285.
J. M. Desimone, J.‐Y. Wang, Y. Wang, in Janus Particle Synthesis, Self‐Assembly and Applications, The Royal Society of Chemistry, London 2012, pp. 90–107.
M. Saadli, D. L. Braunmiller, A. Mourran, J. J. Crassous, Small 2023, 19, 2207035.
D. L. Braunmiller, S. Babu, D. B. Gehlen, M. Seuß, T. Haraszti, A. Falkenstein, J. Eigen, L. De Laporte, J. J. Crassous, Adv. Funct. Mater. 2022, 32, 2202430.
T. G. Anjali, M. G. Basavaraj, Langmuir 2018, 35, 3.
L. Botto, E. P. Lewandowski, M. Cavallaro, K. J. Stebe, Soft Matter 2012, 8, 9957.
J.‐C. Loudet, A. M. Alsayed, J. Zhang, A. G. Yodh, Phys. Rev. Lett. 2005, 94, 018301.
J.‐C. Loudet, A. G. Yodh, B. Pouligny, Phys. Rev. Lett. 2006, 97, 018304.
B. Madivala, J. Fransaer, J. Vermant, Langmuir 2009, 25, 2718.
B. Madivala, S. Vandebril, J. Fransaer, J. Vermant, Soft Matter 2009, 5, 1717.
E. P. Lewandowski, M. Cavallaro Jr, L. Botto, J. C. Bernate, V. Garbin, K. J. Stebe, Langmuir 2010, 26, 15142.
M. Cavallaro Jr, L. Botto, E. P. Lewandowski, M. Wang, K. J. Stebe, Proc. Natl. Acad. Sci. USA 2011, 108, 20923.
S. Dasgupta, T. Auth, G. Gompper, J. Phys.: Condens. Matter 2017, 29, 373003.
K. Gvozden, S. Novak Ratajczak, A. G. Orellana, E. Kentzinger, U. Rücker, J. K. Dhont, C. De Michele, E. Stiakakis, Small 2022, 18, 2104510.
M. Nakata, G. Zanchetta, B. D. Chapman, C. D. Jones, J. O. Cross, R. Pindak, T. Bellini, N. A. Clark, Science 2007, 318, 1276.
D. Li, S. Banon, S. L. Biswal, Soft Matter 2010, 6, 4197.
S. Kuei, B. Garza, S. L. Biswal, Phys. Rev. Fluids 2017, 2, 104102.
J. Byrom, P. Han, M. Savory, S. L. Biswal, Langmuir 2014, 30, 9045.
T. Besseling, M. Hermes, A. Kuijk, B. De Nijs, T. Deng, M. Dijkstra, A. Imhof, A. Van Blaaderen, J. Phys.: Condens. Matter 2015, 27, 194109.
F. Hagemans, R. K. Pujala, D. S. Hotie, D. M. E. Thies‐Weesie, D. A. M. de Winter, J. D. Meeldijk, A. van Blaaderen, A. Imhof, Chem. Mater. 2019, 31, 521.
I. Livsey, J. Chem. Soc., Faraday Trans. 2 1987, 83, 1445.
V. N. Tsvetkov, Rigid‐Chain Polymers: Hydrodynamic and Optical Properties in Solution, Consultants Bureau (Plenum), New York 1989.
I. Martchenko, H. Dietsch, C. Moitzi, P. Schurtenberger, J. Phys. Chem. B 2011, 115, 14838.
J. Schmitt, C. Hartwig, J. J. Crassous, A. M. Mihut, P. Schurtenberger, V. Alfredsson, RSC Adv. 2020, 10, 25393.
N. Hazra, J. Lammertz, A. Babenyshev, R. Erkes, F. Hagemans, C. Misra, W. Richtering, J. J. Crassous, Soft Matter 2024, 20, 4608.
J. Dubbert, T. Honold, J. S. Pedersen, A. Radulescu, M. Drechsler, M. Karg, W. Richtering, Macromolecules 2014, 47, 8700.
J. Zhang, R. Pelton, Langmuir 1999, 15, 8032.
Y. Cohin, M. Fisson, K. Jourde, G. G. Fuller, N. Sanson, L. Talini, C. Monteux, Rheol. Acta 2013, 52, 445.
T. Ngai, S. H. Behrens, H. Auweter, Chemical Commun. 2005, 3, 331.
S. Tsuji, H. Kawaguchi, Langmuir 2008, 24, 3300.
B. Brugger, W. Richtering, Langmuir 2008, 24, 7769.
E. P. Lewandowski, J. A. Bernate, A. Tseng, P. C. Searson, K. J. Stebe, Soft Matter 2009, 5, 886.
E. P. Lewandowski, M. J. Cavallaro, L. Botto, J. C. Bernate, V. Garbin, K. J. Stebe, Langmuir 2010, 26, 15142.
J. Vialetto, F. Camerin, F. Grillo, S. N. Ramakrishna, L. Rovigatti, E. Zaccarelli, L. Isa, ACS Nano 2021, 15, 13105.
S. O. Morgan, A. Muravitskaya, C. Lowe, A. M. Adawi, J.‐S. G. Bouillard, T. S. Horozov, G. J. Stasiuk, D. M. A. Buzza, Phys. Chem. Chem. Phys. 2022, 24, 11000.
M. A. Fernandez‐Rodriguez, A. Martín‐Molina, J. Maldonado‐Valderrama, Adv. Colloid Interface Sci. 2021, 288, 102350.
J. C. Rose, D. B. Gehlen, T. Haraszti, J. Köhler, C. J. Licht, L. De Laporte, Biomaterials 2018, 163, 128.
M. F. Schulte, S. Bochenek, M. Brugnoni, A. Scotti, A. Mourran, W. Richtering, Angew. Chem., Int. Ed. 2021, 60, 2280.