Electrochemical and computational evaluation of hydrazide derivative for mild steel corrosion inhibition and anticancer study.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
10 Sep 2024
Historique:
received: 12 03 2024
accepted: 20 08 2024
medline: 11 9 2024
pubmed: 11 9 2024
entrez: 10 9 2024
Statut: epublish

Résumé

In the present study the authors' main goal is to avoid the corrosive attack of the chloride ions of 3.5% NaCl solution in saline medium on the mild steel (MS), by addition of small amount of a new derivative of the hydrazide called ligand (HL), as a corrosion inhibitor. This study had been achieved by employing different electrochemical measurements such as, open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and potentio-dynamic polarization (PDP) methods. The results of the electrochemical test (OCP), showed that, the open circuit potential of the mild steel in saline solution, was guided to more positive direction in presence of the ligand (HL), at its ideal concentration (1 × 10

Identifiants

pubmed: 39256422
doi: 10.1038/s41598-024-70715-w
pii: 10.1038/s41598-024-70715-w
doi:

Substances chimiques

Steel 12597-69-2
Hydrazines 0
Antineoplastic Agents 0
Sodium Chloride 451W47IQ8X

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

21138

Informations de copyright

© 2024. The Author(s).

Références

Shukla, S. K., Singh, A. K. & Quraishi, M. Triazines: Efficient corrosion inhibitors for mild steel in hydrochloric acid solution. Int. J. Electrochem. Sci. 7, 3371–3389 (2012).
doi: 10.1016/S1452-3981(23)13962-9
De Damborenea, J., Conde, A. & Arenas, M. A. Corrosion inhibition with rare earth metal compounds in aqueous solutions. In Rare Earth-Based Corrosion Inhibitors 84–116 (Woodhead Publishing, 2014).
doi: 10.1533/9780857093585.84
Verma, C., Obot, I., Bahadur, I., Sherif, E.-S.M. & Ebenso, E. E. Choline based ionic liquids as sustainable corrosion inhibitors on mild steel surface in acidic medium: Gravimetric, electrochemical, surface morphology, DFT and Monte Carlo simulation studies. Appl. Surf. Sci. 457, 134–149 (2018).
doi: 10.1016/j.apsusc.2018.06.035
Alhaffar, M. T., Umoren, S. A., Obot, I. B. & Ali, S. A. Isoxazolidine derivatives as corrosion inhibitors for low carbon steel in HCl solution: Experimental, theoretical and effect of KI studies. RSC Adv. 8, 1764–1777 (2018).
pubmed: 35542624 pmcid: 9077101 doi: 10.1039/C7RA11549K
Paul, B. D. A history of the concept of sustainable development: Literature review. Ann. Univ. Oradea Econ. Sci. Ser. 17, 576–580 (2008).
Sajid, M. & Płotka-Wasylka, J. Green analytical chemistry metrics: A review. Talanta 238, 123046 (2022).
pubmed: 34801903 doi: 10.1016/j.talanta.2021.123046
Tobiszewski, M., Marć, M., Gałuszka, A. & Namieśnik, J. Green chemistry metrics with special reference to green analytical chemistry. Molecules 20, 10928–10946 (2015).
pubmed: 26076112 pmcid: 6272361 doi: 10.3390/molecules200610928
Van Aken, K., Strekowski, L. & Patiny, L. EcoScale, a semi-quantitative tool to select an organic preparation based on economical and ecological parameters. Beilstein J. Org. Chem. 2, 3 (2006).
pubmed: 16542013 pmcid: 1409775
Kaczerewska, O. et al. Effectiveness of O-bridged cationic gemini surfactants as corrosion inhibitors for stainless steel in 3 M HCl: Experimental and theoretical studies. J. Mol. Liq. 249, 1113–1124 (2018).
doi: 10.1016/j.molliq.2017.11.142
Verma, C., Quraishi, M. & Ebenso, E. E. Microwave and ultrasound irradiations for the synthesis of environmentally sustainable corrosion inhibitors: An overview. Sustain. Chem. Pharm. 10, 134–147 (2018).
doi: 10.1016/j.scp.2018.11.001
Verma, C., Olasunkanmi, L., Ebenso, E. E. & Quraishi, M. Substituents effect on corrosion inhibition performance of organic compounds in aggressive ionic solutions: A review. J. Mol. Liq. 251, 100–118 (2018).
doi: 10.1016/j.molliq.2017.12.055
Singh, P., Ebenso, E. E., Olasunkanmi, L. O., Obot, I. B. & Quraishi, M. A. Electrochemical, theoretical, and surface morphological studies of corrosion inhibition effect of green naphthyridine derivatives on mild steel in hydrochloric acid. J. Phys. Chem. C 120, 3408–3419 (2016).
doi: 10.1021/acs.jpcc.5b11901
Verma, C., Olasunkanmi, L. O., Ebenso, E. E., Quraishi, M. A. & Obot, I. B. Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: Experimental and theoretical studies. J. Phys. Chem. C 120, 11598–11611 (2016).
doi: 10.1021/acs.jpcc.6b04429
Mishra, A. et al. Synthesis, characterization and corrosion inhibition studies of N-phenyl-benzamides on the acidic corrosion of mild steel: Experimental and computational studies. J. Mol. Liq. 251, 317–332 (2018).
doi: 10.1016/j.molliq.2017.12.011
Sastri, V. S. Green Corrosion Inhibitors: Theory and Practice (John Wiley & Sons, 2012).
Ebenso, E., Ekpe, U., Ita, B., Offiong, O. & Ibok, U. Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid. Mater. Chem. Phys. 60, 79–90 (1999).
doi: 10.1016/S0254-0584(99)00074-7
Mahood, H. B., Sayer, A. H., Mekky, A. H. & Khadom, A. A. Performance of synthesized acetone based inhibitor on low carbon steel corrosion in 1 M HCl solution. Chem. Afr. 3, 263–276 (2020).
doi: 10.1007/s42250-019-00104-8
Ahmed, S. K., Ali, W. B. & Khadom, A. A. Synthesis and characterization of new triazole derivatives as corrosion inhibitors of carbon steel in acidic medium. J. Bio Tribo Corros. 5, 15 (2019).
doi: 10.1007/s40735-018-0209-1
Abuelela, A. M., Bedair, M. A., Zoghaib, W. M., Wilson, L. D. & Mohamed, T. A. Molecular structure and mild steel/HCl corrosion inhibition of 4, 5-dicyanoimidazole: Vibrational, electrochemical and quantum mechanical calculations. J. Mol. Struct. 1230, 129647 (2021).
doi: 10.1016/j.molstruc.2020.129647
Farag, Z. R., Moustapha, M. E. & Abd El-Hafeez, G. M. The inhibition tendencies of novel hydrazide derivatives on the corrosion behavior of mild steel in hydrochloric acid solution. J. Mater. Res. Technol. 16, 1422–1434 (2022).
doi: 10.1016/j.jmrt.2021.12.035
Aslam, R., Mobin, M., Aslam, J. & Lgaz, H. Sugar based N, N′-didodecyl-N, N′ digluconamideethylenediamine gemini surfactant as corrosion inhibitor for mild steel in 3.5% NaCl solution-effect of synergistic KI additive. Sci. Rep. 8, 3690 (2018).
pubmed: 29487360 pmcid: 5829231 doi: 10.1038/s41598-018-21175-6
Abdelshafeek, K. A., Abdallah, W. E., Elsayed, W. M., Eladawy, H. A. & El-Shamy, A. Vicia faba peel extracts bearing fatty acids moieties as a cost-effective and green corrosion inhibitor for mild steel in marine water: Computational and electrochemical studies. Sci. Rep. 12, 20611 (2022).
pubmed: 36446843 pmcid: 9708655 doi: 10.1038/s41598-022-24793-3
Verma, C., Haque, J., Quraishi, M. & Ebenso, E. E. Aqueous phase environmental friendly organic corrosion inhibitors derived from one step multicomponent reactions: A review. J. Mol. Liq. 275, 18–40 (2019).
doi: 10.1016/j.molliq.2018.11.040
Verma, C., Verma, D. K., Ebenso, E. E. & Quraishi, M. A. Sulfur and phosphorus heteroatom-containing compounds as corrosion inhibitors: An overview. Heteroat. Chem. 29, e21437 (2018).
doi: 10.1002/hc.21437
Verma, C., Ebenso, E. E. & Quraishi, M. Molecular structural aspects of organic corrosion inhibitors: Influence of–CN and–NO2 substituents on designing of potential corrosion inhibitors for aqueous media. J. Mol. Liq. 316, 113874 (2020).
doi: 10.1016/j.molliq.2020.113874
Capan, A., Uruş, S. & Sönmez, M. Ru (III), Cr (III), Fe (III) complexes of Schiff base ligands bearing phenoxy groups: Application as catalysts in the synthesis of vitamin K3. J. Saudi Chem. Soc. 22, 757–766 (2018).
doi: 10.1016/j.jscs.2017.12.007
Chen, A. & Ostrom, C. Palladium-based nanomaterials: synthesis and electrochemical applications. Chem. Rev. 115, 11999–12044 (2015).
pubmed: 26402587 doi: 10.1021/acs.chemrev.5b00324
Sönmez, M., Çelebi, M. & Berber, I. Synthesis, spectroscopic and biological studies on the new symmetric Schiff base derived from 2, 6-diformyl-4-methylphenol with N-aminopyrimidine. Eur. J. Med. Chem. 45, 1935–1940 (2010).
pubmed: 20163896 doi: 10.1016/j.ejmech.2010.01.035
Abdelmonem, Y. K., El-Essawy, F. A., Abou El-Enein, S. A. & El-Sheikh-Amer, M. M. Docking studies, synthesis, and evaluation of antioxidant activities of N-alkylated, 1, 2, 4-triazole, 1, 3, 4-oxa-, and thiadiazole containing the aminopyrazolopyridine derivatives. Int. J. Org. Chem. 3, 198–205 (2013).
doi: 10.4236/ijoc.2013.33026
Abdel-Monem, Y. K., Emam, S. M. & Okda, H. M. Solid state thermal decomposition synthesis of CuO nanoparticles from coordinated pyrazolopyridine as novel precursors. J. Mater. Sci. Mater. Electron. 28, 2923–2934 (2017).
doi: 10.1007/s10854-016-5877-3
Rahman, A. A. et al. Synthesis, docking studies into CDK-2 and anticancer activity of new derivatives based pyrimidine scaffold and their derived glycosides. Mini Rev. Med. Chem. 19, 1093–1110 (2019).
pubmed: 30864522 doi: 10.2174/1389557519666190312165717
Frisch, M. J. et al. 16, Revision C. 01, 2016. (Gaussian. Inc., Wallingford CT, 2016).
Andersson, M. P. & Uvdal, P. New scale factors for harmonic vibrational frequencies using the B3LYP density functional method with the triple- basis set 6–311+ G (d, p). J. Phys. Chem. A 109, 2937–2941 (2005).
pubmed: 16833612 doi: 10.1021/jp045733a
Bhat, A. R. et al. Synthesis, biological activity and POM/DFT/docking analyses of annulated pyrano [2, 3-d] pyrimidine derivatives: Identification of antibacterial and antitumor pharmacophore sites. Bioorg. Chem. 106, 104480 (2021).
pubmed: 33279245 doi: 10.1016/j.bioorg.2020.104480
Guerfi, M. et al. An efficient synthesis, characterization, DFT study and molecular docking of novel sulfonylcycloureas. J. Mol. Struct. 1236, 130327 (2021).
doi: 10.1016/j.molstruc.2021.130327
Salhi, A. et al. A correlated theoretical and electrochemical investigation of the corrosion inhibition performance of phenolic Schiff bases on mild steel in HCl solution (part B). Inorg. Chem. Commun. 152, 110684 (2023).
doi: 10.1016/j.inoche.2023.110684
Azghay, I. et al. Elucidating the corrosion inhibition mechanisms: A computational and statistical exploration of the molecular structure-efficiency relationship for phenolic Schiff bases in acidic medium on the mild steel surface. J. Mol. Liq. 393, 123648 (2024).
doi: 10.1016/j.molliq.2023.123648
Anitha, C., Sheela, C., Tharmaraj, P. & Sumathi, S. Spectroscopic studies and biological evaluation of some transition metal complexes of azo Schiff-base ligand derived from (1-phenyl-2, 3-dimethyl-4-aminopyrazol-5-one) and 5-((4-chlorophenyl) diazenyl)-2-hydroxybenzaldehyde. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 96, 493–500 (2012).
doi: 10.1016/j.saa.2012.05.053
Özdemir, Ü. Ö. et al. Characterization, antibacterial, anticarbonic anhydrase II isoenzyme, anticancer, electrochemical and computational studies of sulfonic acid hydrazide derivative and its Cu (II) complex. Inorg. Chim. Acta 423, 194–203 (2014).
doi: 10.1016/j.ica.2014.09.033
AbouEl-Enein, S. A., Emam, S. M., Polis, M. W. & Emara, E. M. Synthesis and characterization of some metal complexes derived from azo compound of 4, 4′-methylenedianiline and antipyrine: Evaluation of their biological activity on some land snail species. J. Mol. Struct. 1099, 567–578 (2015).
doi: 10.1016/j.molstruc.2015.06.072
El-Boraey, H. A. Coordination behavior of tetraaza [N4] ligand towards Co (II), Ni (II), Cu (II), Cu (I) and Pd (II) complexes: Synthesis, spectroscopic characterization and anticancer activity. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 97, 255–262 (2012).
doi: 10.1016/j.saa.2012.05.077
Mahmoud, M., Zaitone, S., Ammar, A. & Sallam, S. Synthesis, structure and antidiabetic activity of chromium (III) complexes of metformin Schiff-bases. J. Mol. Struct. 1108, 60–70 (2016).
doi: 10.1016/j.molstruc.2015.11.055
Ejidike, I. P. & Ajibade, P. A. Ruthenium (III) complexes of heterocyclic tridentate (ONN) Schiff base: Synthesis, characterization and its biological properties as an antiradical and antiproliferative agent. Int. J. Mol. Sci. 17, 60 (2016).
pubmed: 26742030 pmcid: 4730305 doi: 10.3390/ijms17010060
Bidi, M. A., Azadi, M. & Rassouli, M. An enhancement on corrosion resistance of low carbon steel by a novel bio-inhibitor (leech extract) in the H
doi: 10.1016/j.surfin.2021.101159
Gobara, M., Baraka, A. & Zaghloul, B. Green corrosion inhibitor for carbon steel in sulfuric acid medium from “Calotropis gigantiea” latex. Res. Chem. Intermed. 41, 9885–9901 (2015).
doi: 10.1007/s11164-015-1996-3
Sherif, E. S. M. Effects of 2-amino-5-(ethylthio)-1, 3, 4-thiadiazole on copper corrosion as a corrosion inhibitor in 3% NaCl solutions. Appl. Surf. Sci. 252(24), 8615–8623 (2006).
doi: 10.1016/j.apsusc.2005.11.082
Hu, L., Zhang, S., Li, W. & Hou, B. Electrochemical and thermodynamic investigation of diniconazole and triadimefon as corrosion inhibitors for copper in synthetic seawater. Corros. Sci. 52(9), 2891–2896 (2010).
doi: 10.1016/j.corsci.2010.04.038
Elyoussfi, A. et al. Study of the effect nitro and hydroxyl substituents of two imidazopyridines derivatives on inhibitory efficacy: Combining theoretical and experimental study (part A). J. Appl. Electrochem. 53(11), 2169–2184 (2023).
doi: 10.1007/s10800-023-01917-9
Dadou, S. et al. The impact of halogen substitution on the corrosion inhibition of imidazothiazole derivatives for mild steel in corrosive media (part A). Colloids Surf. A Physicochem. Eng. Asp. 687, 133451 (2024).
doi: 10.1016/j.colsurfa.2024.133451
Elyoussfi, A. et al. The effect of functional groups on the inhibitory efficacy of newly synthesized imidazopyridines compounds against the corrosion of mild steel in acidic environments: Electrochemical, thermodynamic, surface and computational investigations (part B). J. Mol. Struct. 1291, 136025 (2023).
doi: 10.1016/j.molstruc.2023.136025
Bhandari, H., Choudhary, V. & Dhawan, S. K. Influence of self-doped poly (aniline co-4-amino-3-hydroxy-naphthalene-1-sulfonic acid) on corrosion inhibition behaviour of iron in acidic medium. Synth. Metals 161(9–10), 753–762 (2011).
doi: 10.1016/j.synthmet.2011.01.026
Nazeer, A. A., Allam, N. K., Fouda, A. S. & Ashour, E. A. Effect of cysteine on the electrochemical behavior of Cu10Ni alloy in sulfide polluted environments: Experimental and theoretical aspects. Mater. Chem. Phys. 136(1), 1–9 (2012).
doi: 10.1016/j.matchemphys.2012.06.039
Bahremand, F., Shahrabi, T., Ramezanzadeh, B. & Hosseini, S. A. Sustainable development of an effective anti-corrosion film over the St12-steel surface against seawater attacks using Ce (III) ions/tri-sodium phosphate anions. Sci. Rep. 13, 12169 (2023).
pubmed: 37500672 pmcid: 10374584 doi: 10.1038/s41598-023-38540-9
Mechbal, N. et al. Correlation between corrosion inhibition efficiency in sulfuric acid medium and the molecular structures of two newly eco-friendly pyrazole derivatives on iron oxide surface. J. Mol. Liq. 331, 115656 (2021).
doi: 10.1016/j.molliq.2021.115656
Oguzie, E. E., Li, Y. & Wang, F. H. Effect of 2-amino-3-mercaptopropanoic acid (cysteine) on the corrosion behaviour of low carbon steel in sulphuric acid. Electrochim. Acta 53(2), 909–914 (2007).
doi: 10.1016/j.electacta.2007.07.076
El-Sherif, R. M. & Badawy, W. A. Mechanism of corrosion and corrosion inhibition of tin in aqueous solutions containing tartaric acid. Int. J. Electrochem. Sci. 6(12), 6469–6482 (2011).
doi: 10.1016/S1452-3981(23)19694-5
Mandour, H. S., Nazeer, A. A., Al-Hetlani, E., Madkour, M. & Abdel-Monem, Y. K. Organic nanoparticles of acetohydrazides as novel inhibitors for mild steel corrosion. New J. Chem. 42(8), 5914–5922 (2018).
doi: 10.1039/C8NJ00602D
Song, C. H., Choi, H. W., Kim, M., Jin, G. Y. & Yang, Y. S. Electrical relaxations of amorphous xKNbO∼ 3 (1–x) SiO∼ 2 (x= 0.33, 0.5, 0.67, 0.8). J. Korean Phys. Soc. 51, 674 (2007).
doi: 10.3938/jkps.51.674
Osman, N. F., Elokr, M. M., Soliman, L. I. & Zayed, H. A. Synthesis and study of electrical properties of Li
Ghosh, J., Ali, M. S. & Bhattacharya, S. Dielectric relaxation and AC conductivity of Fe-doped glassy semiconductors: Role of Fe doping on relaxation time. ECS J. Solid State Sci. Technol. 13, 033001 (2024).
doi: 10.1149/2162-8777/ad2b9e
Morsi, R. M., Basha, M. A. & Morsi, M. M. Synthesis and physical characterization of amorphous silicates in the system SiO
doi: 10.1016/j.jnoncrysol.2016.02.018
Dhahri, A., Dhahri, E. & Hlil, E. K. Electrical conductivity and dielectric behaviour of nanocrystalline La 0.6 Gd 0.1 Sr 0.3 Mn 0.75 Si 0.25 O 3. RSC Adv. 8, 9103–9111 (2018).
pubmed: 35541874 pmcid: 9078605 doi: 10.1039/C8RA00037A
Gustian, I. et al. Synthesis of polymer electrolyte membrane based on acid-base complex pair and its characteristics. J. Math. Fund. Sci. 46(1), 50–61 (2014).
doi: 10.5614/j.math.fund.sci.2014.46.1.5
Moustafa, M. G. Electrical transport properties and conduction mechanisms of semiconducting iron bismuth glasses. Ceram. Int. 42(15), 17723–17730 (2016).
doi: 10.1016/j.ceramint.2016.08.097
Refat, M. S., El-Deen, I. M., Zein, M. A., Adam, A. M. A. & Kobeasy, M. I. Spectroscopic, structural and electrical conductivity studies of Co (II), Ni (II) and Cu (II) complexes derived from 4-acetylpyridine with thiosemicarbazide. Int. J. Electrochem. Sci. 8(7), 9894–9917 (2013).
doi: 10.1016/S1452-3981(23)13021-5
Abd El Wahed, M. G. & Metwally, S. M. Physical studies of some adenine complexes. Materi. Chem. Phys. 78, 299–303 (2003).
doi: 10.1016/S0254-0584(02)00204-3
Saleh, H. A. & Younis, H. A. The effect of the double doping on the electrical properties of polyaniline. Egypt. J. Chem. 65(1), 199–205 (2022).
Ahmed, A. H. & Moustafa, M. G. Spectroscopic, morphology and electrical conductivity studies on Co (II), Ni (II), Cu (II) and Mn (II)-oxaloyldihydrazone complexes. J. Saudi Chem. Soc. 24(5), 381–392 (2020).
doi: 10.1016/j.jscs.2020.02.003
Linksky, J. P., Paul, T. R., Nohre, R. S. & Kenny, M. E. Synthesis characterization and study of electrical properties of Fe (III) and Al (III) complexes of a Schiff base. Inorg. Chem. 19, 3131 (1991).
Abd El Wahed, M. G., El Manakhly, K. A. & Amer, A. Electrical conductivity of some anthraquinone complexes. J. Mater. Sci. Lett. 15, 919–921 (1996).
doi: 10.1007/BF00241425
Hiley, C. I. et al. Incorporation of square-planar Pd
doi: 10.1039/C5TA02007G
Agarwal, R. K. & Prasad, S. Synthesis and spectral investigations of some platinum metals ions coordination compounds of 4 [N-(furan-2’-carboxalidene) amino] antipyrine thiosemicarbazone and 4 [N-(3’, 4’, 5’-trimethoxybenzalidene) amino] antipyrine thiosemicarbazone. Turk. J. Chem. 29(3), 289–298 (2005).
Gałuszka, A., Migaszewski, Z. M., Konieczka, P. & Namieśnik, J. Analytical eco-scale for assessing the greenness of analytical procedures. TrAC Trends Anal. Chem. 37, 61–72 (2012).
doi: 10.1016/j.trac.2012.03.013
Salman, B. I., Hassan, Y. F., Ali, M. F. & Batakoushy, H. A. Ultrasensitive green spectrofluorimetric approach for quantification of Hg (II) in environmental samples (water and fish samples) using cysteine@ MnO
pubmed: 36579943 doi: 10.1002/bio.4431
El Hamd, M. A. et al. Application of quality-by-design for adopting an environmentally green fluorogenic determination of benoxinate hydrochloride in eye drops and artificial aqueous humour. Sci. Rep. 13, 8559 (2023).
pubmed: 37237000 pmcid: 10219972 doi: 10.1038/s41598-023-35347-6

Auteurs

Hany A Batakoushy (HA)

Department of Pharmaceutical Analytical Chemistry, Faculty of Pharmacy, Menoufia University, Shebin Elkom, 32511, Egypt. Hany.Batakoushy@phrm.menofia.edu.eg.

Saeyda A Abouel-Enein (SA)

Department of Chemistry, Faculty of Science, Menoufia University, Shibin El Kom, Egypt.

Reham M M Morsi (RMM)

Physical Chemistry Department, National Research Centre, 33 El Bohoth St., Dokki, P.O. 12622, Giza, Egypt.

Hanem M Awad (HM)

Department Tanning Materials and Leather Technology, National Research Centre, Giza, Egypt.

Basma Ghazal (B)

Organometallic and Organometalloid Department, National Research Centre, Dokki, Cairo, 12622, Egypt.

Howida S Mandour (HS)

Physical Chemistry Department, National Research Centre, 33 El Bohoth St., Dokki, P.O. 12622, Giza, Egypt. Hmandour77@gmail.com.

Articles similaires

[Redispensing of expensive oral anticancer medicines: a practical application].

Lisanne N van Merendonk, Kübra Akgöl, Bastiaan Nuijen
1.00
Humans Antineoplastic Agents Administration, Oral Drug Costs Counterfeit Drugs

Smoking Cessation and Incident Cardiovascular Disease.

Jun Hwan Cho, Seung Yong Shin, Hoseob Kim et al.
1.00
Humans Male Smoking Cessation Cardiovascular Diseases Female
Humans United States Aged Cross-Sectional Studies Medicare Part C
1.00
Humans Yoga Low Back Pain Female Male

Classifications MeSH