Earth-abundant Li-ion cathode materials with nanoengineered microstructures.


Journal

Nature nanotechnology
ISSN: 1748-3395
Titre abrégé: Nat Nanotechnol
Pays: England
ID NLM: 101283273

Informations de publication

Date de publication:
19 Sep 2024
Historique:
received: 21 02 2024
accepted: 19 08 2024
medline: 20 9 2024
pubmed: 20 9 2024
entrez: 19 9 2024
Statut: aheadofprint

Résumé

Manganese-based materials have tremendous potential to become the next-generation lithium-ion cathode as they are Earth abundant, low cost and stable. Here we show how the mobility of manganese cations can be used to obtain a unique nanosized microstructure in large-particle-sized cathode materials with enhanced electrochemical properties. By combining atomic-resolution scanning transmission electron microscopy, four-dimensional scanning electron nanodiffraction and in situ X-ray diffraction, we show that when a partially delithiated, high-manganese-content, disordered rocksalt cathode is slightly heated, it forms a nanomosaic of partially ordered spinel domains of 3-7 nm in size, which impinge on each other at antiphase boundaries. The short coherence length of these domains removes the detrimental two-phase lithiation reaction present near 3 V in a regular spinel and turns it into a solid solution. This nanodomain structure enables good rate performance and delivers 200 mAh g

Identifiants

pubmed: 39300225
doi: 10.1038/s41565-024-01787-y
pii: 10.1038/s41565-024-01787-y
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Informations de copyright

© 2024. The Author(s).

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Auteurs

Han-Ming Hau (HM)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Tara Mishra (T)

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA. tpmishra@lbl.gov.

Colin Ophus (C)

National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Tzu-Yang Huang (TY)

Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, CA, USA.
Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Karen Bustilo (K)

National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Yingzhi Sun (Y)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Xiaochen Yang (X)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Tucker Holstun (T)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Xinye Zhao (X)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Shilong Wang (S)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Yang Ha (Y)

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Gi-Hyeok Lee (GH)

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Chengyu Song (C)

National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

John Turner (J)

National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Jianming Bai (J)

National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.

Lu Ma (L)

National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.

Ke Chen (K)

National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.

Feng Wang (F)

Applied Materials Division, Argonne National Laboratory, Lemont, IL, USA.

Wanli Yang (W)

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Bryan D McCloskey (BD)

Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, CA, USA.
Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Zijian Cai (Z)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA. zjcai@berkeley.edu.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA. zjcai@berkeley.edu.

Gerbrand Ceder (G)

Department of Materials Science and Engineering, University of California Berkeley, Berkeley, CA, USA. gceder@berkeley.edu.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA. gceder@berkeley.edu.

Classifications MeSH