Optimization study and application of box-behnken model for probing eggshell supported transition metals based catalysts to synthesize hydrazone & dihydropyrimidinones.
Box Behnken Model
Schiff base
Solid support Catalyst
Transition metals
Journal
Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288
Informations de publication
Date de publication:
07 Oct 2024
07 Oct 2024
Historique:
received:
13
08
2024
accepted:
30
09
2024
medline:
7
10
2024
pubmed:
7
10
2024
entrez:
6
10
2024
Statut:
epublish
Résumé
Solid supported catalysts have several synthetic applications. Herein, finely ground eggshells were used as a solid support for the preparation of transition metal (Ni, Zn, Cu, Sn and Co) based catalysts to synthesize 2,4-dinitrophenylhydrazone (3) and dihydropyrimidinones (7 and 8). The effect of catalyst load, time and temperature on product yield was studied. Box Behnken Model was employed, and three predictors named catalyst amount (A), reaction time (B), and reaction temperature (C) were used to find the correlation of the predictors with the yield. Second order polynomial equation was used to estimate the effects of these factors. According to the statistical model, about 12% increase in yield was observed as a result of one-unit increase in reaction time while all other terms were kept constant. The values of S (18.1616) and R
Identifiants
pubmed: 39370420
doi: 10.1038/s41598-024-74876-6
pii: 10.1038/s41598-024-74876-6
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
23270Informations de copyright
© 2024. The Author(s).
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