Multidimensional Rietveld refinement of high-pressure neutron diffraction data of PbNCN.

SNAP beamline angular dispersion high-pressure studies lead cyanamide multidimensional Rietveld refinement neutron diffraction wavelength dispersion

Journal

Journal of applied crystallography
ISSN: 0021-8898
Titre abrégé: J Appl Crystallogr
Pays: United States
ID NLM: 9876190

Informations de publication

Date de publication:
01 Oct 2024
Historique:
received: 14 11 2023
accepted: 02 08 2024
medline: 10 10 2024
pubmed: 10 10 2024
entrez: 10 10 2024
Statut: epublish

Résumé

High-pressure neutron powder diffraction data from PbNCN were collected on the high-pressure diffraction beamline SNAP located at the Spallation Neutron Source (SNS) of Oak Ridge National Laboratory (Tennessee, USA). The diffraction data were analyzed using the novel method of multidimensional (two dimensions for now, potentially more in the future) Rietveld refinement and, for comparison, employing the conventional Rietveld method. To achieve two-dimensional analysis, a detailed description of the SNAP instrument characteristics was created, serving as an instrument parameter file, and then yielding both cell and spatial parameters as refined under pressure for the first time for solid-state cyanamides/carbodi-imides. The bulk modulus

Identifiants

pubmed: 39387076
doi: 10.1107/S1600576724007635
pii: S1600576724007635
pmc: PMC11460395
doi:

Types de publication

Journal Article

Langues

eng

Pagination

1436-1445

Informations de copyright

© Yannick Meinerzhagen et al. 2024.

Auteurs

Yannick Meinerzhagen (Y)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Katharina Eickmeier (K)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Peter C Müller (PC)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Jan Hempelmann (J)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Andreas Houben (A)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Richard Dronskowski (R)

Institute of Inorganic Chemistry RWTH Aachen University 52056Aachen Germany.

Classifications MeSH