Efficient Molecular Rectification in Metal-Molecules-Semimetal Junctions.

Molecular rectification is expected to be observed in metal-molecule-metal tunnel junctions in which the resonance levels responsible for their transport properties are spatially localized asymmetrically with respect to the leads. Yet, effects such as electrostatic screening and formation of metal induced gap states reduce the magnitude of rectification that can be realized in such junctions. Here we suggest that junctions of the form metal-molecule(s)-semimetal mitigate these interfacial effects. We report current rectification in junctions based on the semimetal bismuth (Bi) with high rectification ratios (>10