Mercaptopropionic acid-capped CdZnTe Quantum dots as Fluorescence Probe for Sensitive Detection of Cr(III) ions.

Aqueous Method CdZnTe Quantum dots Cr(III) Fluorescence Quenching

Journal

Journal of fluorescence
ISSN: 1573-4994
Titre abrégé: J Fluoresc
Pays: Netherlands
ID NLM: 9201341

Informations de publication

Date de publication:
16 Oct 2024
Historique:
received: 18 08 2024
accepted: 26 09 2024
medline: 16 10 2024
pubmed: 16 10 2024
entrez: 16 10 2024
Statut: aheadofprint

Résumé

Although Cr(III) ions are essential for the human body, excessive amounts can lead to skin inflammation, allergic reactions, and genotoxicity. A highly sensitive fluorescence probe was developed using mercaptopropionic acid (MPA) capped CdZnTe quantum dots (QDs) synthesized via an aqueous solution heating method for precise detection of Cr(III) ions. The synthesized MPA-CdZnTe QDs had a size of 2.38 ± 0.13 nm and exhibited a zinc-blende structure, with MPA molecules effectively capping the surface through Cd-S bonds. Investigation into the effects of reflux times and solution pH on the absorption and fluorescence spectra of MPA-CdZnTe QDs revealed the occurrence of Ostwald ripening during prolonged reflux processes. The quantum yield (QY) of the synthesized CdZnTe QDs could reach 89%, and the QY was higher under acidic conditions than alkaline. Leveraging the quenching effect of Cr(III) ions on MPA-CdZnTe QDs, a robust method for the quantitative detection of trace amounts of Cr(III) ions was established. Linear quenching behavior was observed within the concentration range of 3.33 × 10

Identifiants

pubmed: 39412728
doi: 10.1007/s10895-024-03970-9
pii: 10.1007/s10895-024-03970-9
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : National Natural Science Foundation of China
ID : 51002012

Informations de copyright

© 2024. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.

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Auteurs

Min Wu (M)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China.

Dongmei Zeng (D)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China. zengdongmei@bipt.edu.cn.

Shuo Han (S)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China.

Minmin Zou (M)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China.

Ting Zhang (T)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China.

You Zhang (Y)

College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, P. R. China.

Classifications MeSH