From Corn Starch to Nanostructured Magnetic Laser-Induced Graphene Nanocomposite.
biodegradables
bioderived
core–shell nanoparticles
iron‐catalytic
laser‐induced graphene
magnetic
starch
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
18 Oct 2024
18 Oct 2024
Historique:
revised:
02
10
2024
received:
26
06
2024
medline:
18
10
2024
pubmed:
18
10
2024
entrez:
18
10
2024
Statut:
aheadofprint
Résumé
Laser-Induced Graphene (LIG) is a 3D, conductive, porous material with a high surface area, produced by laser irradiation of synthetic polymers with high thermal stability. Recently, the focus has shifted toward sustainable bioderived and biodegradable precursors, such as lignocellulosic materials. Despite starch being an abundant and cost-effective biopolymer, direct laser scribing on starch-derived precursors has not yet been explored. This study demonstrates that corn starch bioplastic (SP) can be converted into LIG through iron-catalyzed laser-induced pyrolysis, using Fe(NO₃)₃ as an additive. The impact of iron additive concentration on LIG formation and on its properties is investigated, with only certain concentrations yielding reliable and reproducible results. The investigation of LIG's crystal structure reveals magnetic and non-magnetic iron phases: γ-Fe₂O₃, Fe₃C, and Fe(C). The LIG nanocomposite exhibits soft magnetic properties, with a coercive field of H
Identifiants
pubmed: 39420870
doi: 10.1002/smll.202405252
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2405252Subventions
Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca
ID : CCI 2014IT16M2OP005
Organisme : H2020 Excellent Science
ID : 899349
Informations de copyright
© 2024 The Author(s). Small published by Wiley‐VCH GmbH.
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