An Alternative Polymer Material to PVDF Binder and Carbon Additive in Li-Ion Battery Positive Electrode.

Li‐ion battery positive electrode Poly(3,4‐ethylenedioxythiophene) (PEDOT) mixed conducting polymer olivine LiFe1‐yMnyPO4 polymer binder

Journal

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
ISSN: 2198-3844
Titre abrégé: Adv Sci (Weinh)
Pays: Germany
ID NLM: 101664569

Informations de publication

Date de publication:
21 Oct 2024
Historique:
revised: 29 09 2024
received: 08 08 2024
medline: 21 10 2024
pubmed: 21 10 2024
entrez: 21 10 2024
Statut: aheadofprint

Résumé

Li-ion battery performance relies fundamentally on modulation at the microstructure and interface levels of the composite electrodes. Correspondingly, the binder is a crucial component for mechanical integrity of the electrode, serving to interconnect the active material and conductive additive and to firmly attach this composite to the current collector. However, the commonly used poly(vinylidenefluoride) (PVDF) binder presents several limitations, including the use of toxic solvent during processing, a low electrical conductivity which for compensation requires the addition of carbon black, and weak interactions with active materials and collectors. This study investigates Poly(3,4-ethylenedioxythiophene):poly[(4-styrenesulfonyl) (trifluoromethylsulfonyl) imide] (PEDOT:PSSTFSI) as an alternative binder and conductive additive, in replacement of both PVDF and carbon black, in Li-ion batteries with LiFe

Identifiants

pubmed: 39429199
doi: 10.1002/advs.202409403
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2409403

Subventions

Organisme : HORIZON EUROPE Marie Sklodowska-Curie Actions
ID : Cofund DESTINY Grant No. 945357
Organisme : Conseil Régional Aquitaine
ID : AAPR2021A-2020-11998810
Organisme : Agence Nationale de la Recherche
ID : STORE-EX Labex project ANR-10-LABX-76-01

Informations de copyright

© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.

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Auteurs

Ivone Marselina Nugraha (IM)

Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, Pessac, F-33600, France.
Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, Pessac, F-33600, France.
RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, CNRS FR 3459, Amiens Cedex 1, 80039, France.
ALISTORE-ERI, FR CNRS 3104, 33 Rue Saint-Leu, Amiens Cedex 1, 80039, France.

Jacob Olchowka (J)

Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, Pessac, F-33600, France.
RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, CNRS FR 3459, Amiens Cedex 1, 80039, France.
ALISTORE-ERI, FR CNRS 3104, 33 Rue Saint-Leu, Amiens Cedex 1, 80039, France.

Cyril Brochon (C)

Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, Pessac, F-33600, France.

Delphine Flahaut (D)

RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, CNRS FR 3459, Amiens Cedex 1, 80039, France.
ALISTORE-ERI, FR CNRS 3104, 33 Rue Saint-Leu, Amiens Cedex 1, 80039, France.
IPREM - UMR 5254 UPPA, CNRS - ECP Technopole Helioparc, 2, av. Pdt P. Angot, PAU Cedex 09, 64 053, France.

Mélanie Bousquet (M)

Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, Pessac, F-33600, France.

Benjamin Cabannes-Boue (B)

Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, Pessac, F-33600, France.

Rafael Bianchini Nuernberg (R)

Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, Pessac, F-33600, France.

Éric Cloutet (É)

Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, Pessac, F-33600, France.

Laurence Croguennec (L)

Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, Pessac, F-33600, France.
RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, CNRS FR 3459, Amiens Cedex 1, 80039, France.
ALISTORE-ERI, FR CNRS 3104, 33 Rue Saint-Leu, Amiens Cedex 1, 80039, France.

Classifications MeSH