Molecular imprinting sensor based on zeolitic imidazolate framework derived Co, N-doped carbon loaded on reduced graphene oxide toward the determination of dopamine.


Journal

Mikrochimica acta
ISSN: 1436-5073
Titre abrégé: Mikrochim Acta
Pays: Austria
ID NLM: 7808782

Informations de publication

Date de publication:
22 Oct 2024
Historique:
received: 06 08 2024
accepted: 08 10 2024
medline: 22 10 2024
pubmed: 22 10 2024
entrez: 22 10 2024
Statut: epublish

Résumé

A novel voltammetric sensor designed for dopamine (DA) detection is presented utilizing a combination of zeolitic imidazolate framework (ZIF-67) derived cobalt and nitrogen-doped carbon on reduced graphene oxide (Co-N-C/rGO). ZIF-67 cubic crystals were synthesized in situ and deposited onto the graphene oxide (GO) surface through room-temperature reactions. High-temperature calcination resulted in partially collapsed cubic and spherical carbon, while simultaneously reducing GO to rGO. A molecular imprinting resorcinol polymer (MIP) membrane was also in situ applied to the Co-N-C/rGO/glassy carbon electrode (GCE) via electropolymerization. Analyses using cyclic voltammetry, electrochemical impedance, and pulse voltammetry reveal that the modified MIP/Co-N-C/rGO/GCE electrodes show improved electroconductivity and notable electrochemical reactivity towards dopamine. After optimizing detection parameters, the sensor demonstrates a wide linear detection range of 0.01-0.5 and 0.5-100 μmol/L, with a limit of detection (LOD) of 3.33 nmol/L (S/N = 3). Additionally, the sensor displays strong robustness, including excellent selectivity, significant resistance to interference, and long-term stability. It also shows satisfactory recovery in detecting spiked real samples.

Identifiants

pubmed: 39436464
doi: 10.1007/s00604-024-06759-6
pii: 10.1007/s00604-024-06759-6
doi:

Substances chimiques

Graphite 7782-42-5
Dopamine VTD58H1Z2X
Zeolites 1318-02-1
Cobalt 3G0H8C9362
Imidazoles 0
graphene oxide 0
Carbon 7440-44-0
Nitrogen N762921K75
Molecularly Imprinted Polymers 0
Metal-Organic Frameworks 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

688

Subventions

Organisme : National Natural Science Foundation of China
ID : 22164003
Organisme : Natural Science Foundation of Gansu Province
ID : 23JRRA1228
Organisme : Higher Education Innovation Fund Project of Gansu Province
ID : 2023A-097, 2021B-177
Organisme : Higher Education Innovation Fund Project of Gansu Province
ID : 2023A-097, 2021B-177
Organisme : Science and Technology Major Project of Gansu Province
ID : 21ZD4FA032
Organisme : Key Talent Project of Gansu Province
ID : 2022RCXM085

Informations de copyright

© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.

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Auteurs

Shufang Ren (S)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China. rsf@gsupl.edu.cn.

Xiaohang Liu (X)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China.

Yahui Liu (Y)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China.

Junpeng Zhao (J)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China.

Yuan Zhang (Y)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China.

Zhixiang Zheng (Z)

Key Laboratory of Evidence Science Techniques Research and Application of Gansu Province, Gansu University of Political Science and Law, Lanzhou, 730070, China.

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