Active Quantum Biomaterials-Enhanced Microrobots for Food Safety.

affinity peptide endotoxins fluorescence microrobots quantum materials

Journal

Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338

Informations de publication

Date de publication:
24 Oct 2024
Historique:
revised: 22 09 2024
received: 25 05 2024
medline: 25 10 2024
pubmed: 25 10 2024
entrez: 25 10 2024
Statut: aheadofprint

Résumé

Timely disruptive tools for the detection of pathogens in foods are needed to face global health and economic challenges. Herein, the utilization of quantum biomaterials-enhanced microrobots (QBEMRs) as autonomous mobile sensors designed for the precise detection of endotoxins originating from Salmonella enterica (S. enterica) as an indicator species for food-borne contamination globally is presented. A fluorescent molecule-labeled affinity peptide functions as a specific probe, is quenched upon binding to the surface of QBEMRs. Owing to its selective affinity for endotoxin, in the presence of S. enterica the fluorescence is restored and easy to observe and quantifies optical color change to indicate the presence of Salmonella. The devised approach is designed to achieve highly sensitive detection of the S. enterica serovar Typhimurium endotoxin with exquisite selectivity through the utilization of QBEMRs. Notably, no fluorescence signal is observed in the presence of endotoxins bearing similar structural characteristics, highlighting the selectivity of the approach during food sample analysis. Technically, the strategy is implemented in microplate readers to extend microrobots-based approaches to the routine laboratory. This new platform can provide fast and anticipated results in food safety.

Identifiants

pubmed: 39449211
doi: 10.1002/smll.202404248
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2404248

Subventions

Organisme : Community of Madrid
ID : CM/JIN/2021-012
Organisme : Universidad de Alcalá
ID : UAH EPU-INV-UAH/2022/003
Organisme : Ministry of Health of Czech Republic
ID : NU21-08-00407
Organisme : ERDF/ESF project TECHSCALE
ID : CZ.02.01.01/00/22_008/0004587
Organisme : European Union under the REFRESH -Research Excellence For REgion Sustainability and High-tech Industries
ID : CZ.10.03.01/00/22_003/0000048
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : GrantPID2020-118154GB-I00fundedbyMCIN/AEI/10.13039/501100011033
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : grantCNS2023-144653fundedbyMCIN/AEI/10.13039/501100011033andtheEuropeanUnion"NextGenerationEU"/PRTR
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : TED2021-132720B-I00,fundedbyMCIN/AEI/10.13039/501100011033andtheEuropeanUnion"NextGenerationEU"/PRTR
Organisme : Junta de Comunidades de Castilla la Mancha
ID : SBPLY/23/180225/000058

Informations de copyright

© 2024 The Author(s). Small published by Wiley‐VCH GmbH.

Références

P. Pashazadeh, A. Mokhtarzadeh, M. Hasanzadeh, M. Hejazi, M. Hashemi, M. de la Guardia, Biosens. Bioelectron. 2017, 87, 1050.
B. Stephen Inbaraj, B. H. Chen, J. Food Drug Anal. 2016, 24, 15.
J. Guo, E. W. C. Chan, S. Chen, Z. Zeng, Front. Microbiol. 2017, 8, 8.
T Yang, S. Wu, K. Li, J. B. Shuai, Z. H. Ye, X. Z., Chinase J. Prevent. Vet. Med. 2020, 42, 584.
Multi‐Country Outbreak of Salmonella Typhimurium Linked to Chocolate Products – Europe and the United States of America, World Health Organization, 2022.
R. Johnson, E. Mylona, G. Frankel, Cell. Microbiol. 2018, 20, e12939.
A Commission Regulation EC No 2160/2003 of 17 2003 on the Control of Salmonella and Other Specified Food‐Borne Zoonotic Agents, Regulation, 2003.
Union European (EU), COMMISSION REGULATION (EC) No 2073/2005 of 15 November 2005 on Microbiological Criteria for Foodstuffs, Official Journal of the European Union 2005.
R. Kumar, P. K. Surendran, N. Thampuran, Lett. Appl. Microbiol. 2008, 46, 221.
K. N. Kasturi, T. Drgon, Appl. Environ. Microbiol. 2017, 83, 14.
M. Sousa, R. Rocha, D. Araújo, J. Castro, A. Barbosa, F Nuno, L. Azevedo, C. A. Cerqueira, Foodborne Pathog. Dis. 2024, 21, 298.
L. Croci, E. Delibato, G. Volpe, D. De Medici, G. Palleschi, Appl. Environ. Microbiol. 2004, 70, 3.
R. L. Brigmon, S. G. Zam, H. R. Wilson, Poultry Sci. 1995, 74, 1232.
K. Saikia, P. Deb, E. Kalita, Phys. Scr. 2013, 87, 065802.
D. Jana, C. Matti, J. He, L. Sagle, Anal. Chem. 2015, 87, 3964.
S. Unser, I. Bruzas, J. He, L. Sagle, Sensors 2015, 15, 15684.
X. T. Zheng, A. Ananthanarayanan, K. Q. Luo, P. Chen, Small 2015, 11, 1620.
E. C. Alocilja, S. M. Radke, Biosens. Bioelectron. 2003, 18, 841.
G. Liu, X. Mao, J. A. Phillips, H. Xu, W. Tan, L. Zeng, Anal. Chem. 2009, 81, 10013.
H. Chen, Z. Wang, S. Zong, P. Chen, D. Zhu, L. Wu, Y. Cui, Nanoscale 2015, 7, 15477.
J. Shi, C. Chan, Y. Pang, W. Ye, F. Tian, J. Lyu, Y. Zhang, M. Yang, Biosens. Bioelectron. 2015, 67, 595.
K. Agarwal, H. Rai, S. Mondal, Mater. Res. Express 2023, 10, 062001.
Y. Chen, Y. Cao, C. Ma, J. J. Zhu, Mater. Chem. Front. 2020, 4, 369.
A. Ananthanarayanan, X. Wang, P. Routh, B. Sana, S. Lim, D. H. Kim, K. H. Lim, J. Li, P. Chen, Adv. Funct. Mater. 2014, 24, 3021.
R. Xie, Z. Wang, W. Zhou, Y. Liu, L. Fan, Y. Li, X. Li, Analyt. Methods 2016, 8, 4001.
L. Li, G. Wu, T. Hong, Z. Yin, D. Sun, E. S. Abdel‐Halim, J. J. Zhu, ACS Appl. Mater. Interfaces 2014, 6, 2858.
J. Zhao, L. Zhao, C. Lan, S. Zhao, Sensors Act., B: Chem. 2016, 223, 246.
X. Zhang, C. Chen, J. Wu, H. Ju, ACS Appl. Mater. Interfaces 2019, 11, 13581.
Z. Li, L. Bai, C. Zhou, X. Yan, L. Mair, A. Zhang, L. Zhang, Part. Part. Syst. Charact. 2017, 34, 1600277.
S. Fu, X. Zhang, Y. Xie, J. Wu, H. Ju, Nanoscale 2017, 9, 9026.
E. Morales‐Narváez, M. Guix, M. Medina‐Sánchez, C. C. Mayorga‐Martinez, A. Merkoçi, Small 2014, 10, 2542.
M. Beltrán‐Gastélum, B. Esteban‐Fernández de Ávila, H. Gong, P. L. Venugopalan, T. Hianik, J. Wang, V. Subjakova, ChemPhysChem 2019, 20, 3177.
B. Jurado‐Sánchez, M. Pacheco, J. Rojo, A. Escarpa, Angew. Chem. Int. Ed. 2017, 56, 6957.
M. Pacheco, B. Jurado‐Sánchez, A. Escarpa, Anal. Chem. 2018, 90, 2912.
M. Pacheco, B. Jurado‐Sánchez, A. Escarpa, Microchim. Acta 2022, 189, 194.
M. Pacheco, V. de la Asunción‐Nadal, B. Jurado‐Sánchez, A. Escarpa, Biosens. Bioelectron. 2020, 165, 112286.
R. Maria‐Hormigos, B. Jurado‐Sánchez, A. Escarpa, Chem. Commun. 2019, 55, 6795.
J. Jyoti, J. Munoz, M. Pumera, ACS Appl. Mater. Interfaces 2023, 15, 58548.
B. D. Mansuriya, Z. Altintas, Sensors 2020, 20, 1072.
Y. R. Kumar, K. Deshmukh, K. K. Sadasivuni, S. K. K. Pasha, RSC Adv. 2020, 10, 23861.
S. Chattopadhyay, M. Choudhary, H. Singh, Anal. Biochem. 2022, 654, 114801.
J. Mujtaba, J. Liu, K. K. Dey, T. Li, R. Chakraborty, K. Xu, D. Makarov, R. A. Barmin, D. A. Gorin, V. P. Tolstoy, G. Huang, A. A. Solovev, Y. Mei, Adv. Mater. 2021, 33, 2007465.
B. Jurado‐Sánchez, Biosensors 2018, 8, 66.
F. Zha, T. Wang, M. Luo, J. Guan, Micromachines 2018, 9, 78.
B. Xu, B. Zhang, L. Wang, G. Huang, Y. Mei, Adv. Funct. Mater. 2018, 28, 1705872.
J. Simmchen, V. Magdanz, S. Sanchez, S. Chokmaviroj, D. Ruiz‐Molina, A. Baeza, O. G. Schmidt, RSC Adv. 2014, 4, 20334.
H. Wang, G. Zhao, M. Pumera, J. Phys. Chem. C 2014, 118, 5268.
P. Kreissl, C. Holm, J. De Graaf, J. Chem. Phys. 2016, 144, 204902.
S. Naeem, F. Naeem, J. Zhang, J. Mujtaba, K. Xu, G. Huang, A. A. Solovev, Y. Mei, Micromachines 2020, 11, 643.
F. Cao, Y. Li, J. Wu, W. Liu, T. Ngai, Soft Matter 2022, 18, 236.
J. K. Kim, S. J. Kim, M. J. Park, S. Bae, S. P. Cho, Q. G. Du, D. H. Wang, J. H. Park, B. H. Hong, Sci. Rep. 2015, 5, 14274.
A. Suryawanshi, M. Biswal, D. Mhamane, R. Gokhale, S. Patil, D. Guin, S. Ogale, Nanoscale 2014, 6, 11664.
S. M. Saad, J. Abdullah, S. A. Rashid, Y. W. Fen, F. Salam, L. H. Yih, Microchim. Acta 2019, 186, 804.
D. Choi, R. S. W. Tsang, M. H. Ng, J. Appl. Bacteriol. 1992, 72, 134.
S. Sannigrahi, S. K. Arumugasamy, J. K. Mathiyarasu, K. Suthindhiran, Mater. Sci. Engin. C 2020, 114, 111071.
X. Wang, P. Zhu, F. Pi, H. Jiang, J. Shao, Y. Zhang, X. Sun, Biosens. Bioelectron. 2016, 81, 349.
S. Wu, J. P. Hulme, Int. J. Mol. Sci. 2021, 22, 3499.
M. Wang, Y. Zhang, F. Tian, X. Liu, S. Du, G. Ren, Foods 2021, 10, 2402.
K. M. Lee, M. Runyon, T. J. Herrman, R. Phillips, J. Hsieh, Food Control 2015, 47, 264.
Y. Shen, L. Xu, Y. Li, Compr. Rev. Food Sci. Food Saf. 2021, 20, 149.
J. Du, Adv. Engin. Technol. Res. 2023, 6, 2023.
V. de la Asunción‐Nadal, R. Maria‐Hormigos, B. Jurado‐Sánchez, A. Escarpa, Appl. Mater. Today 2022, 29, 101664.
D. Presutti, T. Agarwal, A. Zarepour, N. Celikkin, S. Hooshmand, C. Nayak, M. Ghomi, A. Zarrabi, M. Costantini, B. Behera, T. K. Maiti, Materials 2022, 15, 337.
K. Yuan, Z. Jiang, B. Jurado‐Sánchez, A. Escarpa, Chem.–Eur. J. 2020, 26, 2309.
L. Cai, D. Xu, Z. Zhang, N. Li, Y. Zhao, Research 2023, 6, 0044.
Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, G. Chen, Carbon 2012, 50, 4738.
Y. Wang, C. C. Mayorga‐Martinez, J. G. S. Moo, M. Pumera, ACS Appl. Energy Mater. 2018, 1, 3443.
K. M. Manesh, M. Cardona, R. Yuan, M. Clark, D. Kagan, S. Balasubramanian, J. Wang, ACS Nano 2010, 4, 1799.
A. Martín, B. Jurado‐Sánchez, A. Escarpa, J. Wang, Small 2015, 11, 3568.

Auteurs

Department of Analytical Chemistry, Physical Chemistry, and Chemical Engineering, Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.
Future Energy and Innovation Laboratory, Central European Institute of Technology, Brno University of Technology (CEITEC-BUT), Brno, 61200, Czech Republic.

Alberto-Rodríguez Castillo (AR)

Department of Analytical Chemistry, Physical Chemistry, and Chemical Engineering, Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.

Beatriz Jurado-Sánchez (B)

Department of Analytical Chemistry, Physical Chemistry, and Chemical Engineering, Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.
Chemical Research Institute "Andres M. Del Río,", Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.

Martin Pumera (M)

Future Energy and Innovation Laboratory, Central European Institute of Technology, Brno University of Technology (CEITEC-BUT), Brno, 61200, Czech Republic.
Advanced Nanorobots & Multiscale Robotics Laboratory, Faculty of Electrical Engineering and Computer Science, VSB-Technical University of Ostrava, 17. Listopadu 2172/15, Ostrava, 70800, Czech Republic.
Department of Medical Research, China Medical University Hospital, China Medical University, No. 91 Hsueh-Shih Road, Taichung, 40402, Taiwan.

Alberto Escarpa (A)

Department of Analytical Chemistry, Physical Chemistry, and Chemical Engineering, Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.
Chemical Research Institute "Andres M. Del Río,", Universidad de Alcala, Alcala de Henares, Madrid, E-28802, Spain.

Classifications MeSH