Remote chirality transfer in low-dimensional hybrid metal halide semiconductors.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
25 Oct 2024
25 Oct 2024
Historique:
received:
02
04
2024
accepted:
26
09
2024
medline:
26
10
2024
pubmed:
26
10
2024
entrez:
25
10
2024
Statut:
aheadofprint
Résumé
In hybrid metal halide perovskites, chiroptical properties typically arise from structural symmetry breaking by incorporating a chiral A-site organic cation within the structure, which may limit the compositional space. Here we demonstrate highly efficient remote chirality transfer where chirality is imposed on an otherwise achiral hybrid metal halide semiconductor by a proximal chiral molecule that is not interspersed as part of the structure yet leads to large circular dichroism dissymmetry factors (g
Identifiants
pubmed: 39455700
doi: 10.1038/s41557-024-01662-2
pii: 10.1038/s41557-024-01662-2
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : DOE | SC | Basic Energy Sciences (BES)
ID : CHOISE EFRC
Organisme : DOE | Office of Science (SC)
ID : DE-AC36-08GO28308
Informations de copyright
© 2024. The Author(s), under exclusive licence to Springer Nature Limited.
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