Multicompartmentalized Micellar Structures by Gold Nanoparticles Grafted with Diblock-Copolymer Ligands.
Block copolymers
Colloids
Gold nanoparticles
Multicompartmentalized structures
Surface-pinned micelles
Journal
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN: 1439-7641
Titre abrégé: Chemphyschem
Pays: Germany
ID NLM: 100954211
Informations de publication
Date de publication:
28 Oct 2024
28 Oct 2024
Historique:
revised:
28
08
2024
received:
23
07
2024
medline:
28
10
2024
pubmed:
28
10
2024
entrez:
28
10
2024
Statut:
aheadofprint
Résumé
We study the formation of hybrid polymer/inorganic colloidal particles with multicompartmentalized structure, comprising gold nanoparticles grafted with polystyrene-block-poly(methacrylic acid) (PSt-block-PMAA) diblock copolymer ligands, through experiments and molecular dynamics simulations. The PMAA blocks segregate into small satellite-like domains that are separated by the polystyrene spacer from the gold nanoparticle core. Dialysis against water leads to the re-configuration of the formed structures into unique, kinetically trapped pinned-micelle-decorated nanoparticles with internal structure.
Identifiants
pubmed: 39467074
doi: 10.1002/cphc.202400747
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202400747Subventions
Organisme : Fonds der Chemischen Industrie
Organisme : Deutsche Forschungsgemeinschaft
ID : 445740352
Organisme : Deutsche Forschungsgemeinschaft
ID : 470113688
Informations de copyright
© 2024 The Authors. ChemPhysChem published by Wiley-VCH GmbH.
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