Chromatic covalent organic frameworks enabling in-vivo chemical tomography.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
28 Oct 2024
Historique:
received: 29 01 2024
accepted: 15 10 2024
medline: 29 10 2024
pubmed: 29 10 2024
entrez: 29 10 2024
Statut: epublish

Résumé

Covalent organic frameworks designed as chromatic sensors offer opportunities to probe biological interfaces, particularly when combined with biocompatible matrices. Particularly compelling is the prospect of chemical tomography - or the 3D spatial mapping of chemical detail within the complex environment of living systems. Herein, we demonstrate a chromic Covalent Organic Framework (COF) integrated within silk fibroin (SF) microneedles that probe plant vasculature, sense the alkalization of vascular fluid as a biomarker for drought stress, and provide a 3D in-vivo mapping of chemical gradients using smartphone technology. A series of Schiff base COFs with tunable pKa ranging from 5.6 to 7.6 enable conical, optically transparent SF microneedles with COF coatings of 120 to 950 nm to probe vascular fluid and the surrounding tissues of tobacco and tomato plants. The conical design allows for 3D mapping of the chemical environment (such as pH) at standoff distances from the plant, enabling in-vivo chemical tomography. Chromatic COF sensors of this type will enable multidimensional chemical mapping of previously inaccessible and complex environments.

Identifiants

pubmed: 39468049
doi: 10.1038/s41467-024-53532-7
pii: 10.1038/s41467-024-53532-7
doi:

Substances chimiques

Fibroins 9007-76-5
Schiff Bases 0
Metal-Organic Frameworks 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

9300

Informations de copyright

© 2024. The Author(s).

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Auteurs

Song Wang (S)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Yangyang Han (Y)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Vaishnavi Amarr Reddy (VA)

Temasek Life Sciences Laboratory Limited, Singapore, 117604, Singapore.

Mervin Chun-Yi Ang (MC)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Gabriel Sánchez-Velázquez (G)

Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.

Jolly Madathiparambil Saju (JM)

Temasek Life Sciences Laboratory Limited, Singapore, 117604, Singapore.

Yunteng Cao (Y)

Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.

Duc Thinh Khong (DT)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Praveen Kumar Jayapal (PK)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Raju Cheerlavancha (R)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Suh In Loh (SI)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Gajendra Pratap Singh (GP)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore.

Daisuke Urano (D)

Temasek Life Sciences Laboratory Limited, Singapore, 117604, Singapore.

Sarojam Rajani (S)

Temasek Life Sciences Laboratory Limited, Singapore, 117604, Singapore.

Benedetto Marelli (B)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore. bmarelli@mit.edu.
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA. bmarelli@mit.edu.

Michael S Strano (MS)

Disruptive & Sustainable Technologies for Agricultural Precision, Singapore-MIT Alliance for Research and Technology Centre, Singapore, 138602, Singapore. strano@mit.edu.
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA. strano@mit.edu.

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