Chemoproteogenomic stratification of the missense variant cysteinome.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
28 Oct 2024
Historique:
received: 28 08 2023
accepted: 15 10 2024
medline: 29 10 2024
pubmed: 29 10 2024
entrez: 29 10 2024
Statut: epublish

Résumé

Cancer genomes are rife with genetic variants; one key outcome of this variation is widespread gain-of-cysteine mutations. These acquired cysteines can be both driver mutations and sites targeted by precision therapies. However, despite their ubiquity, nearly all acquired cysteines remain unidentified via chemoproteomics; identification is a critical step to enable functional analysis, including assessment of potential druggability and susceptibility to oxidation. Here, we pair cysteine chemoproteomics-a technique that enables proteome-wide pinpointing of functional, redox sensitive, and potentially druggable residues-with genomics to reveal the hidden landscape of cysteine genetic variation. Our chemoproteogenomics platform integrates chemoproteomic, whole exome, and RNA-seq data, with a customized two-stage false discovery rate (FDR) error controlled proteomic search, which is further enhanced with a user-friendly FragPipe interface. Chemoproteogenomics analysis reveals that cysteine acquisition is a ubiquitous feature of both healthy and cancer genomes that is further elevated in the context of decreased DNA repair. Reference cysteines proximal to missense variants are also found to be pervasive, supporting heretofore untapped opportunities for variant-specific chemical probe development campaigns. As chemoproteogenomics is further distinguished by sample-matched combinatorial variant databases and is compatible with redox proteomics and small molecule screening, we expect widespread utility in guiding proteoform-specific biology and therapeutic discovery.

Identifiants

pubmed: 39468056
doi: 10.1038/s41467-024-53520-x
pii: 10.1038/s41467-024-53520-x
doi:

Substances chimiques

Cysteine K848JZ4886
Proteome 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

9284

Subventions

Organisme : Arnold and Mabel Beckman Foundation
ID : Beckman Ynoung Investigator Award
Organisme : V Foundation for Cancer Research (V Foundation)
ID : V2019-017
Organisme : UC | UCLA | Jonsson Comprehensive Cancer Center (UCLA Jonsson Comprehensive Cancer Center)
ID : Seed Grant
Organisme : U.S. Department of Health & Human Services | NIH | National Institute of General Medical Sciences (NIGMS)
ID : T32GM136614
Organisme : U.S. Department of Health & Human Services | NIH | National Institute of General Medical Sciences (NIGMS)
ID : R01-GM094231
Organisme : U.S. Department of Health & Human Services | NIH | National Cancer Institute (NCI)
ID : U24-CA271037
Organisme : U.S. Department of Energy (DOE)
ID : DE-FC02-02ER63421

Informations de copyright

© 2024. The Author(s).

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Auteurs

Heta Desai (H)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.
Molecular Biology Institute, UCLA, Los Angeles, CA, USA.

Katrina H Andrews (KH)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.

Kristina V Bergersen (KV)

Department of Pathology and Laboratory Medicine, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.

Samuel Ofori (S)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.

Fengchao Yu (F)

Department of Pathology, University of Michigan, Ann Arbor, MI, USA.

Flowreen Shikwana (F)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.
Department of Chemistry and Biochemistry, UCLA, Los Angeles, CA, USA.

Mark A Arbing (MA)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.
UCLA-DOE Institute for Genomics and Proteomics, UCLA, Los Angeles, CA, USA.

Lisa M Boatner (LM)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.
Department of Chemistry and Biochemistry, UCLA, Los Angeles, CA, USA.

Miranda Villanueva (M)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.
Molecular Biology Institute, UCLA, Los Angeles, CA, USA.

Nicholas Ung (N)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.

Elaine F Reed (EF)

Department of Pathology and Laboratory Medicine, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA.

Alexey I Nesvizhskii (AI)

Department of Pathology, University of Michigan, Ann Arbor, MI, USA.
Department of Computational Medicine and Bioinformatics, University of Michigan, Ann Arbor, MI, USA.

Keriann M Backus (KM)

Biological Chemistry Department, David Geffen School of Medicine, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.
Molecular Biology Institute, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.
Department of Chemistry and Biochemistry, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.
UCLA-DOE Institute for Genomics and Proteomics, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.
Eli and Edythe Broad Center of Regenerative Medicine and Stem Cell Research, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.
Jonsson Comprehensive Cancer Center, UCLA, Los Angeles, CA, USA. kbackus@mednet.ucla.edu.

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