Integrating Compositional and Structural Diversity in Heterometallic Titanium Frameworks by Metal Exchange Methods.

The increasing use of Metal-Organic Frameworks (MOFs) in separation, catalysis, or storage is linked to the targeted modification of their composition or porosity metrics. While modification of pore shape and size necessarily implies the assembly of alternative nets, compositional changes often rely on postsynthetic modification adapted to the functionalization or exchange of the organic linker or the modification of the inorganic cluster by metal exchange methods. We describe an alternative methodology that enables the integration of both types of modification, structural and compositional, in titanium MOFs by metal exchange reaction of the heterometallic cluster Ti