Benzylamides and piperazinoarylamides of ibuprofen as fatty acid amide hydrolase inhibitors.


Journal

Journal of enzyme inhibition and medicinal chemistry
ISSN: 1475-6374
Titre abrégé: J Enzyme Inhib Med Chem
Pays: England
ID NLM: 101150203

Informations de publication

Date de publication:
Dec 2019
Historique:
entrez: 29 1 2019
pubmed: 29 1 2019
medline: 8 5 2019
Statut: ppublish

Résumé

Fatty Acid Amide Hydrolase (FAAH) is a serine hydrolase that plays a key role in controlling endogenous levels of endocannabinoids. FAAH inhibition is considered a powerful approach to enhance the endocannabinoid signalling, and therefore it has been largely studied as a potential target for the treatment of neurological disorders such as anxiety or depression, or of inflammatory processes. We present two novel series of amide derivatives of ibuprofen designed as analogues of our reference FAAH inhibitor Ibu-AM5 to further explore its structure-activity relationships. In the new amides, the 2-methylpyridine moiety of Ibu-AM5 was substituted by benzylamino and piperazinoaryl moieties. The obtained benzylamides and piperazinoarylamides showed FAAH inhibition ranging from the low to high micromolar potency. The binding of the new amides in the active site of FAAH, estimated using the induced fit protocol, indicated arylpiperazinoamides binding the ACB channel and the cytosolic port, and benzylamides binding the ACB channel.

Identifiants

pubmed: 30688118
doi: 10.1080/14756366.2018.1532418
pmc: PMC6352954
doi:

Substances chimiques

Amides 0
Enzyme Inhibitors 0
Piperazine 1RTM4PAL0V
Amidohydrolases EC 3.5.-
fatty-acid amide hydrolase EC 3.5.1.-
Ibuprofen WK2XYI10QM

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

562-576

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Auteurs

Alessandro Deplano (A)

a Department of Life and Environmental Sciences - Unit of Pharmaceutical, Pharmacological and Nutraceutical Sciences , University of Cagliari , Cagliari , Italy.

Mariateresa Cipriano (M)

b Department of Pharmacology and Clinical Neuroscience , Umeå University , Umeå , Sweden.

Federica Moraca (F)

c Department of Chemical Sciences , University of Napoli Federico II , Napoli , Italy.

Ettore Novellino (E)

d Department of Pharmacy , University of Napoli Federico II , Napoli , Italy.

Bruno Catalanotti (B)

d Department of Pharmacy , University of Napoli Federico II , Napoli , Italy.

Christopher J Fowler (CJ)

b Department of Pharmacology and Clinical Neuroscience , Umeå University , Umeå , Sweden.

Valentina Onnis (V)

a Department of Life and Environmental Sciences - Unit of Pharmaceutical, Pharmacological and Nutraceutical Sciences , University of Cagliari , Cagliari , Italy.

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Classifications MeSH