Selectivity in multiple multicomponent reactions: types and synthetic applications.

isocyanides multicomponent reactions reaction discovery selectivity

Journal

Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746

Informations de publication

Date de publication:
2019
Historique:
received: 13 12 2018
accepted: 07 02 2019
entrez: 16 3 2019
pubmed: 16 3 2019
medline: 16 3 2019
Statut: epublish

Résumé

Multiple multicomponent reactions reach an unparalleled level of connectivity, leading to highly complex adducts. Usually, only one type of transformation involving the same set of reactants takes place. However, in some occasions this is not the case. Selectivity issues then arise, and different scenarios are analyzed. The structural pattern of the reactants, the reaction design and the experimental conditions are the critical factors dictating selectivity in these processes.

Identifiants

pubmed: 30873236
doi: 10.3762/bjoc.15.46
pmc: PMC6404517
doi:

Types de publication

Journal Article Review

Langues

eng

Pagination

521-534

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Auteurs

Ouldouz Ghashghaei (O)

Laboratory of Medicinal Chemistry, Faculty of Pharmacy and Food Sciences and Institute of Biomedicine (IBUB), University of Barcelona, Av. de Joan XXIII, 27-31, 08028 Barcelona, Spain.

Francesca Seghetti (F)

Department of Pharmacy and Biotechnology (FaBiT), University of Bologna, Via Belmeloro, 6, 40126, Bologna, Italy.

Rodolfo Lavilla (R)

Laboratory of Medicinal Chemistry, Faculty of Pharmacy and Food Sciences and Institute of Biomedicine (IBUB), University of Barcelona, Av. de Joan XXIII, 27-31, 08028 Barcelona, Spain.

Classifications MeSH