Characterization of a trans-trans Carbonic Acid-Fluoride Complex by Infrared Action Spectroscopy in Helium Nanodroplets.

Carbonic Acid / chemistry Fluorides / chemistry Helium / chemistry Molecular Conformation Molecular Dynamics Simulation Nanostructures / chemistry Spectrophotometry, Infrared Stereoisomerism

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
10 04 2019
Historique:
pubmed: 19 3 2019
medline: 25 7 2020
entrez: 19 3 2019
Statut: ppublish

Résumé

The high Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen bonds in the complexation of fluoride with protic molecules. Herein, we report that carbonic acid, a thermodynamically disfavored species that is challenging to investigate experimentally, forms a complex with fluoride in the gas phase. Intriguingly, this complex is highly stable and is observed in abundance upon nanoelectrospray ionization of an aqueous sodium fluoride solution in the presence of gas-phase carbon dioxide. We characterize the structure and properties of the carbonic acid-fluoride complex, F

Identifiants

DOI: 10.1021/jacs.8b13542 PMID: 30883095 PMC: PMC6727381
pubmed: 30883095
doi: 10.1021/jacs.8b13542
pmc: PMC6727381
doi:

Substances chimiques

Helium 206GF3GB41
Carbonic Acid 463-79-6
Fluorides Q80VPU408O

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

5815-5823

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Auteurs

Daniel A Thomas (DA)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.
ORCID: 0000-0001-9415-5991

Eike Mucha (E)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.

Maike Lettow (M)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.

Gerard Meijer (G)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.
ORCID: 0000-0001-9669-8340

Mariana Rossi (M)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.
ORCID: 0000-0002-3552-0677

Gert von Helden (G)

Fritz-Haber-Institut der Max-Planck-Gesellschaft , Faradayweg 4-6 , 14195 Berlin , Germany.
ORCID: 0000-0001-7611-8740

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Composés inorganiques du carbone › Acide carbonique › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Produits chimiques inorganiques › Composés du fluor › Acide fluorhydrique › Fluorures › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Produits chimiques inorganiques › Gaz › Gaz rares › Hélium › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Conformation moléculaire › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Sciences de l'information › Méthodologies informatiques › Simulation numérique › Simulation de dynamique moléculaire › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Nanostructures › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Techniques d'investigation › Techniques de chimie analytique › Analyse spectrale › Spectrophotométrie › Spectrophotométrie IR › Characterization of a trans-trans Carbonic...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Characterization of a trans-trans Carbonic...