Charge Transport through Self-Assembled Monolayers of Monoterpenoids.

Monoterpenes / chemistry Sulfhydryl Compounds / chemistry
charge transport origin of life quantum tunneling self-assembled monolayers terpenes

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
11 06 2019
Historique:
received: 10 03 2019
pubmed: 17 4 2019
medline: 9 9 2020
entrez: 17 4 2019
Statut: ppublish

Résumé

The nature of the processes at the origin of life that selected specific classes of molecules for broad incorporation into cells is controversial. Among those classes selected were polyisoprenoids and their derivatives. This paper tests the hypothesis that polyisoprenoids were early contributors to membranes in part because they (or their derivatives) could facilitate charge transport by quantum tunneling. It measures charge transport across self-assembled monolayers (SAMs) of carboxyl-terminated monoterpenoids (O

Identifiants

DOI: 10.1002/anie.201902997 PMID: 30989746
pubmed: 30989746
doi: 10.1002/anie.201902997
doi:

Substances chimiques

Monoterpenes 0
Sulfhydryl Compounds 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

8097-8102

Subventions

Organisme : Simons Foundation
ID : 290364
Pays : International
Organisme : National Science Foundation
ID : CHE1808361
Pays : International

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Brian J Cafferty (BJ)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
ORCID: 0000-0002-9971-354X

Li Yuan (L)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.

Mostafa Baghbanzadeh (M)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.

Dmitrij Rappoport (D)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.

M Hassan Beyzavi (MH)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
Current address: Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, AR, 72701, USA.

George M Whitesides (GM)

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
Kalvi Institute for Bionano Science and Technology, Harvard University, 29 Oxford Street, Cambridge, MA, 02138, USA.
Wyss Institute for Biologically Inspired Engineering, Harvard University, 60 Oxford Street, Cambridge, MA, 02138, USA.
ORCID: 0000-0001-9451-2442

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Terpènes › Monoterpènes › Charge Transport through Self-Assembled...
questionsmedicales.fr › Composés chimiques organiques › Composés du soufre › Thiols › Charge Transport through Self-Assembled...