Design, synthesis and molecular docking of new N-4-piperazinyl ciprofloxacin-triazole hybrids with potential antimicrobial activity.


Journal

Bioorganic chemistry
ISSN: 1090-2120
Titre abrégé: Bioorg Chem
Pays: United States
ID NLM: 1303703

Informations de publication

Date de publication:
07 2019
Historique:
received: 19 08 2018
revised: 20 04 2019
accepted: 24 04 2019
pubmed: 1 5 2019
medline: 23 9 2020
entrez: 1 5 2019
Statut: ppublish

Résumé

New N-4-piperazinyl ciprofloxacin-triazole hybrids 6a-o were prepared and characterized. The in vitro antimycobacterial activity revealed that compound 6a experienced promising antimycobacterial activity against Mycobactrium smegmatis compared with the reference isoniazide (INH). Additionally, compound 6a exhibited broad spectrum antibacterial activity against all the tested strains either Gram-positive or Gram-negative bacteria compared with the reference ciprofloxacin. Also, compounds 6g and 6i displayed considerable antifungal activity compared with the reference ketoconazole. DNA cleavage assay of the highly active compounds 6c and 6h showed a good correlation between the Mycobactrium cleaved DNA gyrase assay and their in vitro antimycobactrial activity. Moreover, molecular modeling studies were done for the designed ciprofloxacin derivatives to predict their binding modes towards Topoisomerase II enzyme (PDB: 5bs8).

Identifiants

pubmed: 31039471
pii: S0045-2068(18)30898-8
doi: 10.1016/j.bioorg.2019.102952
pii:
doi:

Substances chimiques

Anti-Bacterial Agents 0
Triazoles 0
Ciprofloxacin 5E8K9I0O4U

Types de publication

Journal Article Research Support, N.I.H., Extramural

Langues

eng

Sous-ensembles de citation

IM

Pagination

102952

Subventions

Organisme : NCI NIH HHS
ID : R01 CA077373
Pays : United States

Informations de copyright

Copyright © 2019 Elsevier Inc. All rights reserved.

Auteurs

Hamada H H Mohammed (HHH)

Department of Medicinal Chemistry, Faculty of Pharmacy, Minia University, Minia 61519, Egypt; Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Deraya University, New-Minia 61519, Egypt.

El-Shimaa M N Abdelhafez (EMN)

Department of Medicinal Chemistry, Faculty of Pharmacy, Minia University, Minia 61519, Egypt.

Samar H Abbas (SH)

Department of Medicinal Chemistry, Faculty of Pharmacy, Minia University, Minia 61519, Egypt.

Gamal A I Moustafa (GAI)

Department of Medicinal Chemistry, Faculty of Pharmacy, Minia University, Minia 61519, Egypt.

Glenn Hauk (G)

Deprtment of Biophysics and Biophysical Chemistry, Johns Hopkins University School of Medicine, Baltimore, MD, USA.

James M Berger (JM)

Deprtment of Biophysics and Biophysical Chemistry, Johns Hopkins University School of Medicine, Baltimore, MD, USA.

Satoshi Mitarai (S)

Bacteriology Division, Department of Mycobacterium Reference and Research, Research Institute of Tuberculosis, Japan Anti-Tuberculosis Association, Kiyose 204-8533, Japan.

Masayoshi Arai (M)

Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.

Rehab M Abd El-Baky (RM)

Department of Microbiology & Immunology, Faculty of Pharmacy, Minia University, Minia 61519, Egypt.

Gamal El-Din A Abuo-Rahma (GEA)

Department of Medicinal Chemistry, Faculty of Pharmacy, Minia University, Minia 61519, Egypt. Electronic address: gamal.aborahma@mu.edu.eg.

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Classifications MeSH