Overcoming insecticide resistance through computational inhibitor design.


Journal

Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876

Informations de publication

Date de publication:
15 10 2019
Historique:
pubmed: 3 10 2019
medline: 28 3 2020
entrez: 3 10 2019
Statut: ppublish

Résumé

Insecticides allow control of agricultural pests and disease vectors and are vital for global food security and health. The evolution of resistance to insecticides, such as organophosphates (OPs), is a serious and growing concern. OP resistance often involves sequestration or hydrolysis of OPs by carboxylesterases. Inhibiting carboxylesterases could, therefore, restore the effectiveness of OPs for which resistance has evolved. Here, we use covalent virtual screening to produce nano-/picomolar boronic acid inhibitors of the carboxylesterase αE7 from the agricultural pest

Identifiants

pubmed: 31575743
pii: 1909130116
doi: 10.1073/pnas.1909130116
pmc: PMC6800356
doi:

Substances chimiques

Insecticides 0
Organophosphates 0
Carboxylic Ester Hydrolases EC 3.1.1.-
Acetylcholinesterase EC 3.1.1.7
Malathion U5N7SU872W
Diazinon YUS1M1Q929

Banques de données

PDB
['5TYJ', '5TYP']

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

21012-21021

Déclaration de conflit d'intérêts

Competing interest statement: G.J.C., C.J.J., and N.L., are inventors on a US patent application (62/443,825) for the described synergists.

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Auteurs

Galen J Correy (GJ)

Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia.

Daniel Zaidman (D)

Department of Organic Chemistry, The Weizmann Institute of Science, 76100 Rehovot, Israel.

Alon Harmelin (A)

Department of Veterinary Resources, The Weizmann Institute of Science, 76100 Rehovot, Israel.

Silvia Carvalho (S)

Maurice and Vivienne Wohl Institute for Drug Discovery, Nancy and Stephen Grand Israel National Center for Personalized Medicine, The Weizmann Institute of Science, 76100 Rehovot, Israel.

Peter D Mabbitt (PD)

Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia.

Viviane Calaora (V)

BioTransfer, F-93100 Montreuil, France.

Peter J James (PJ)

Queensland Alliance for Agriculture and Food Innovation, The University of Queensland, Brisbane, QLD 4072, Australia.

Andrew C Kotze (AC)

Agriculture and Food, Commonwealth Scientific and Industrial Research Organization (CSIRO), St. Lucia, QLD 4067, Australia.

Colin J Jackson (CJ)

Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia; colin.jackson@anu.edu.au nir.london@weizmann.ac.il.

Nir London (N)

Department of Organic Chemistry, The Weizmann Institute of Science, 76100 Rehovot, Israel; colin.jackson@anu.edu.au nir.london@weizmann.ac.il.

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Classifications MeSH