Poly(2-oxazoline)s Based on Phenolic Acids.

Hydroxybenzoates / chemistry Kinetics Microwaves Oxazoles / chemistry Polymerization Polymers / chemical synthesis
2-oxazoline catechol cationic ring-opening polymerization microwave phenolic acid

Journal

Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239

Informations de publication

Date de publication:
Jan 2020
Historique:
received: 08 08 2019
revised: 06 09 2019
pubmed: 5 10 2019
medline: 30 5 2020
entrez: 5 10 2019
Statut: ppublish

Résumé

A series of phenolic-acid-based 2-oxazoline monomers with methoxy-substituted phenyl and cinnamyl side chains is synthesized and polymerized in a microwave reactor at 140 °C using methyl tosylate as the initiator. The obtained poly(2-oxazoline)s are characterized by NMR spectroscopy, MALDI-TOF mass spectrometry, and size-exclusion chromatography (SEC). Kinetic studies reveal that the microwave-assisted polymerization is fast and completed within less than ≈10 min for low monomer-to-initiator ratios of ≤25. Polymers with number-average molar masses of up to 6500 g mol

Identifiants

DOI: 10.1002/marc.201900404 PMID: 31583798
pubmed: 31583798
doi: 10.1002/marc.201900404
doi:

Substances chimiques

Hydroxybenzoates 0
Oxazoles 0
Polymers 0
poly(2-oxazoline) 0
phenolic acid I3P9R8317T

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e1900404

Subventions

Organisme : University of Potsdam

Informations de copyright

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Nils Lüdecke (N)

Institute of Chemistry, University of Potsdam, Karl-Liebknecht Str. 24-25, 14476, Potsdam, Germany.

Steffen M Weidner (SM)

Federal Institute for Materials Research and Testing - BAM 1.3, Richard-Willstätter-Straße 11, 12489, Berlin, Germany.

Helmut Schlaad (H)

Institute of Chemistry, University of Potsdam, Karl-Liebknecht Str. 24-25, 14476, Potsdam, Germany.
ORCID: 0000-0002-5824-7204

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures cycliques › Hydrocarbures aromatiques › Dérivés du benzène › Phénols › Hydroxybenzoates › Poly(2-oxazoline)s Based on Phenolic Acids.
questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Cinétique › Poly(2-oxazoline)s Based on Phenolic Acids.
questionsmedicales.fr › Phénomènes physiques › Rayonnement › Rayonnement non ionisant › Ondes hertziennes › Micro-ondes › Poly(2-oxazoline)s Based on Phenolic Acids.
questionsmedicales.fr › Composés hétérocycliques › Composés hétéromonocycliques › Azoles › Oxazoles › Poly(2-oxazoline)s Based on Phenolic Acids.
questionsmedicales.fr › Phénomènes chimiques › Polymérisation › Poly(2-oxazoline)s Based on Phenolic Acids.
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Poly(2-oxazoline)s Based on Phenolic Acids.