Labeled substance P as a neuropeptide reporter substance for enzyme activity.


Journal

Journal of pharmaceutical and biomedical analysis
ISSN: 1873-264X
Titre abrégé: J Pharm Biomed Anal
Pays: England
ID NLM: 8309336

Informations de publication

Date de publication:
30 Jan 2020
Historique:
received: 08 08 2019
revised: 18 10 2019
accepted: 22 10 2019
pubmed: 14 11 2019
medline: 5 6 2020
entrez: 14 11 2019
Statut: ppublish

Résumé

Recently, we developed a bradykinin reporter assay and demonstrated the differing protease activity in Complex Regional Pain Syndrome patients vs. controls. In order to further characterize CRPS pathophysiology, the neuropeptide substance P was evaluated as possible reporter substance, here. It was labeled with a chromophore at the lysine residue and generated two major fragments following incubation with serum (amino acid residues 3-8 and 3-11) which were reproducibly separated by thin-layer chromatography. Dabsylated substance P was shown to be a substrate of angiotensin-converting enzyme. The combination of both bradykinin and substance P reporter substances with specific enzyme inhibitors will shed more light on biochemical pathways in inflammatory processes and pain. Comparative clinical studies are now needed to define the application range of both assays in more detail.

Identifiants

pubmed: 31718985
pii: S0731-7085(19)31950-8
doi: 10.1016/j.jpba.2019.112953
pii:
doi:

Substances chimiques

Angiotensin-Converting Enzyme Inhibitors 0
Neuropeptides 0
Substance P 33507-63-0
Peptidyl-Dipeptidase A EC 3.4.15.1
Bradykinin S8TIM42R2W

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

112953

Informations de copyright

Copyright © 2019 Elsevier B.V. All rights reserved.

Auteurs

Ulrich Schreiber (U)

Core Unit Proteomics, Interdisciplinary Center for Clinical Research, Medical Faculty, University of Münster, Germany.

Christian Engl (C)

Core Unit Proteomics, Interdisciplinary Center for Clinical Research, Medical Faculty, University of Münster, Germany.

Malte Bayer (M)

Core Unit Proteomics, Interdisciplinary Center for Clinical Research, Medical Faculty, University of Münster, Germany.

Simone König (S)

Core Unit Proteomics, Interdisciplinary Center for Clinical Research, Medical Faculty, University of Münster, Germany. Electronic address: koenigs@uni-muenster.de.

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Classifications MeSH