Fabric phase sorptive extraction for the determination of 17 multiclass fungicides in environmental water by gas chromatography-tandem mass spectrometry.
environmental water monitoring
fabric phase sorptive extraction
fungicides
gas chromatography-tandem mass spectrometry
sample preparation
Journal
Journal of separation science
ISSN: 1615-9314
Titre abrégé: J Sep Sci
Pays: Germany
ID NLM: 101088554
Informations de publication
Date de publication:
May 2020
May 2020
Historique:
received:
03
12
2019
revised:
13
01
2020
accepted:
14
01
2020
pubmed:
21
1
2020
medline:
14
1
2021
entrez:
21
1
2020
Statut:
ppublish
Résumé
A rapid environmental pollution screening and monitoring workflow based on fabric phase sorptive extraction-gas chromatography-tandem mass spectrometry (FPSE-GC-MS/MS) is proposed for the first time for the analysis of 17 widespread used fungicides (metalaxyl, cyprodinil, tolylfluanid, procymidone, folpet, fludioxonil, myclobutanil, kresoxim methyl, iprovalicarb, benalaxyl, trifloxystrobin, fenhexamid, tebuconazole, iprodione, pyraclostrobin, azoxystrobin and dimethomorph) in environmental waters. The most critical parameters affecting FPSE, such as sample volume, matrix pH, desorption solvent and time, and ionic strength were optimized by statistical design of experiment to obtain the highest extraction efficiency. Under the optimized conditions, the proposed FPSE-GC-MS/MS method was validated in terms of linearity, repeatability, reproducibility, accuracy and precision. To assess matrix effects, recovery studies were performed employing different water matrices including ultrapure, fountain, river, spring, and tap water at 4 different concentration levels (0.1, 0.5, 1 and 5 µg/L). Recoveries were quantitative with values ranging between 70-115%, and relative standard deviation values lower than 14%. Limits of quantification were at the low ng/L for all the target fungicides. Finally, the validated FPSE-GC-MS/MS method was applied to real water samples, revealing the presence of 11 out of the 17 target fungicides.
Identifiants
pubmed: 31958358
doi: 10.1002/jssc.201901232
doi:
Substances chimiques
Fungicides, Industrial
0
Water Pollutants, Chemical
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1817-1829Subventions
Organisme : Xunta de Galicia
ID : FEADER 2017/056B
Organisme : Ministerio de Ciencia e Innovación
ID : RED2018-102522-T
Organisme : Ministerio de Ciencia e Innovación
ID : UNST10-1E-491
Informations de copyright
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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