pH dependent degradation properties of lactide based 3D microchamber arrays for sustained cargo release.


Journal

Colloids and surfaces. B, Biointerfaces
ISSN: 1873-4367
Titre abrégé: Colloids Surf B Biointerfaces
Pays: Netherlands
ID NLM: 9315133

Informations de publication

Date de publication:
Apr 2020
Historique:
received: 30 09 2019
revised: 23 01 2020
accepted: 24 01 2020
pubmed: 3 2 2020
medline: 24 11 2020
entrez: 3 2 2020
Statut: ppublish

Résumé

Encapsulation of small water soluble molecules is important in a large variety of applications, ranging from medical substance releasing implants in the field of medicine over release of catalytically active substances in the field of chemical processing to anti-corrosion agents in industry. In this work polylactic acid (PLA) based hollow-structured microchamber (MC) arrays are fabricated via one-step dip coating of a silicone rubber stamp into PLA solution. These PLA MCs are able to retain small water soluble molecules (Rhodamine B) stably entrapped within aqueous environments. It is shown, that degradation of PLA MCs strongly depends on environmental conditions like surrounding pH and follows first order degradation kinetics. This pH dependent PLA MC degradation can be utilized to control the release kinetics of encapsulated cargo.

Identifiants

pubmed: 32007703
pii: S0927-7765(20)30056-4
doi: 10.1016/j.colsurfb.2020.110826
pii:
doi:

Substances chimiques

Polyesters 0
poly(lactide) 459TN2L5F5

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

110826

Informations de copyright

Copyright © 2020 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Yuechi Liu (Y)

Key Laboratory of Micro-systems and Micro-structures Manufacturing Ministry of Education, Harbin Institute of Technology, Harbin, 150001, China.

Meiyu Gai (M)

Max Plank Institute of Polymer Research, Ackermannweg 10, 55128, Mainz, Germany; School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London, E1 4NS, United Kingdom. Electronic address: gai01@mpip-mainz.mpg.de.

Dusita Sukvanitvichai (D)

School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London, E1 4NS, United Kingdom.

Johannes Frueh (J)

Key Laboratory of Micro-systems and Micro-structures Manufacturing Ministry of Education, Harbin Institute of Technology, Harbin, 150001, China; Department of Civil, Environmental and Geomatic Engineering, ETH Zürich, Stefano-Franscini-Platz 3, 8093, Zürich, Switzerland. Electronic address: Johannes.frueh@hit.edu.cn.

Gleb B Sukhorukov (GB)

School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London, E1 4NS, United Kingdom; Skolkovo Institute of Science and Technology, Moscow, 143025, Russia. Electronic address: g.sukhorukov@qmul.ach.uk.

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Classifications MeSH