Nickel-Catalyzed Removal of Alkene Protecting Group of Phenols, Alcohols via Chain Walking Process.
alcohol
chain walking
deprotection
nickel
phenol
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
30 Jan 2020
30 Jan 2020
Historique:
received:
11
12
2019
revised:
25
01
2020
accepted:
28
01
2020
entrez:
6
2
2020
pubmed:
6
2
2020
medline:
21
11
2020
Statut:
epublish
Résumé
An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alcoholic ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group.
Identifiants
pubmed: 32019185
pii: molecules25030602
doi: 10.3390/molecules25030602
pmc: PMC7037277
pii:
doi:
Substances chimiques
Alcohols
0
Alkenes
0
Phenols
0
Nickel
7OV03QG267
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : National Natural Science Foundation of China
ID : 21602017
Organisme : Natural Science Foundation of Jiangsu Province
ID : BK20160405
Organisme : Research Start-up Fund of Changshu Institute of Technology
ID : No. XZ1508
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
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