Metalloporphyrinic metal-organic frameworks: Controlled synthesis for catalytic applications in environmental and biological media.
Catalysis applications
Metal-organic frameworks (MOFs)
Metalloporphyrin coordination
Metalloporphyrin-MOFs composites
Modulation strategies
Journal
Advances in colloid and interface science
ISSN: 1873-3727
Titre abrégé: Adv Colloid Interface Sci
Pays: Netherlands
ID NLM: 8706645
Informations de publication
Date de publication:
Mar 2020
Mar 2020
Historique:
received:
07
11
2019
revised:
09
01
2020
accepted:
20
01
2020
pubmed:
7
2
2020
medline:
24
11
2020
entrez:
7
2
2020
Statut:
ppublish
Résumé
Recently, as a new sub-family of porous coordination polymers (PCPs), porphyrinic-MOFs (Porph-MOFs) with biomimetic features have been developed using porphyrin macrocycles as ligands and/or pillared linkers. The control over the coordination of the porphyrin ligand and its derivatives however remains a challenge for engineering new tunable Porph-MOF frameworks by self-assembly methods. The key challenges exist in the following respects: (i) collapse of the large open pores of Porph-MOFs during synthesis, (ii) deactivation of unsaturated metal-sites (UMCs) by axial coordination, and (iii) the tendency of both coordinated moieties (at peripheral meso- and beta-carbon sites) and the N
Identifiants
pubmed: 32028075
pii: S0001-8686(19)30415-4
doi: 10.1016/j.cis.2020.102108
pii:
doi:
Substances chimiques
Metal-Organic Frameworks
0
Metalloporphyrins
0
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
102108Informations de copyright
Copyright © 2020 Elsevier B.V. All rights reserved.