Discovery of multidrug efflux pump inhibitors with a novel chemical scaffold.


Journal

Biochimica et biophysica acta. General subjects
ISSN: 1872-8006
Titre abrégé: Biochim Biophys Acta Gen Subj
Pays: Netherlands
ID NLM: 101731726

Informations de publication

Date de publication:
06 2020
Historique:
received: 25 11 2019
revised: 21 01 2020
accepted: 30 01 2020
pubmed: 8 2 2020
medline: 23 10 2020
entrez: 8 2 2020
Statut: ppublish

Résumé

Multidrug efflux is a major contributor to antibiotic resistance in Gram-negative bacterial pathogens. Inhibition of multidrug efflux pumps is a promising approach for reviving the efficacy of existing antibiotics. Previously, inhibitors targeting both the efflux transporter AcrB and the membrane fusion protein AcrA in the Escherichia coli AcrAB-TolC efflux pump were identified. Here we use existing physicochemical property guidelines to generate a filtered library of compounds for computational docking. We then experimentally test the top candidate coumpounds using in vitro binding assays and in vivo potentiation assays in bacterial strains with controllable permeability barriers. We thus identify a new class of inhibitors of E. coli AcrAB-TolC. Six molecules with a shared scaffold were found to potentiate the antimicrobial activity of erythromycin and novobiocin in hyperporinated E. coli cells. Importantly, these six molecules were also active in wild-type strains of both Acinetobacter baumannii and Klebsiella pneumoniae, potentiating the activity of erythromycin and novobiocin up to 8-fold.

Identifiants

pubmed: 32032658
pii: S0304-4165(20)30036-2
doi: 10.1016/j.bbagen.2020.129546
pmc: PMC7153915
mid: NIHMS1570345
pii:
doi:

Substances chimiques

AcrA protein, E coli 0
AcrAB-TolC protein, E coli 0
AcrB protein, E coli 0
Anti-Bacterial Agents 0
Anti-Infective Agents 0
Carrier Proteins 0
Escherichia coli Proteins 0
Lipoproteins 0
Membrane Transport Proteins 0
Multidrug Resistance-Associated Proteins 0
Novobiocin 17EC19951N
Erythromycin 63937KV33D

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

129546

Subventions

Organisme : NIAID NIH HHS
ID : R01 AI052293
Pays : United States
Organisme : NIAID NIH HHS
ID : R56 AI052293
Pays : United States
Organisme : NIH HHS
ID : S10 OD025014
Pays : United States

Informations de copyright

Copyright © 2020 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Auteurs

Adam T Green (AT)

UT/ORNL Center for Molecular Biophysics, Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA; Graduate School of Genome Science and Technology, University of Tennessee, Knoxville, TN, 37996, USA.

Mohammad Moniruzzaman (M)

Department of Chemistry and Biochemistry, University of Oklahoma, Norman, OK 73019, USA.

Connor J Cooper (CJ)

UT/ORNL Center for Molecular Biophysics, Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA; Graduate School of Genome Science and Technology, University of Tennessee, Knoxville, TN, 37996, USA.

John K Walker (JK)

Department of Pharmacology and Physiology, Saint Louis University School of Medicine and the Henry and Amelia Nasrallah Center for Neuroscience, Saint Louis, MO, 63104, USA.

Jeremy C Smith (JC)

UT/ORNL Center for Molecular Biophysics, Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA; Graduate School of Genome Science and Technology, University of Tennessee, Knoxville, TN, 37996, USA; Department of Biochemistry and Cellular and Molecular Biology, University of Tennessee, Knoxville, TN 37996, USA.

Jerry M Parks (JM)

UT/ORNL Center for Molecular Biophysics, Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA; Graduate School of Genome Science and Technology, University of Tennessee, Knoxville, TN, 37996, USA. Electronic address: parksjm@ornl.gov.

Helen I Zgurskaya (HI)

Department of Chemistry and Biochemistry, University of Oklahoma, Norman, OK 73019, USA. Electronic address: elenaz@ou.edu.

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Classifications MeSH